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Graphite-like Carbon Nitride And Functionalized Layered Double Hydroxide Filled Polypropylene-grafted Maleic Anhydride Nanocomposites: Comparison In Flame Retardancy, And Thermal, Mechanical And UV-shielding Properties

Yongqian Shi, Z. Gui, B. Yu, R. Yuen, Bi-bo Wang, Yuan Hu
Published 2015 · Materials Science

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Abstract Graphite-like carbon nitride (g-C 3 N 4 ) and borate modified layered double hydroxides (LDH-B) were successfully fabricated by thermal pyrolysis and modified aqueous miscible organic solvent treatment methods, respectively. Then these nano-additives were introduced to prepare polypropylene-grafted maleic anhydride (PP-g-MA)/g-C 3 N 4 and PP-g-MA/LDH-B nanocomposites using a modified solvent mixing strategy. Several important parameters of the nanocomposites including thermal, mechanical and UV-blocking properties were investigated. Results indicated that pure g-C 3 N 4 exhibited 347.6 and 427.2 °C increase in onset decomposition temperature under air and nitrogen conditions, respectively, compared with LDH-B. In case of PP-g-MA nanocomposites, both T -10 and T -50 (the temperature at 10% and 50% weight loss, respectively) were improved by 14.6 and 27.7 °C, respectively, by the addition of g-C 3 N 4 while those only increased by 2.3 and 17.8 °C upon introducing LDH-B. Furthermore, PP-g-MA/g-C 3 N 4 system showed a remarkable increment (9.8 °C) in crystallization temperature while an increase of 4.2 °C for PP-g-MA/LDH-B nanocomposite. Introducing g-C 3 N 4 and LDH-B into PP-g-MA led to a reduction of 28% and 19% in pHRR, respectively. It was noted that the incorporation of g-C 3 N 4 caused significant improvement in storage modulus from 2445.0 MPa for neat PP-g-MA to 2783.5 MPa for PP-g-MA/g-C 3 N 4 while that of PP-g-MA/LDH-B was dramatically decreased by 27.3%. Optical results indicated that PP-g-MA/g-C 3 N 4 was rendered fascinating UV adsorption ability relative to PP-g-MA/LDH-B. It is expected that the novel two-dimensional nanomaterial could bring new creativity into polymer composites.
This paper references
10.1016/J.APSUSC.2012.06.088
Functionalization of layered double hydroxides by intumescent flame retardant: Preparation, characterization, and application in ethylene vinyl acetate copolymer
Guobo Huang (2012)
10.1039/c0cc01432j
Graphitic carbon nitride as a metal-free catalyst for NO decomposition.
J. Zhu (2010)
10.1016/J.POLY.2011.01.012
Polymeric nanocomposite materials: Preparation and characterization of star-shaped PbS nanocrystals
M. Salavati-Niasari (2011)
10.1021/am4044932
Influence of g-C3N4 nanosheets on thermal stability and mechanical properties of biopolymer electrolyte nanocomposite films: a novel investigation.
Yongqian Shi (2014)
10.1016/J.POLYMDEGRADSTAB.2010.08.007
Preparation and burning behaviors of flame retarding biodegradable poly(lactic acid) nanocomposite based on zinc aluminum layered double hydroxide
D. Wang (2010)
10.1021/CM950319W
Synthesis and Characterization of Tetraborate Pillared Hydrotalcite
L. Li (1996)
10.1021/CM0110268
Polymer Interleaved Layered Double Hydroxide: A New Emerging Class of Nanocomposites
Fabrice Leroux and (2001)
10.1039/C2RA20189E
Structural characteristics and flammability of fire retarding EPDM/layered double hydroxide (LDH) nanocomposites
D. Wang (2012)
10.1016/J.POLYMDEGRADSTAB.2008.04.002
Synergistic effect of ammonium polyphosphate and layered double hydroxide on flame retardant properties of poly(vinyl alcohol)
Chun-Xia Zhao (2008)
10.1021/CM901238A
One-Step Synthesis of Organic LDH and Its Comparison with Regeneration and Anion Exchange Method
D. Wang (2009)
10.1039/C0JM03784B
Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler
A. Das (2011)
10.1039/c1cc10250h
Polymer composites of carbon nitride and poly(3-hexylthiophene) to achieve enhanced hydrogen production from water under visible light.
