Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

Adsorption Of Hg(II) From Aqueous Solution Using Thiourea Functionalized Chelating Fiber

Yao Xiao-xia, Wang Hui-cai, Ma Zhenhua, M. Liu, Zhao Xiu-qing, Dai Jia
Published 2016 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract A fast and selective adsorbent for Hg(II) from aqueous solutions using thiourea (TU) functionalized polypropylene fiber grafted acrylic acid (PP-g-AA), PP-g-AA-TU fibers, was characterized by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The adsorption behavior of the functionalized chelating fibers for Hg(II) was investigated by static adsorption experiments, and the effects of some essential factors on adsorption of Hg(II) were examined, such as pH, initial concentration, adsorption time, coexisting cations, and temperature. The results showed that the adsorptive equilibrium could be achieved in 10 min, and the equilibrium adsorption quantity of PP-g-AA-TU fibers was 20 times that of PP-g-AA fibers. The PP-g-AA-TU fibers showed a very high adsorption rate and a good selectivity for Hg(II) over a wide range of pH. The adsorption isotherm can be well described with Langmuir model, with the maximum adsorption capacity for Hg(II) up to 52.04 mg·g − 1 and the removal of Hg(II) more than 97%. The kinetic data indicate that the adsorption process is best-fitted into the pseudo-second-order model.
This paper references
10.1016/J.WATRES.2004.02.024
Removal of trivalent and hexavalent chromium with aminated polyacrylonitrile fibers: performance and mechanisms.
S. Deng (2004)
10.1080/01496390600851665
Development of a Precipitation Based Separation Scheme for Selective Removal and Recovery of Heavy Metals from Cadmium Rich Electroplating Industry Effluents
Sezin Islamoglu (2006)
10.1016/J.JHAZMAT.2006.01.033
Adsorption properties of crosslinked carboxymethyl-chitosan resin with Pb(II) as template ions.
S. Sun (2006)
10.1016/j.jhazmat.2009.11.020
Adsorption studies of heavy metal ions on mesoporous aluminosilicate, novel cation exchanger.
H. Sepehrian (2010)
10.1002/MASY.200690091
Swelling Behavior of N-t-butylacrylamide Copolymer and Terpolymers
Aysecik Kacmaz (2006)
10.1016/j.carbpol.2012.05.057
Biocomposite fiber of calcium alginate/multi-walled carbon nanotubes with enhanced adsorption properties for ionic dyes.
Kunyan Sui (2012)
10.1021/IE202859N
Applicability of New Acrylic, Weakly Basic Anion Exchanger Purolite A-830 of Very High Capacity in Removal of Palladium(II) Chloro-complexes
A. Wołowicz (2012)
10.1021/CM0202355
Adsorption of Chromate and Arsenate by Amino-Functionalized MCM-41 and SBA-1
H. Yoshitake (2002)
10.1016/J.DYEPIG.2006.01.014
Equilibrium sorption of anionic dye from aqueous solution by palm kernel fibre as sorbent
A. Ofomaja (2007)
10.1016/j.jhazmat.2008.11.047
Activated carbons prepared from wood particleboard wastes: characterisation and phenol adsorption capacities.
P. Girods (2009)
10.1016/j.jhazmat.2009.05.012
The study of adsorption characteristics Cu2+ and Pb2+ ions onto PHEMA and P(MMA-HEMA) surfaces from aqueous single solution.
O. Moradi (2009)
10.1016/j.jhazmat.2009.07.066
Adsorption behaviors of Hg(II) on chitosan functionalized by amino-terminated hyperbranched polyamidoamine polymers.
Fang Ma (2009)
10.1016/J.CEJ.2010.03.080
Extraction and recovery of precious metal ions in wastewater by polystyrene-coated magnetic particles functionalized with 2-(3-(2-aminoethylthio)propylthio)ethanamine
Kunawoot Jainae (2010)
10.1016/j.jcis.2012.07.034
Selective and effective adsorption of methyl blue by barium phosphate nano-flake.
Fan Zhang (2012)
10.1002/APP.23456
Preparation of polysulfone hollow fiber affinity membrane modified with mercapto and its recovery properties. II. Preparation of PSF‐SH hollow fiber affinity membrane for recovery of Hg2+
B. Wang (2006)
10.1021/la202267p
Different EDC/NHS activation mechanisms between PAA and PMAA brushes and the following amidation reactions.
