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Electrochemical Properties Of TiP2O7 And LiTi2(PO4)3 As Anode Material For Lithium Ion Battery With Aqueous Solution Electrolyte

Haibo Wang, Ke‐long Huang, Yuqun Zeng, Saiyu Yang, Li-quan Chen
Published 2007 · Chemistry

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Abstract Some polyanionic compounds, e.g. TiP 2 O 7 and LiTi 2 (PO 4 ) 3 with 3D framework structure were proposed to be used as anodes of lithium ion battery with aqueous electrolyte. The cyclic voltammetry properties TiP 2 O 7 and LiTi 2 (PO 4 ) 3 suggested that Li-ion de/intercalation reaction can occur without serious hydrogen evolution in 5 M LiNO 3 aqueous solution. The TiP 2 O 7 and LiTi 2 (PO 4 ) 3 give capacities of about 80 mAh/g between potentials of −0.50 V and 0 V (versus SHE) and 90 mAh/g between −0.65 V and −0.10 V (versus SHE), respectively. A test cell consisting of TiP 2 O 7 /5 M LiNO 3 /LiMn 2 O 4 delivers approximately 42 mAh/g (weight of cathode and anode) at average voltage of 1.40 V, and LiTi 2 (PO 4 ) 3 /5 M LiNO 3 /LiMn 2 O 4 delivers approximately 45 mAh/g at average voltage of 1.50 V. Both as-assembled cells suffered from short cycle life. The capacity fading may be related to deterioration of anode material.
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