H. Yan (2011)
10.1016/J.COMPOSITESB.2014.11.027
Functionalized graphene sheets filled isotactic polypropylene nanocomposites
F. Qiu (2015)
10.1021/MA401133S
Synthesis of Flame-Retardant Polypropylene/LDH-Borate Nanocomposites
Qiang Wang (2013)
10.1016/J.JSSC.2004.07.024
Intercalation behavior of amino acids into Zn–Al-layered double hydroxide by calcination–rehydration reaction
S. Aisawa (2004)
10.1016/J.JIEC.2013.12.042
Sonochemical synthesis of La(OH)3 nanoparticle and its influence on the flame retardancy of cellulose acetate nanocomposite
P. Jamshidi (2014)
10.1038/nmat2317
A metal-free polymeric photocatalyst for hydrogen production from water under visible light.
X. Wang (2009)
10.1016/J.JALLCOM.2010.12.138
Preparation and investigation of the combustion behavior of polypropylene/organomodified MgAl-LDH micro-nanocomposite
D. Wang (2011)
10.1002/asia.200900685
Photocurrent generation by polymeric carbon nitride solids: an initial step towards a novel photovoltaic system.
Yuanjian Zhang (2010)
10.1002/anie.200906920
Biologically inspired, strong, transparent, and functional layered organic-inorganic hybrid films.
H. Yao (2010)
10.1002/ASIA.201090016
Cover Picture: Photocurrent Generation by Polymeric Carbon Nitride Solids: An Initial Step towards a Novel Photovoltaic System (Chem. Asian J. 6/2010)
Yuanjian Zhang (2010)
10.1016/J.POLYMER.2009.01.031
Preparation and nonisothermal crystallization behavior of polypropylene/ layered double hydroxide nanocomposites
S. Lonkar (2009)
10.1039/C3RA44256J
Facile preparation of ZnS/g-C3N4 nanohybrids for enhanced optical properties
Yongqian Shi (2014)
10.1021/la102449m
Synthesis of organo cobalt-aluminum layered double hydroxide via a novel single-step self-assembling method and its use as flame retardant nanofiller in PP.
De-Yi Wang (2010)
10.1021/CM0002057
Efficient Separation of Terephthalate and Phthalate Anions by Selective Ion-Exchange Intercalation in the Layered Double Hydroxide Ca2Al(OH)6·NO3·2H2O
F. Millange (2000)
10.1016/S0169-1317(99)00023-X
Surface and interfacial properties of polymer-intercalated layered double hydroxide nanocomposites
O. Wilson (1999)
10.1039/c3cc42918k
Large-scale synthesis of highly dispersed layered double hydroxide powders containing delaminated single layer nanosheets.
Q. Wang (2013)
10.1039/C3TA00035D
Self-assembly of Ni–Fe layered double hydroxide/graphene hybrids for reducing fire hazard in epoxy composites
X. Wang (2013)
10.1016/J.JIEC.2014.09.043
Synthesis of urchin-like CdS-Fe3O4 nanocomposite and its application in flame retardancy of magnetic cellulose acetate
D. Ghanbari (2015)
10.1016/J.COMPOSITESB.2013.06.018
Solvothermal synthesis of carbon nanostructure and its influence on thermal stability of poly styrene
Hamid Reza Shams (2013)
10.1002/anie.201209017
Nanostructure engineering and doping of conjugated carbon nitride semiconductors for hydrogen photosynthesis.
Zhenzhen Lin (2013)
10.1039/C2TA01069K
Facile fabrication of magnetically separable graphitic carbon nitride photocatalysts with enhanced photocatalytic activity under visible light
Sheng Ye (2013)
10.1016/J.COMPOSITESB.2012.04.006
Influence of mesoporous fillers with PP-g-MA on flammability and tensile behavior of polypropylene composites
N. Wang (2013)
10.1016/J.POLYMDEGRADSTAB.2010.03.003
Thermal degradation behaviors of a novel nanocomposite based on polypropylene and Co–Al layered double hydroxide
D. Wang (2011)
10.1002/APP.28159
Effects of vinyltrimethoxy silane on thermal properties and dynamic mechanical properties of polypropylene–wood flour composites
R. Bouza (2008)
10.1016/J.CEMCONRES.2009.08.013
Fundamental mechanisms for polycarboxylate intercalation into C3A hydrate phases and the role of sulfate present in cement
J. Plank (2010)
10.1021/ja308249k
Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging.