Cuie Wang (2011)
10.1016/j.jhazmat.2013.01.056
Modification and characterization of PET fibers for fast removal of Hg(II), Cu(II) and Co(II) metal ions from aqueous solutions.
M. Monier (2013)
10.1016/j.jhazmat.2011.08.038
Synthesis of a novel silica-supported dithiocarbamate adsorbent and its properties for the removal of heavy metal ions.
L. Bai (2011)
10.1016/S0021-9797(02)00243-6
Behaviors and mechanisms of copper adsorption on hydrolyzed polyacrylonitrile fibers.
S. Deng (2003)
10.1023/A:1024906212586
Mercury pollution and remediation: the chemist's response to a global crisis
A. Hutchison (2003)
10.1002/APP.1989.070380313
Benzoyl‐peroxide‐initiated graft copolymerization of poly(ethylene terephthalate) fibers with acrylamide
M. Saçak (1989)
10.1016/J.JELECHEM.2005.01.044
The adsorption of thiourea on the mercury from neutral and acidic solutions of perchlorates
A. Nosal–Wiercińska (2005)
10.1016/j.jhazmat.2008.04.078
Characteristics of equilibrium, kinetics studies for adsorption of Hg(II), Cu(II), and Ni(II) ions by thiourea-modified magnetic chitosan microspheres.
L. Zhou (2009)
10.1002/APP.1979.070230723
Grafting onto polyester fibers. II. Kinetics of grafting of acrylic acid, acrylonitrile, and vinyl acetate onto polyester fibers
K. N. Rao (1979)
10.1016/j.jhazmat.2010.08.013
Preparation and characterization of chelating fibers based on natural wool for removal of Hg(II), Cu(II) and Co(II) metal ions from aqueous solutions.
M. Monier (2010)
10.1016/J.JHAZMAT.2006.08.001
Evaluation of Fuller's earth for the adsorption of mercury from aqueous solutions: a comparative study with activated carbon.
J. U. K. Oubagaranadin (2007)
10.1016/J.JCIS.2007.10.019
Adsorption of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) and related compounds onto montmorillonite clay.
N. Greesh (2008)
10.1002/1521-3773(20020816)41:16<2892::AID-ANIE2892>3.0.CO;2-6
Macromolecules containing bipyridine and terpyridine metal complexes: towards metallosupramolecular polymers.
U. Schubert (2002)
10.1021/IE9703954
Metal-Anion Sorption by Chitosan Beads: Equilibrium and Kinetic Studies
E. Guibal (1998)
10.1016/J.JIEC.2014.08.028
Adsorption of Hg(II) from aqueous solutions by thiol-functionalized polymer-coated magnetic particles
Kunawoot Jainae (2015)
10.1016/J.CEJ.2012.03.070
Preparation of new chelating fiber with waste PET as adsorbent for fast removal of Cu2+ and Ni2+ from water: Kinetic and equilibrium adsorption studies
J. Wang (2012)
10.1016/0039-9140(88)80104-8
Synthesis and analytical characterization of a chelating resin loaded with dithizone.
J. Chwastowska (1988)
10.1016/J.EURPOLYMJ.2005.08.018
Study of free-radical copolymerization of itaconic acid/2-acrylamido-2-methyl-1-propanesulfonic acid and their metal chelates
R. Coşkun (2006)
10.1002/APP.1982.070271021
Graft copolymerization of methyl methacrylate onto poly(ethylene terephthalate) fibers using thallium(III) ions as initiator
S. Misra (1982)
10.1016/j.talanta.2005.08.066
Preconcentration and speciation of inorganic and methyl mercury in waters using polyaniline and gold trap-CVAAS.
M. V. Balarama Krishna (2005)
10.1016/j.jhazmat.2014.09.042
Adsorption of anionic MO or cationic MB from MO/MB mixture using polyacrylonitrile fiber hydrothermally treated with hyperbranched polyethylenimine.
