Online citations, reference lists, and bibliographies.
← Back to Search

Phosphate Removal From Water Using Freshly Formed Fe–Mn Binary Oxide: Adsorption Behaviors And Mechanisms

Jianbo Lu, Huijuan Liu, Xu Zhao, William A. Jefferson, F. Cheng, J. Qu
Published 2014 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Freshly formed metal oxide suspensions usually have high reactivity and are easy to achieve in-situ preparation and dosing in water treatment. In this study, a freshly formed Fe-Mn binary oxide (FMBO) suspension was prepared for phosphate removal using simultaneous oxidation and coprecipitation method. FMBO was characterized by SEM, TEM, XRD and zeta potential and compared with the mixture of ferric oxide and manganese oxides (FMMO), hydrous ferric oxide (HFO) and hydrous manganese oxide (HMO). Results indicated that ferric oxide was relatively enriched on the surface of nanostructured binary oxide, resulting in its pH(ZPC) and XRD pattern close to HFO. At pH 3-10, phosphate removals followed trend: FMBO g FMMO g HFO g HMO. The pseudo-second-order kinetics model provided a better fit for phosphate adsorption onto FMBO, indicating that chemisorption may play a dominant role. The maximum adsorption capacity estimated from the Langmuir equation was 0.223 mol-P/mol-Fe at pH 5.0. The competition effects of coexisting substances such as sulfate, bicarbonate, silicate and DOC on phosphate adsorption using FMBO were not significant. Phosphate adsorption onto FMBO could be attributed to electrostatic interaction and replacement of surface hydroxyl groups via formation of monodentate and bidentate complexes. (C) 2014 Elsevier B.V. All rights reserved.
This paper references
Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters
W. Stumm (1970)
The surface chemistry of soils
G. Sposito (1984)
Surface and bulk characteristics of binary oxide suspensions
P. Anderson (1990)
Effect of component oxide interaction on the adsorption properties of mixed oxides
X. Meng (1993)
Structure and Bonding of Orthophosphate Ions at the Iron Oxide-Aqueous Interface.
Persson (1996)
Effects of silicate, sulfate, and carbonate on arsenic removal by ferric chloride
X. Meng (2000)
Effects of dissolved carbonate on arsenate adsorption and surface speciation at the hematite--water interface.
Yuji Arai (2004)
Arsenate adsorption on an Fe-Ce bimetal oxide adsorbent: role of surface properties.
Y. Zhang (2005)
Phosphate adsorption by fresh and aged aluminum hydroxide. Consequences for lake restoration.
I. de Vicente (2008)
Individual and competitive adsorption of arsenate and phosphate to a high-surface-area iron oxide-based sorbent.
H. Zeng (2008)
Effect of silica and pH on arsenic uptake by resin/iron oxide hybrid media.
T. Möller (2008)
Temperature effect on the mechanism of phosphate anions sorption by β-MnO2
S. Mustafa (2008)
Adsorptive selenite removal from water using iron-coated GAC adsorbents.
N. Zhang (2008)
Arsenic removal using hydrous nanostructure iron(III)-titanium(IV) binary mixed oxide from aqueous solution.
K. Gupta (2009)
Development of polymer-based nanosized hydrated ferric oxides (HFOs) for enhanced phosphate removal from waste effluents.
B. Pan (2009)
Removal of arsenic from water: effects of competing anions on As(III) removal in KMnO4-Fe(II) process.
X. Guan (2009)
Removal of phosphate from water by a Fe-Mn binary oxide adsorbent.
G. Zhang (2009)
Chemical composition and discharge characteristics of γ-MnO2 prepared using manganese ore
H. Malankar (2009)
Influences of co-existing species on the sorption of toxic oxyanions from aqueous solution by nanocrystalline Mg/Al layered double hydroxide.
K. Goh (2010)
The oxidative transformation of sodium arsenite at the interface of alpha-MnO2 and water.
Xiu-Juan Li (2010)
Fluoride removal efficiency from aqueous solution by synthetic iron(III)–aluminum(III)–chromium(III) ternary mixed oxide
K. Biswas (2010)
Phosphate bonding on noncrystalline Al/Fe-hydroxide coprecipitates.
Yuting Liu (2011)
Iron and aluminium based adsorption strategies for removing arsenic from water.
Dion E Giles (2011)
Enhanced trace phosphate removal from water by zirconium(IV) loaded fibrous adsorbent.
M. R. Awual (2011)
Mn-Ce oxide as a high-capacity adsorbent for fluoride removal from water.
S. Deng (2011)
Comparison of low-cost and engineered materials for phosphorus removal from organic-rich surface water.
Treavor H. Boyer (2011)
Defluoridation by freshly prepared aluminum hydroxides
Ruiping Liu (2011)
Development of chemically engineered porous metal oxides for phosphate removal.
P. Delaney (2011)
Cd2+sorption characteristics of iron coated silica
M. Waseem (2011)

