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Solid Phase Photopolymerization Of Pyrrole In Poly(vinylchloride) Matrix

A. W. Rinaldi, Marcos H. Kunita, M. L. Santos, E. Radovanovic, A. F. Rubira, E. M. Girotto
Published 2005 · Materials Science

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Electrically conductive films were obtained by solid phase photopolymerization of pyrrole (Py) into a poly(vinylchloride) (PVC) matrix. We attempted to characterize the structure, electrochemical and thermal properties, and morphology of the resulting polypyrrole/PVC blend. The blend obtained has low conductivity and rather poor electroactivity due to the loss of conjugation length of polypyrrole (PPy) provoked by halogenation. Micrographs of cryofracture surface suggested two distinct phases, and thermogravimetric analysis revealed a low thermal stability of the blend. On the basis of our experimental results, we propose a reaction mechanism that explains the PPy formation in solid phase induced by UV light.
This paper references
10.1016/S0378-7753(03)00594-9
Characteristics of tantalum electrolytic capacitors using soluble polypyrrole electrolyte
Kwan Sik Jang (2003)
10.1039/A706386E
Conducting polymer image formation with photoinduced electron transfer reaction
N. Kobayashi (1998)
10.1016/S0151-9107(03)00008-4
Caractérisation des mélanges PVC-PMMA rigides et plastifiés. I - Étude de la miscibilité
N. Belhaneche-Bensemra (2003)
10.1016/S0378-7753(03)00669-4
Fabrication of microcapacitors using conducting polymer microelectrodes
Joo-Hwan Sung (2003)
10.1039/C39890000657
Photochemical deposition of electrically conducting polypyrrole
Jean-Marc Kern (1989)
10.1063/1.1609241
Study of ammonia-gas-induced irreversibility in polypyrrole films
Jaewu Choi (2003)
10.1016/S0378-7753(03)00736-5
Electrochemical behavior of the polypyrrole/polyimide composite by potential step amperometry
Kirill L. Levine (2003)
10.1016/S0169-4332(02)00938-8
Deposition of copper sulfide on modified low-density polyethylene surface: morphology and electrical characterization
Marcos H. Kunita (2002)
10.1016/S0378-7753(03)00730-4
A modified Nafion membrane with in situ polymerized polypyrrole for the direct methanol fuel cell
M. Smit (2003)
10.1016/S0379-6779(00)00537-3
Electrical, magnetic, and structural properties of chemically and electrochemically synthesized polypyrroles
J. Joo (2001)
10.1016/S0379-6779(02)00086-3
Conductivity of de-doped poly(3,4-ethylenedioxythiophene)
Tomas Johansson (2002)
10.1016/B978-012513745-4/50082-2
Optical devices based on conductive polymers
W. Gazotti (2001)
10.1016/S0040-6090(96)09577-6
Morphology and microstructure of polypyrrole formed by electrochemical polymerization
J. Shan (1997)
10.1002/1616-3028(20020201)12:2<89::AID-ADFM89>3.0.CO;2-1
Electrochromic Window Based on Conducting Poly(3,4‐ethylenedioxythiophene)–Poly(styrene sulfonate)
Helmut Werner Dr. Heuer (2002)
10.1039/C39890000132
A novel photo-sensitized polymerization of pyrrole
H. Segawa (1989)
10.1016/S0013-4686(01)00419-4
High coloration efficiency electrochromics and their application to multi-color devices
R. D. Rauh (2001)
10.1016/S0379-6779(02)00107-8
An electronic tongue using polypyrrole and polyaniline
A. Riul (2003)
10.1016/S0925-4005(03)00445-3
Multicomponent analysis of Korean green tea by means of disposable all-solid-state potentiometric electronic tongue microsystem
L. Lvova (2003)
10.1016/S0927-0248(00)00397-4