Y. Fan (2015)
10.1016/J.SEPPUR.2012.11.025
Application of Fered-Fenton and chemical precipitation process for the treatment of electroless nickel plating wastewater
Yu Jen Shih (2013)
10.1021/IE050145K
A Novel Amine-Shielded Surface Cross-Linking of Chitosan Hydrogel Beads for Enhanced Metal Adsorption Performance
N. Li (2005)
10.1021/ac951159a
Immobilization of crown ether carboxylic acids on silica gel and their use in column concentration of alkali metal cations from dilute aqueous solutions.
M. G. Hankins (1996)
10.1016/S0927-7757(00)00678-6
Characterization of metal ion interactions with chitosan by X-ray photoelectron spectroscopy
L. Dambies (2001)
10.1021/OM970388F
Carbonylation of Amines with a Tungsten(IV) Carbonyl Complex
J. E. McCusker (1997)
10.2174/1874846501003020016
Thiosemicarbazone Metal Complexes: From Structure to Activity~!2009-12-08~!2010-01-13~!2010-03-25~!
G. Pelosi (2010)
10.1007/S00289-003-0212-6
Kinetics of swelling assisted grafting of 4-vinyl pyridine onto poly(ethylene terephthalate) fibers using a benzoyl peroxide initiator
M. Arslan (2003)
10.1016/J.JHAZMAT.2005.07.049
Adsorption of acid dye onto organobentonite.
P. Baskaralingam (2006)
10.1016/J.ACA.2005.02.017
Highly selective determination of inorganic mercury(II) after preconcentration with Hg(II)-imprinted diazoaminobenzene-vinylpyridine copolymers
Y. Liu (2005)
10.1002/(SICI)1521-3773(19990315)38:6<771::AID-ANIE771>3.0.CO;2-V
Metal Complexes Bearing Terminal Borylene Ligands.
B. Wrackmeyer (1999)
10.1002/CHIN.201047228
Thiosemicarbazone Metal Complexes: From Structure to Activity
G. Pelosi (2010)
10.1002/PAT.1113
Competitive heavy metal removal by poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid‐co‐itaconic acid)
S. Çavuş (2008)
10.1002/APP.1988.070350211
Effect of graft copolymerization of 2‐hydroxyethyl methacrylate on the properties of polyester fibers and fabric
E. Abdel-Bary (1988)
10.1016/j.jhazmat.2008.11.074
Use of rice straw as biosorbent for removal of Cu(II), Zn(II), Cd(II) and Hg(II) ions in industrial effluents.
C. G. Rocha (2009)
10.1016/J.DESAL.2010.06.050
Adsorption of humic acid onto ultrafiltration membranes in the presence of protein and metal ions
E. Salehi (2010)
10.1016/J.MATLET.2011.02.006
Preparation and characterizations of antibacterial PET-based hollow fibers containing silver particles
L. Lin (2011)
10.1016/j.jhazmat.2009.11.034
Adsorption of Cu(II), Hg(II), and Ni(II) ions by modified natural wool chelating fibers.
M. Monier (2010)
10.1016/J.MEMSCI.2008.12.042
Influence of multivalent ions on power production from mixing salt and fresh water with a reverse electrodialysis system
J. W. Post (2009)
10.1016/J.WATRES.2004.09.027
Mercury removal from water using activated carbons derived from organic sewage sludge.
F. Zhang (2005)
10.1002/chem.201400175
Incorporating polyoxometalates into a porous MOF greatly improves its selective adsorption of cationic dyes.
Ai-Xue Yan (2014)
10.1002/APP.26351
Preparation of a heterogeneous hollow‐fiber affinity membrane modified with a mercapto chelating resin
B. Wang (2007)
10.1016/J.JENVMAN.2007.02.005
Use of an activated carbon from antibiotic waste for the removal of Hg(II) from aqueous solution.
T. Budinova (2008)
10.1021/am400427n
Design of polymer-brush-grafted magnetic nanoparticles for highly efficient water remediation.
