Online citations, reference lists, and bibliographies.
← Back to Search

Synthesis And Characterization Of Microporous Carbon Nitride

L. Liu, Ding Ma, H. Zheng, Xiujie Li, M. Cheng, X. Bao
Published 2008 · Materials Science

Cite This
Download PDF
Analyze on Scholarcy
Share
Abstract This research reports the preparation and characterization of amorphous microporous carbon nitride using HZSM-5 zeolite as template, and ethidene diamine and carbon tetrachloride as chemical precursors. Microporous amorphous carbon nitride is generated by removal of HZSM-5 zeolite in the obtained zeolite/carbon nitride composite using hydrofluoric acid after carbonization the precursor inside the channels of zeolite. The microporous carbon nitride was characterized by nitrogen sorption techniques, scanning electron microscopy, elemental analysis, X-ray diffraction, X-ray photoelectron spectroscopy, IR spectroscopy, Ultraviolet–visible spectroscopy, Raman spectroscopy, and thermo-gravimetric analysis. Amorphous microporous carbon nitride with high surface area and narrow pore size distribution is thermal stable under atmosphere conditions up to 700 K.
This paper references
10.1002/ADMA.200401756
Synthesis of g-C3N4 Nanoparticles in Mesoporous Silica Host Matrices†
Matthijs Groenewolt (2005)
10.1021/CM960430H
Formation of New Type of Porous Carbon by Carbonization in Zeolite Nanochannels
T. Kyotani (1997)
10.1002/ADMA.19970090805
B/C/N Materials Based on the Graphite Network
M. Kawaguchi (1997)
10.1016/S0008-6223(99)00142-6
Control of pore structure in carbon
T. Kyotani (2000)
10.1126/science.261.5119.334
Experimental Realization of the Covalent Solid Carbon Nitride
C. Niu (1993)
10.1557/JMR.2002.0072
Synthesis of superhard and elastic carbon nitride films by filtered cathodic vacuum arc combined with radio frequency ion beam source
Y. H. Cheng (2002)
10.1021/CM9703278
Effect of Micropore Topology on the Structure and Properties of Zeolite Polymer Replicas
S. A. Johnson (1997)
10.1002/ADMA.200305307
Unique single-crystalline beta carbon nitride nanorods
Longwei Yin (2003)
10.1021/JP0029663
Templated Synthesis of Carbon Materials from Zeolites (Y, Beta, and ZSM-5) and a Montmorillonite Clay (K10): Physical and Electrochemical Characterization
C. J. Meyers (2001)
10.1016/S0925-9635(01)00467-8
Mechanosynthesis of carbon nitride compounds
M. Alcalá (2001)
10.1002/ADMA.200401643
Preparation and Characterization of Well‐Ordered Hexagonal Mesoporous Carbon Nitride
A. Vinu (2005)
10.1039/B307086G
Chemical synthesis of turbostratic carbon nitride, containing C-N crystallites, at atmospheric pressure.
Y. Qiu (2003)
10.1039/B303210H
Formation of crystalline carbon nitride powder by a mild solvothermal method
Q. Lv (2003)
10.1021/JP046142N
Mesostructured Hollow Spheres of Graphitic N-Doped Carbon Nanocast from Spherical Mesoporous Silica
Yongde Xia (2004)
10.1016/S0925-9635(00)00276-4
Raman spectroscopy measurements of DC-magnetron sputtered carbon nitride (a-C:N) thin films for magnetic hard disk coatings
M. Neuhaeuser (2000)
10.1116/1.580190
Reactive magnetron sputter deposited CNx: Effects of N2 pressure and growth temperature on film composition, bonding, and microstructure
W. Zheng (1996)
10.1126/science.245.4920.841
Prediction of New Low Compressibility Solids
A. Liu (1989)
10.1016/S0040-6090(97)00420-3
Preparation of carbon nitride thin films by ion beam assisted deposition and their mechanical properties
M. Kohzaki (1997)
10.1007/BF02711178
Influence of N atomic percentages on cell attachment for CNx coatings
D. Li (2003)
10.1021/BA-1995-0245
Materials Chemistry: An Emerging Discipline
L. V. Interrante (1995)
10.1016/S0008-6223(03)00090-3
Template synthesis of novel porous carbons using various types of zeolites
T. Kyotani (2003)
10.1126/SCIENCE.282.5390.897
Carbon structures with three-dimensional periodicity at optical wavelengths
Zakhidov (1998)
10.1063/1.113114
Reactive pulsed laser deposition of CNx films
X. Zhao (1995)
10.1021/CM000328R
Powder synthesis and characterization of amorphous carbon nitride, a-C3N4
V. Khabashesku (2000)
10.1002/1521-4095(200105)13:9<677::AID-ADMA677>3.0.CO;2-C
Ordered mesoporous carbons
R. Ryoo (2001)
10.1063/1.119562
Fabrication of amorphous-carbon-nitride field emitters
E. Chi (1997)
10.1016/S0925-9635(98)00283-0
Nano-carbon nitride synthesis from a bio-molecular target for ion beam sputtering at low temperature
J. Wu (1999)
10.1021/CM970552P
Structural and Textural Properties of Pyrolytic Carbon Formed within a Microporous Zeolite Template
J. Rodríguez-Mirasol (1998)
10.1016/S0169-4332(01)00356-7
Influence of NHn+ beam bombarding energy on structural characterization and cell attachment of CNx coating
D. Li (2001)
10.1103/PHYSREVB.49.5034
Observation of crystalline C3N4.