Solid-state photoelectrochemical cell using a polythiophene derivative as photoactive electrode
W. Gazotti (2001)
10.1021/JP994440S
Photoelectrochemical Properties of Poly(3,4-ethylenedioxythiophene)
E. M. Girotto (2000)
10.1590/S0103-50531999000500010
Flexible electrochromic windows: a comparison using liquid and solid electrolytes
E. M. Girotto (1999)
10.1080/10101329208052162
Photopolymerization of Pyrrole Initiated by the Ferrocene- and Iron-Arene Salts-Chlorinated Solvents Complexes
J. Rabek (1992)
10.1016/S0009-2614(02)00651-6
Theoretical investigation of the nature of the ground state in the low-bandgap conjugated polymer, poly(3,4-ethylenedioxythiophene)
A. Dkhissi (2002)
10.1002/APP.1359
Structural, mechanical, and electrical properties of electropolymerized polypyrrole composite films
N. Bhat (2001)
10.1016/S0379-6779(01)00404-0
Electrochemical synthesis of polypyrrole films over each of well-aligned carbon nanotubes
J. Chen (2001)
10.1016/S0167-2738(01)00813-X
Poly(ethylene oxide-co-epichlorohydrin)/NaI: a promising polymer electrolyte for photoelectrochemical cells
A. Nogueira (2001)
10.1016/S0379-6779(98)00184-2
Interpenetrating polymer network composites of polypyrrole and poly(vinyl acetate)
M. Chakraborty (1999)
10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
Poly(3,4‐ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future
L. Groenendaal (2000)
10.1016/S0379-6779(01)00576-8
Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents
J. Kim (2002)
10.1002/APP.12492
Conducting polymer blends of polypyrrole with polyvinyl acetate, polystyrene, and polyvinyl chloride based toxic gas sensors
S. Hosseini (2003)
10.1103/PHYSREVB.56.5207
FRACTAL ANALYSIS OF THE PERCOLATION NETWORK IN EPOXY-POLYPYRROLE COMPOSITES
Jéro⁁me Fournier (1997)
10.1002/PAT.259
A Synopsis of recent attempts toward construction of rechargeable batteries utilizing conducting polymer cathodes and anodes
M. Levi (2002)
10.1080/10601328808055088
Transparent, Electrically Conductive Composites Derived from Polypyrrole and Poly[Vinyl Chloride) by Vapor-Phase Polymerization: Effect of Environment on Polymerization and Reaction Mechanism
T. Ueno (1988)



This paper is referenced by
10.1002/cptc.202000212
Advances in the Synthesis of π‐Conjugated Polymers by Photopolymerization
Eliot F. Woods (2020)
10.1016/J.SNB.2012.04.027
A selective DMSO gas sensor based on nanostructured conducting polypyrrole doped with sulfonate anion
S. Pirsa (2012)
10.1039/C7NJ00678K
A novel methodology for fabrication of Ag–polypyrrole core–shell nanosphere using microemulsion system and evaluation of its antibacterial application
A. Salabat (2017)
10.1016/J.POLYMER.2015.05.060
Hybrid assemblies by pyrrole polymerization on nano graphene oxide platelets
S. Percec (2015)
10.1002/ELAN.201600089
Nanostructured Conducting Polymer/Copper Oxide as a Modifier for Fabrication of L‐DOPA and Uric Acid Electrochemical Sensor
Mohammad Ali Sheikh-Mohseni (2016)
10.1016/J.APSUSC.2009.08.060
Synthesis and characterization of silver-polypyrrole film composite
M. Ayad (2009)
10.1002/VNL.21319
Coating of poly(vinyl chloride) nanoparticles with a conductive polyaniline in the presence of various surfactants
Z. Vatani (2013)
10.1007/s10854-013-1681-5
Deposition of electrically conductive ceria/polypyrrole nanocomposite particles on flexible polyethylene naphthalate film via in situ photo-induced polymerization
Hamid Reza Heydarnezhad (2013)
10.1002/APP.25912