Xiaodong Zhang (2013)
10.1039/C0EE00064G
CO2 capture by solid adsorbents and their applications: current status and new trends
Q. Wang (2011)
10.1021/JP301026Y
Nitrogen Vacancy-Promoted Photocatalytic Activity of Graphitic Carbon Nitride
Ping Niu (2012)
10.1016/J.COMPOSITESB.2013.08.010
Effect of crystallite size of zinc oxide on the mechanical, thermal and flow properties of polypropylene/zinc oxide nanocomposites
Saisy Kudilil Esthappan (2015)
10.1016/J.COMPOSITESB.2014.09.033
Mechanical and thermal properties of carbon fiber/polypropylene composite filled with nano-clay
Mohamed H. Gabr (2015)
10.1016/S1003-6326(09)60055-8
Self-assembling organomodified Co/Al based layered double hydroxides (LDH) via one-step route
D. Wang (2009)
10.1016/J.CLAY.2013.11.002
Combination effects of graphene and layered double hydroxides on intumescent flame-retardant poly(methyl methacrylate) nanocomposites
Guobo Huang (2014)
10.1002/chem.200800190
Ionothermal synthesis of crystalline, condensed, graphitic carbon nitride.
Michael J Bojdys (2008)
10.1016/J.APCATB.2010.11.036
Fabrication and photocatalytic performance of a ZnxCd1−xS solid solution prepared by sulfuration of a single layered double hydroxide precursor
X. Xu (2011)
10.1016/J.ICA.2011.02.020
Polymeric nanocomposite materials: Synthesis and thermal degradation of acrylonitrile–butadiene–styrene/tin sulfide (ABS/SnS)
Mohammad Yousefi (2011)
10.1021/CS300240X
Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis
X. Wang (2012)
10.1007/s10856-009-3792-3
Improved adherence and spreading of Saos-2 cells on polypropylene surfaces achieved by surface texturing and carbon nitride coating
Katja Myllymaa (2009)
10.1039/C0JM01211D
Bionanocomposites based on alginate–zein/layered double hydroxide materials as drug delivery systems
A. Alcántara (2010)
10.1021/IE404115G
Bioinspired Nacre-like Heparin/Layered Double Hydroxide Film with Superior Mechanical, Fire-Shielding, and UV-Blocking Properties
Yingqi Shu (2014)
10.1039/C3RA44452J
Polypropylene/Mg3Al–tartrazine LDH nanocomposites with enhanced thermal stability, UV absorption, and rheological properties
Q. Wang (2013)
10.1016/J.POLYMDEGRADSTAB.2007.07.009
LDPE/Mg–Al layered double hydroxide nanocomposite: Thermal and flammability properties
F. Costa (2007)
10.1002/anie.201101182
Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry.
Yong Wang (2012)
10.1021/ja310849c
Two-dimensional mesoporous carbon nanosheets and their derived graphene nanosheets: synthesis and efficient lithium ion storage.
Y. Fang (2013)
10.1002/anie.200903886
Synthesis of a carbon nitride structure for visible-light catalysis by copolymerization.
J. Zhang (2010)



This paper is referenced by
10.1007/s11244-020-01359-z
Synthesis and Photocatalytic Activity of Ni–Fe Layered Double Hydroxide Modified Sulphur Doped Graphitic Carbon Nitride (SGCN/Ni–Fe LDH) Photocatalyst for 2,4-Dinitrophenol Degradation
Vasudha Hasija (2020)
10.3390/nano7090259
Hypophosphite/Graphitic Carbon Nitride Hybrids: Preparation and Flame-Retardant Application in Thermoplastic Polyurethane
Yongqian Shi (2017)
10.1002/pat.4894
Synergistic effect of flame retardants and graphitic carbon nitride on flame retardancy of polylactide composites
X. Cao (2020)
10.1021/acsami.8b11299
Rapid Synthesis of Oxygen-Rich Covalent C2N (CNO) Nanosheets by Sacrifice of HKUST-1: Advanced Metal-Free Nanofillers for Polymers.
