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Preparation Of Highly Functionalized Carbon Nanoparticles Using A One-step Acid Dehydration Of Glycerol

Christopher S. Estes, Angela Y. Gerard, J. Dennis Godward, Spencer B. Hayes, Sabrina H. Liles, Jacob L. Shelton, T. S. Stewart, Rebekah I. Webster, H. Francis Webster
Published 2019 · Materials Science
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Abstract In this paper, we report the low-cost synthesis of a highly functionalized carbon material synthesized through controlled acid dehydration of glycerol. Physical properties were investigated using scanning and transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, and dynamic light scattering. Chemical properties were determined using elemental analysis, acid-base titration, uv–vis spectroscopy, fluorescence spectroscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The acid dehydration temperature during synthesis was varied and at moderate temperatures (160 °C), highly functionalized fluorescent carbon nanoparticles (hydrodynamic radius
This paper references
10.1038/nature11458
A roadmap for graphene
Kostya S Novoselov (2012)
10.1039/C2RA20103H
Nanosize effects of sulfonated carbon nanofiber fabrics for high capacity ion-exchanger
Shinji Imaizumi (2012)
10.1021/CM901593Y
Simple Aqueous Solution Route to Luminescent Carbogenic Dots from Carbohydrates
Hui Peng (2009)
10.1021/la801744a
Graphene oxide dispersions in organic solvents.
Juan Ignacio Paredes (2008)
10.1039/9781782622567
Nanostructured Carbon Materials for Catalysis
Philippe Serp (2015)
10.1016/S0016-7037(02)01044-X
Proton-binding study of standard and reference fulvic acids, humic acids, and natural organic matter
Jason D. Ritchie (2003)
10.1002/anie.200906623
Luminescent carbon nanodots: emergent nanolights.
S. N. Baker (2010)
10.1007/S11434-012-4986-5
A brief review of graphene-based material synthesis and its application in environmental pollution management
Kui Lü (2012)
10.1007/s10562-012-0840-2
Preparation of a Novel Carbon Based Solid Acid Catalyst for Biodiesel Production via a Sustainable Route
Xue-li Song (2012)
10.1155/2011/346206
Carbon nanostructures production by AC arc discharge plasma process at atmospheric pressure
S. Zhao (2011)
10.1016/J.NANOEN.2011.11.006
Nanostructured carbon for energy storage and conversion
Stephanie L. Candelaria (2012)
The Chemical History Of A Candle, A Course Of Lectures Delivered Before A Juvenile Audience At The Royal Institution;
Michael Faraday (2008)
10.1016/J.CATCOM.2010.01.010
Novel sulfonated carbonaceous materials from p-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst
Baohua Zhang (2010)
10.1063/1.124012
Nanoporous carbon produced by ball milling
Ying Chen (1999)
10.2166/wst.2016.213
Removal of Pb(II) from aqueous solutions by graphene oxide aerogels.
Nooshin Salman Tabrizi (2016)
10.1002/adma.201101007
Sulfonated graphene for persistent aromatic pollutant management.
Guixia Zhao (2011)
10.1016/S0165-2370(97)00060-0
Thermal stability of oxygenated functions in activated carbons
Gabriela de la Puente (1997)
10.1039/C3TA14751G
Bio-inspired surface-functionalization of graphene oxide for the adsorption of organic dyes and heavy metal ions with a superhigh capacity
Zhihui Dong (2014)
10.1016/j.jhazmat.2006.07.049
Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies.
B. H. Hameed (2007)
10.1038/nature02087
Drying-mediated self-assembly of nanoparticles
Eran Rabani (2003)
10.1002/cssc.201300332
Formation, molecular structure, and morphology of humins in biomass conversion: influence of feedstock and processing conditions.