This paper is referenced by
Selective adsorption of phosphate in water using lanthanum-based nanomaterials: A critical review
M. Razanajatovo (2021)
Transformation of typical components in anaerobically digested sludge during its conditioning process by KMnO4
Shun Zhang (2021)
Tuning microscopic structure of Al-based metal-organic frameworks by changing organic linkers for efficient phosphorus removal
Shengjian Li (2021)
Advanced applications of green materials in nitrate, phosphate, and fluoride removal
R. Ollier (2021)
Preparation and Characterization of Fe-Mn Binary Oxide/Mulberry Stem Biochar Composite Adsorbent and Adsorption of Cr(VI) from Aqueous Solution
M. Liang (2020)
Improvement of Ultrafiltration for Treatment of Phosphorus-Containing Water by a Lanthanum-Modified Aminated Polyacrylonitrile Membrane
K. Koh (2020)
Study of orthophosphate detection method using DGT (diffusive gradients in thin films) device with modified binding layer Fe-chitosan-bentonite biocomposite in aquatic system
S. Andini (2020)
Phosphorus retention using iron (II/III) modified biochar in saline-alkaline soils: Adsorption, column and field tests.
Lipeng Wu (2020)
Fabrication of zirconium(IV) cross-linked alginate/kaolin hybrid beads for nitrate and phosphate retention
Ilango Aswin Kumar (2020)
Adsorptive removal of phosphate by a Fe–Mn–La tri-metal composite sorbent: Adsorption capacity, influence factors, and mechanism
Yuanrong Zhu (2020)
Investigation into lanthanum-coated biochar obtained from urban dewatered sewage sludge for enhanced phosphate adsorption.
J. Li (2020)
Assessing the suitability of solid aggregates for nutrient recovery from aqua systems
T. D. Saliu (2020)
Synthesis, application and mechanisms of Ferro-Manganese binary oxide in water remediation: A review
Yaoning Chen (2020)
Preparation of Tetraethylenepentamine‐Functionalized 4A Zeolite for effective removal of phosphate in water
Qingqing Guan (2020)
Mechanistic insights into effect of storage conditions of Fe-Mn co-oxide filter media on their catalytic properties in ammonium-nitrogen and manganese oxidative removal
Yanxun Cheng (2020)
Study of orthophosphate uptake by diffusive gradient in thin film (DGT) system with Co-loaded chitosan bentonite biocomposite binding gel and the effect of its anion interferences on the phosphate response
P. Sitadevi (2020)
Hydrothermally synthesized lanthanum carbonate nanorod for adsorption of phosphorus: Material synthesis and optimization, and demonstration of excellent performance
K. Koh (2020)
Dephosphorization using ceramsites modified by coprecipitation with FeSo4 and KMnO4 and high-temperature combustion
Linjun Wu (2020)
Layered double hydroxide modified biochar combined with sodium alginate: A powerful biomaterial for enhancing bioreactor performance to remove nitrate.
Zhijie Zheng (2020)
Simultaneous removal of iron and manganese from acid mine drainage by acclimated bacteria.
Dongmei Hou (2020)
An innovative lanthanum carbonate grafted microfibrous composite for phosphate adsorption in wastewater.
Y. Yang (2019)
Enhanced removal of lead ions from aqueous solution by iron oxide nanomaterials with cobalt and nickel doping
Weihong Chen (2019)
PO43− adsorption in a complex solution by nickel–cobalt hydroxide, and its cytotoxicity on bovine aortic endothelial cells
Fumihiko Ogata (2019)
Adsorptive removal of phosphate from aqueous solutions by thermally modified copper tailings
Runjuan Zhou (2019)
Investigating adsorption mechanism and surface complex formation modeling for aqueous sulfadiazine bonding on Fe/Mn binary oxides
J. Yu (2019)
Development of Magnetic Particles Encrusted LDH-Admixed Biopolymeric Complex Beads for Selective Phosphate Remediation
Ilango Aswin Kumar (2019)
Corncob-supported aluminium-manganese binary oxide composite enhanced removal of cadmium ions
Liuchun Zheng (2019)
Synthesis of a novel Fe-Mn binary oxide modified lava adsorbent and its effect on ammonium removal from aqueous solutions.
Ziyi Zhao (2019)
Synthesis of a novel magnetic Caragana korshinskii biochar/Mg–Al layered double hydroxide composite and its strong adsorption of phosphate in aqueous solutions
Qingliang Cui (2019)
Removal of Tetracycline by Hydrous Ferric Oxide: Adsorption Kinetics, Isotherms, and Mechanism
Ji Zang (2019)
Facile synthesis of Al/Fe bimetallic (oxyhydr)oxide-coated magnetite for efficient removal of fluoride from water
Haoyang Fu (2019)
Highly selective adsorption of vanadium (V) by nano-hydrous zirconium oxide-modified anion exchange resin.
Min Li (2019)
See more
Semantic Scholar Logo Some data provided by SemanticScholar