Morphology, structure, and conductivity of polypyrrole prepared in the presence of mixed surfactants in aqueous solutions
S. Xing (2007)
10.1007/S00289-006-0663-7
Morphology and thermostability of polypyrrole prepared from SDBS aqueous solution
S. Xing (2006)
10.1088/1361-665X/AB35F1
Fabrication of 3D Conjugated Polymer Structures via Vat Polymerization Additive Manufacturing
Andrew T. Cullen (2019)
10.1002/ELAN.201300231
Gas Sensing Ability of a Nanostructured Conducting Polypyrrole Film Prepared by Catalytic Electropolymerization on Cu/Au Interdigital Electrodes
N. Alizadeh (2013)
10.15407/HFTP07.01.073
Structure and morphology of polypyrrole films chemically deposited on the polyethylene terephthalate substrates
Mykhaylo Yatsyshyn (2016)
10.1117/12.2260350
Fabrication of multilayered conductive polymer structures via selective visible light photopolymerization
Andrew T. Cullen (2017)
10.1016/J.POLYMER.2012.09.029
Bromide-doped polypyrrole microcapsules modified with gold nanoparticles
Krystyna Kijewska (2012)
10.1016/J.MATLET.2007.04.067
Direct synthesis of PbS/polypyrrole core-shell nanocomposites based on octahedral PbS nanocrystals colloid
S. Jing (2008)
10.1002/9783527819249.ch10
Surface Modification of Polymeric Substrates with Photo‐ and Sonochemically Designed Macromolecular Grafts
Fatima Mousli (2019)
10.1016/J.SYNTHMET.2015.08.004
Photopolymerization of pyrrole/methacrylate mixtures using α-cleavage type photoinitiators in combination with iodonium salt
Silvana Asmussen (2015)
10.1016/B978-1-895198-85-0.50007-8
5 – PRINCIPLES OF UV DEGRADATION
G. Wypych (2015)
10.1002/POLA.26328
In situ polymerization and morphology of polypyrrole obtained in water‐soluble polymer templates
S. Percec (2012)
10.1002/ADMI.201701593
Fabrication of pyrrole-based electrochemical biosensor platform using nanoimprint lithography
J. Ahn (2018)
10.1016/J.MATLET.2007.02.045
Synthesis and characterization of Ag/polypyrrole nanocomposites based on silver nanoparticles colloid
S. Jing (2007)
10.1002/polb.24893
3D printing of conjugated polymers
R. S. Jordan (2019)
10.1007/s10854-013-1413-x
One-step synthesis of conductive ceria/polypyrrole nanocomposite particles via photo-induced polymerization method
Hamid Reza Heydarnezhad (2013)
10.2478/s11696-011-0120-4
Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation
M. Omastová (2012)
10.1007/s11581-012-0762-4
Preparation of Si-PPy-Ag composites and their electrochemical performance as anode for lithium-ion batteries
J. Yao (2012)
10.1016/J.SYNTHMET.2014.09.005
Template free method for the synthesis of Ag–PPy core–shell nanospheres with inherent colloidal stability
Abhijit D Suryawanshi (2014)
10.1080/03602559.2017.1370111
Conducting Electroactive Polymers via Photopolymerization: A Review on Synthesis and Applications
Hamid Reza Heydarnezhad (2018)
10.1016/J.POLYMER.2013.08.034
Pyrrole polymerization on polyimide surfaces creates conductive nano-domains
S. Percec (2013)
10.22090/JWENT.2017.04.004
Kinetic and Isotherm Studies of Cadmium Adsorption on Polypyrrole/Titanium dioxide Nanocomposite
Marjan Tanzifi (2017)
10.1007/S10853-008-2905-6
Preparation and characterization of Pt-polypyrrole nanocomposite for electrochemical reduction of oxygen
Liu Ji-wei (2008)
10.1016/J.SYNTHMET.2017.11.003
Digital light processing for the fabrication of 3D intrinsically conductive polymer structures
Andrew T. Cullen (2018)
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