Yu. (1994)
10.1016/J.CARBON.2004.06.028
Synthesis and characterization of microporous carbons templated by ammonium-form zeolite Y
F. Su (2004)
10.1016/J.MSEB.2005.05.007
A facile mechanochemical way to prepare g-C3N4
H. Zhao (2005)
10.1021/JA048939Y
Synthesis and structure of 2,5,8-triazido-s-heptazine: an energetic and luminescent precursor to nitrogen-rich carbon nitrides.
D. R. Miller (2004)
10.1039/B311390F
Synthesis of carbon nitride nanotubes with the C(3)N(4) stoichiometry via a benzene-thermal process at low temperatures.
Q. Guo (2004)
10.1103/PHYSREVLETT.75.1336
Superhard and elastic carbon nitride thin films having fullerenelike microstructure.
Sjöström (1995)
10.1016/S0040-6090(98)01072-4
Carbon nitride thin films prepared by nitrogen ion assisted pulsed laser deposition of graphite using KrF excimer laser
K. Yamamoto (1999)
10.1002/ANIE.200600412
Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for Friedel-Crafts reaction of benzene.
F. Goettmann (2006)
10.1039/B311541K
Synthesis of new nanoporous carbon materials using nanostructured silica materials as templates
J. Lee (2004)
10.1039/B109700H
Rapid, facile synthesis of nitrogen-rich carbon nitride powders
D. R. Miller (2002)
10.1103/PHYSREVLETT.73.118
Carbon nitride deposited using energetic species: A two-phase system.
Marton. (1994)
10.1002/ANIE.200461758
Preparation of nitrogen-rich nanolayered, nanoclustered, and nanodendritic carbon nitrides.
M. Huynh (2005)
10.1021/JA984406B
Theoretical Tracing of a Novel Route from Molecular Precursors through Polymers to Dense, Hard C3N4 Solids
P. Kroll (1999)
10.1021/CM001160C
Hardening Mechanisms in Graphitic Carbon Nitride Films Grown with N2/Ar Ion Assistance
R. Gago (2001)
10.1063/1.1419034
Lithium storage in polymerized carbon nitride nanobells
D. Y. Zhong (2001)
10.1021/CM9601289
High-Pressure Synthesis of sp2-Bonded Carbon Nitrides
D. C. Nesting (1996)



This paper is referenced by
10.1016/J.CERAMINT.2014.12.145
Novel magnetically separable g-C3N4/AgBr/Fe3O4 nanocomposites as visible-light-driven photocatalysts with highly enhanced activities
Anise Akhundi (2015)
10.3390/CATAL7040099
Fivefold Enhanced Photoelectrochemical Properties of ZnO Nanowire Arrays Modified with C3N4 Quantum Dots
Hao Yang (2017)
10.1039/C2JM34965E
Enhanced visible-light photocatalytic activity of g-C3N4–ZnWO4 by fabricating a heterojunction: investigation based on experimental and theoretical studies
Liming Sun (2012)
10.1080/09593330.2019.1646323
Microwave-assisted fabrication of g-C3N4 nanosheets sustained Bi2S3 heterojunction composites for the catalytic reduction of 4-nitrophenol.