Y. Hou (2018)
10.1016/J.COMPOSITESB.2018.12.035
Effects of tension rates and filler size on tensile properties of polypropylene/graphene nano-platelets composites
J. Liang (2019)
10.1080/01496395.2017.1398759
Comparative studies of functionalized polyacrylamide/graphite composites for the removal of direct blue 2b from aqueous solution
Gayathri Kumarasamy (2018)
10.1016/J.CLAY.2017.05.048
Improving flame retardancy of IFR/PP composites through the synergistic effect of organic montmorillonite intercalation cobalt hydroxides modified by acidified chitosan
Q. Kong (2017)
10.1016/j.clay.2020.105600
Intercalation of a novel containing nitrogen and sulfur anion into hydrotalcite and its highly efficient flame retardant performance for polypropylene
S. Xu (2020)
10.1002/app.48598
Mechanical and thermal performances of epoxy resin/graphitic carbon nitride composites
Yuhao Qi (2020)
10.1177/0021998317746478
Effects of graphene nano-platelets size and content on tensile properties of polypropylene composites at higher tension rate
J. Liang (2018)
10.1016/J.COMPOSITESB.2017.11.060
An insight into the interaction between functionalized thermoplastic elastomer and layered double hydroxides through rheological investigations
R. Arrigo (2018)
10.1002/MAME.201700407
Preparation of Novel Fluorinated Copolyimide/Amine‐Functionalized Sepia Eumelanin Nanocomposites with Enhanced Mechanical, Thermal, and UV‐Shielding Properties
Q. Li (2018)
10.1016/J.COMPOSITESB.2016.04.011
Tensile properties of graphene nano-platelets reinforced polypropylene composites
J. Liang (2016)
10.1002/PAT.4693
Metal‐organic framework MIL‐53 (Fe)@C/graphite carbon nitride hybrids with enhanced thermal stability, flame retardancy, and smoke suppression for unsaturated polyester resin
Z. Chen (2019)
10.1016/J.MATCHEMPHYS.2016.04.029
Synergistic effect of graphitic carbon nitride and ammonium polyphosphate for enhanced thermal and flame retardant properties of polystyrene
Yongqian Shi (2016)
10.1039/c9mh01497g
Graphitic carbon nitride and polymers: a mutual combination for advanced properties
Q. Cao (2020)
10.1016/j.pmatsci.2020.100687
Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants
Wentao He (2020)
10.1016/J.COMPOSITESB.2018.10.003
High temperature resistant polyimide/boron carbide composites for neutron radiation shielding
Li Xiaomin (2019)
10.3390/polym12010076
A New Filler for Epoxy Resin: Study on the Properties of Graphite Carbon Nitride (g-C3N4) Reinforced Epoxy Resin Composites
T. Wang (2020)
10.1016/J.CEJ.2019.122267
Strengthening, toughing and thermally stable ultra-thin MXene nanosheets/polypropylene nanocomposites via nanoconfinement
Y. Shi (2019)
10.1002/mame.202000231
Significantly Strengthening Epoxy by Incorporating Carbon Nanotubes/Graphitic Carbon Nitride Hybrid Nanofillers
Bo Song (2020)
10.1016/J.COMPOSITESB.2019.107068
Facile fabrication of a novel polyborosiloxane-decorated layered double hydroxide for remarkably reducing fire hazard of silicone rubber
Jiedong Qiu (2019)
10.1016/J.CARBON.2016.06.019
Characterization of urea derived polymeric carbon nitride and resultant thermally vacuum deposited amorphous thin films: Structural, chemical and photophysical properties
A. Lazauskas (2016)
10.1021/ACS.IECR.6B01237
Processable dispersions of graphitic carbon nitride based nanohybrids and application in polymer nanocomposites
Yongqian Shi (2016)
10.1016/J.POLYMDEGRADSTAB.2018.05.027
Low molecular weight hindered amine light stabilizers (HALS) intercalated MgAl-Layered double hydroxides: Preparation and anti-aging performance in polypropylene nanocomposites
Q. Zhang (2018)
10.1021/acsami.6b07909
Synthesis of Spherical Carbon Nitride-Based Polymer Composites by Continuous Aerosol-Photopolymerization with Efficient Light Harvesting.
Jalal Poostforooshan (2016)
10.1002/PC.24826
Impact fracture behavior and morphology of polypropylene/graphene nanoplatelets composites
J. Liang (2019)
10.1155/2019/4273253
Nanoreinforcements of Two-Dimensional Nanomaterials for Flame Retardant Polymeric Composites: An Overview
Shaolin Lu (2019)
10.1039/c9dt00111e
UV absorber co-intercalated layered double hydroxides as efficient hybrid UV-shielding materials for polypropylene.
Ruoyu Ma (2019)
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