Ilona van Zandvoort (2013)
10.1016/J.JPOWSOUR.2012.09.068
Preparation and properties of cross-linked sulfonated poly(imide-siloxane) for polymer electrolyte fuel cell application
Chao-Chieh Lin (2013)
10.1016/J.CARBON.2007.06.049
Low-temperature solution synthesis of carbon nanoparticles, onions and nanoropes by the assembly of aromatic molecules
Yan Yan (2007)
10.1007/S00706-009-0213-8
Preparation of an improved sulfonated carbon-based solid acid as a novel, efficient, and reusable catalyst for chemoselective synthesis of 2-oxazolines and bis-oxazolines
Valiollah Mirkhani (2009)
10.1039/C2JM16608A
Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions
Fujian Liu (2012)
10.1063/1.362745
Raman spectroscopy on amorphous carbon films
J. Schwan (1996)
10.1016/j.carbon.2007.03.038
X-ray diffraction patterns of graphite and turbostratic carbon
Zhe Qin Li (2007)
10.2136/sssaj1965.03615995002900030016x
Determination of Acidity in Soil Organic Matter 1
M. Schnitzer (1965)
10.1016/0009-2614(95)00825-O
Catalytic growth of single-walled manotubes by laser vaporization
T. Guo (1995)
10.1038/srep21286
Camphor-mediated synthesis of carbon nanoparticles, graphitic shell encapsulated carbon nanocubes and carbon dots for bioimaging
Goldie Oza (2016)
10.1016/j.carbon.2005.04.004
Sulfonated carbon nanotubes as a strong protonic acid catalyst
Feng Peng (2005)
10.1016/J.CARBON.2010.01.030
One-step synthesis of carbon functionalized with sulfonic acid groups using hydrothermal carbonization
Xuezheng Liang (2010)
10.1002/cssc.201301149
Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels.
Margarida M Antunes (2014)
10.1016/j.matlet.2005.08.009
Fabrication and growth mechanism of carbon nanotubes by catalytic chemical vapor deposition
Naiqin Zhao (2006)
10.4028/www.scientific.net/AMR.624.76
Solution Phase Synthesis of Amorphous Carbon Nanoparticles under Ambient Atmosphere
Bo Yang Victor Liu (2012)
10.1016/S0008-6223(02)00146-X
Sulfonation of pyropolymeric fibers derived from phenol-formaldehyde resins
Kelly R. Benak (2002)
10.1016/J.CARBON.2014.01.016
Photoluminescent carbon dots directly derived from polyethylene glycol and their application for cellular imaging
Rui-jun Fan (2014)
10.1021/nl080604h
Synthesis of water soluble graphene.
Yongchao Si (2008)
10.1155/2011/938491
Characterization of multiwalled carbon nanotubes dispersing in water and association with biological effects
Xuelian Cheng (2011)
10.1016/j.biortech.2013.12.002
A green recyclable SO(3)H-carbon catalyst derived from glycerol for the production of biodiesel from FFA-containing karanja (Pongamia glabra) oil in a single step.
B. L. A. Prabhavathi Devi (2014)
10.3390/molecules18078168
Preparation of a Sulfonated Carbonaceous Material from Lignosulfonate and Its Usefulness as an Esterification Catalyst
Duckhee Lee (2013)
10.1021/nl803798y
Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents.
Sungjin Park (2009)
10.1039/C2JM32206D
Facile synthesis of highly emissive carbon dots from pyrolysis of glycerol; gram scale production of carbon dots/mSiO2 for cell imaging and drug release
Chih-wei Lai (2012)
10.1039/A904529E
NIR FT Raman spectroscopic study of flame soot
Bernd Dippel (1999)
10.1039/c4cs00269e
Carbon quantum dots and their applications.
Shi Ying Lim (2015)
10.1016/J.MOLCATA.2011.05.025
Synthesis of sulfonic acid functionalized carbon catalyst from glycerol pitch and its application for tetrahydropyranyl protection/deprotection of alcohols and phenols
B.L.A. Prabhavathi Devi (2011)
10.1016/j.cattod.2006.01.037
Esterification of higher fatty acids by a novel strong solid acid
Atsushi Takagaki (2006)
10.1039/C5RA14310A
Dispersion analysis of carbon nanotubes, carbon onions, and nanodiamonds for their application as reinforcement phase in nickel metal matrix composites
Leander Reinert (2015)
10.1021/CS300103K
Amorphous Carbon with SO3H Groups as a Solid Brønsted Acid Catalyst
Kiyotaka Nakajima (2012)
10.1039/C2JM15944A
Bottom-up synthesis of large-scale graphene oxide nanosheets
Libin Tang (2012)
10.1021/ja803983h
Hydrolysis of cellulose by amorphous carbon bearing SO3H, COOH, and OH groups.
Satoshi Suganuma (2008)
10.1039/b917103g
The chemistry of graphene oxide.