Aleeza Farrukh (2013)
10.1021/JA972674O
Evaluation of Molybdenum−Sulfur Interactions in Molybdoenzyme Model Complexes by Gas-Phase Photoelectron Spectroscopy. The “Electronic Buffer” Effect
Barry L. Westcott (1998)
10.1021/LA000287D
Controlled and Reversible Formation of Nanoparticle Aggregates and Films Using Cu2+−Carboxylate Chemistry
A. Templeton (2000)
10.2166/WST.1992.0089
Removal of mercury from waste water: Large scale performance of an ion exchange process
J. Ritter (1992)
10.1016/J.APSUSC.2012.04.131
Adsorption of copper and nickel ions on macroporous chitosan membrane: Equilibrium study
Azadeh Ghaee (2012)
10.1016/S0022-2860(03)00147-9
Binding of Co(II) and Cu(II) cations to chemically modified wool fibres: an IR investigation
P. Taddei (2003)



This paper is referenced by
10.1016/J.MICROC.2018.01.028
Mercury(II) adsorption by a novel adsorbent mercapto-modified bentonite using ICP-OES and use of response surface methodology for optimization
T. Şahan (2018)
Fe 3 O 4 Nanoparticles as Efficient Material for the Adsorption of Mercury ( II ) from Water at Low Concentrations
Edgar Emir González (2019)
10.22059/POLL.2019.269364.540
Synthesis of Activated Carbon from Sugarcane Bagasse and Application for Mercury Adsorption
K. Alsadi (2019)
10.1007/s13726-019-00716-4
Hydrophilic thiourea-modified poly(acrylonitrile-co-acrylic acid) adsorbent: preparation, characterization, and dye removal performance
A. A. Adeyi (2019)
10.1016/J.ENMM.2019.100243
Adsorption kinetics, isotherms and desorption studies of mercury from aqueous solution at different temperatures on magnetic sodium alginate-thiourea microbeads
David Patiño-Ruiz (2019)
10.1002/PAT.4214
Preparation and characterization of polyphenylene sulfide–based chelating resin–functionalized 2‐amino‐1,3,4‐thiadiazole for selective removal Hg(II) from aqueous solutions
Gonglei Shao (2018)
10.1080/01932691.2018.1463243
Bioremoval of mercury (II) from aqueous solutions by Phragmites australis: Kinetic and equilibrium studies
Gökben Başaran Kankılıç (2018)
10.1016/j.jcis.2017.11.004
Preparation of ruthenium (III) ion-imprinted beads based on 2-pyridylthiourea modified chitosan.
M. Monier (2018)
10.1007/S13369-017-2438-X
Synthesis, Characterization, Electrical and Photocatalytic Studies of Polyacrylamide Zr(IV) Phosphosulphosalicylate, a Cation Exchanger: Its Application in the Removal of Hg (II) from Aqueous Solution
S. A. Ansari (2017)
10.1007/s11814-017-0116-z
Response surface approach for optimization of Hg(II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution
S. Yilmaz (2017)
10.1016/J.JECE.2019.103350
Sulphur functionalized materials for Hg(II) adsorption: A review
Tarisai Velempini (2019)
10.5004/DWT.2018.21850
The wheat straw biochar research on the adsorption/desorption behaviour of mercury in wastewater
Shici Zhang (2018)
10.1016/j.chemosphere.2018.12.099
Effect of nitric acid pre-oxidation concentration on pore structure and nitrogen/oxygen active decoration sites of ethylenediamine -modified biochar for mercury(II) adsorption and the possible mechanism.
Boyu Li (2019)
10.3390/molecules25112650
Simultaneous Adsorption of Malachite Green and Methylene Blue Dyes in a Fixed-Bed Column Using Poly(Acrylonitrile-Co-Acrylic Acid) Modified with Thiourea
A. A. Adeyi (2020)
10.1080/01496395.2018.1547313
Adsorption of Hg(II) in aqueous solution by magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids
Y. Ma (2019)
10.1016/j.micromeso.2019.109905
Experimental and DFT study on the selective adsorption mechanism of Au(III) using amidinothiourea-functionalized UiO-66-NH2
Minghu Zhao (2020)
Adsorption of Hg(II) Ions from Aqueous Solution by Thiosemicarbazide-modified Cellulose Adsorbent
Jiahao Jiang (2019)
10.1039/c9py01544b
Hyperbranched multiple polythioamides made from elemental sulfur for mercury adsorption
Akram Yasin (2020)
10.1016/j.apsusc.2019.143970
Removal of mercury by magnetic nanomaterial with bifunctional groups and core-shell structure: Synthesis, characterization and optimization of adsorption parameters
Zhenzong Zhang (2020)
Semantic Scholar Logo Some data provided by SemanticScholar