D. R. Dreyer (2010)
10.1039/C4RA00904E
A novel fuel cell membrane with high efficiency
Deivanayagam Paradesi (2014)
10.3390/molecules190914582
Graphene-Based Nanomaterials as Heterogeneous Acid Catalysts: A Comprehensive Perspective
Bhaskar Garg (2014)
10.1366/0003702021954908
Fourier Transform Infrared, UV-Visible, and X-Ray Diffraction Analyses of Organic Matter in Humin, Humic Acid, and Fulvic Acid Fractions in Soil Exposed to Elevated CO2 and N Fertilization
A. Naidja (2002)
10.3762/bjnano.5.207
Carbon nano-onions (multi-layer fullerenes): chemistry and applications
Juergen Bartelmess (2014)
10.1016/j.jcis.2018.03.094
Sulfonated graphene oxide as an adsorbent for removal of Pb2+ and methylene blue.
Mao-ping Wei (2018)
10.1016/J.CARBON.2010.10.010
Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis
Rowan K. Leary (2011)
10.1039/C0SC00484G
Sulfonated graphene as water-tolerant solid acid catalyst
Junyi Ji (2011)
10.1039/c0cc02724c
Commercially activated carbon as the source for producing multicolor photoluminescent carbon dots by chemical oxidation.
Zhen-An Qiao (2010)
10.1103/PhysRevB.72.085401
Raman spectroscopy of hydrogenated amorphous carbons
C. Casiraghi (2005)
10.1016/J.CARBON.2009.07.045
Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation
L. Zhang (2009)
10.1016/j.carbon.2005.02.018
Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information
A. Sadezky (2005)
10.1007/S10008-007-0390-5
Introducing hydrophilic carbon nanoparticles into hydrophilic sol-gel film electrodes
Stuart M. Macdonald (2008)
10.1039/B812943F
One-step synthesis of fluorescent carbon nanoparticles by laser irradiation
Shengliang Hu (2009)
10.1016/j.carbon.2006.02.008
A graphite oxide-like carbogenic material derived from a molecular precursor
Athanasios B. Bourlinos (2006)
10.1039/C6RA04919B
Carbonized glycerol nanotubes as efficient catalysts for biofuel production
Nagabhatla Viswanadham (2016)
10.1002/cssc.200900097
A glycerol-based carbon catalyst for the preparation of biodiesel.
Bethala L. A. Prabhavathi Devi (2009)
10.1039/B615447F
Preparation of a sugar catalyst and its use for highly efficient production of biodiesel.
M. Zong (2007)
10.1016/j.fuel.2006.03.008
FT-Raman spectroscopic study of the evolution of char structure during the pyrolysis of a Victorian brown coal
XiaoJiang Li (2006)
10.1016/J.SCRIPTAMAT.2010.02.035
Hydrothermally enhanced photoluminescence of carbon nanoparticles
Lei Tian (2010)
10.1063/1.4747817
Ultraviolet-visible spectroscopy of graphene oxides
Qi Hui Lai (2012)
10.1021/ACS.ENERGYFUELS.6B02675
Effects of p-Toluenesulfonic Acid in the Conversion of Glucose for Levulinic Acid and Sulfonated Carbon Production
Shimin Kang (2017)
10.1038/srep15931
Waste-Glycerol-Directed Synthesis of Mesoporous Silica and Carbon with Superior Performance in Room-Temperature Hydrogen Production from Formic Acid
Dong-Wook Lee (2015)
10.1021/acs.est.5b01057
Sulfonated graphene nanosheets as a superb adsorbent for various environmental pollutants in water.
Yi Shen (2015)
10.1021/jp027482g
Infrared spectroscopy of carbon materials: A quantum chemical study of model compounds
Elena Fuente (2003)
10.1016/S0008-6223(98)00055-4
New carbon materials for research and technology
Peter Priv.-Doz. Dr. Scharff (1998)
10.1021/ACS.CGD.5B01753
Nanographite Synthesized from Acidified Sucrose Microemulsions under Ambient Conditions
Natasha Jayne Hargreaves (2016)
10.1016/j.biomaterials.2012.01.052
Nano-carrier for gene delivery and bioimaging based on carbon dots with PEI-passivation enhanced fluorescence.
C. Liu (2012)
10.1021/ja1078943
Graphene oxide nanocolloids.
Jiayan Luo (2010)
10.1007/1-4020-3252-8
Use of humic substances to remediate polluted environments : from theory to practice
Irina V. Perminova (2005)
10.1038/srep13166
Crack formation and prevention in colloidal drops
Jin Young Kim (2015)
10.1016/j.jhazmat.2004.11.004
Production of activated carbon from a new precursor molasses by activation with sulphuric acid.
K. Legrouri (2005)
10.1007/s11671-009-9343-5
A Two-Step Hydrothermal Synthesis Approach to Monodispersed Colloidal Carbon Spheres
Chuyang Chen (2009)



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