D. Ayodhya (2019)
10.1039/C1RA00249J
Acid-driven, microwave-assisted production of photoluminescent carbon nitride dots from N,N-dimethylformamide
S. Liu (2011)
10.1016/J.MATCHEMPHYS.2018.08.019
Boron carbonitride sheet/ Cu2O composite for an efficient photocatalytic hydrogen evolution
S. Kalimuthu (2018)
10.1016/J.MICROMESO.2017.03.046
Photocatalytic degradation of Rhodamine B over a novel mesoporous titanosilicate/g-C3N4 nanocomposite under direct sunlight irradiation
Ajay Kumar Adepu (2017)
10.1016/J.CERAMINT.2016.01.086
Template-free method for synthesizing sponge-like graphitic carbon nitride with a large surface area and outstanding nitrogen photofixation ability induced by nitrogen vacancies
G. Wu (2016)
10.1007/S11434-016-1053-7
Enhanced visible-light photocatalytic activity of a g-C3N4/m-LaVO4 heterojunction: band offset determination
Xiaoping Liu (2016)
10.1039/c7cp05334g
Polysulfide intercalation in bilayer-structured graphitic C3N4: a first-principles study.
S. Li (2017)
FTIR-DTA Studies of Ultradisrersed C–N System’s Crystalline Phases
A. Sivkov (2010)
10.1007/s10008-014-2563-3
Preparation and enhanced visible light photoelectrochemical activity of g-C3N4/ZnO nanotube arrays
J. Wang (2014)
10.1039/C5TA05002B
Visible light-driven novel g-C3N4/NiFe-LDH composite photocatalyst with enhanced photocatalytic activity towards water oxidation and reduction reaction
Susanginee Nayak (2015)
10.1039/c7dt01029j
Syntheses of asymmetric zinc porphyrins bearing different pseudo-pyridine substituents and their photosensitization for visible-light-driven H2 production activity.
Y. Zheng (2017)
10.1016/j.jhazmat.2014.01.021
Graphitic-C(3)N(4)-hybridized TiO(2) nanosheets with reactive {001} facets to enhance the UV- and visible-light photocatalytic activity.
Liuan Gu (2014)
10.1016/J.APCATB.2013.09.039
Significantly enhancement of photocatalytic performances via core-shell structure of ZnO@mpg-C3N4
D. Chen (2014)
10.1039/b919918g
Tackling the stacking disorder of melon--structure elucidation in a semicrystalline material.
L. Seyfarth (2010)
10.1149/2.0671803JES
A Facile Construction of Porous g-C3N4/poly(3,4-ethylenedioxythiophene) Composite Modified Electrode for Ascorbic Acid Determination
Yuting Wu (2018)
10.1016/J.JPCS.2016.08.008
Preparation of graphitic carbon nitride with large specific surface area and outstanding N 2 photofixation ability via a dissolve-regrowth process
H. Ma (2016)
10.1007/s10853-015-8865-8
In-situ synthesis of CdS/g-C3N4 hybrid nanocomposites with enhanced visible photocatalytic activity
Zhang L. Fang (2015)
10.1016/J.ELECTACTA.2012.03.102
Modification of TiO2 nanorod arrays by graphite-like C3N4 with high visible light photoelectrochemical activity
J. Wang (2012)
10.1039/c6nr09137g
Solvothermal-assisted synthesis of self-assembling TiO2 nanorods on large graphitic carbon nitride sheets with their anti-recombination in the photocatalytic removal of Cr(vi) and rhodamine B under visible light irradiation.
Dingze Lu (2017)
10.1038/s41598-020-69578-8
Graphitic carbon nitride/graphene nanoflakes hybrid system for electrochemical sensing of DNA bases in meat samples
J. Kalaiyarasi (2020)
10.1016/j.colsurfa.2020.125107
Trace samarium doped graphitic carbon nitride photocatalytic activity toward metanil yellow dye degradation under visible light irradiation
Ngonidzashe Masunga (2020)
10.1016/S1872-2067(16)62561-5
Enhanced photochemical oxidation ability of carbon nitride by π–π stacking interactions with graphene
Q. Hao (2017)
10.1016/J.JALLCOM.2019.06.350
Z-scheme mpg-C3N4/Ag6Si2O7 heterojunction for highly efficient photocatalytic degradation of organic pollutants under visible light
Shengnan Jin (2019)
10.1007/s41664-017-0024-6
Recent Advances in Graphitic Carbon Nitride-Based Chemiluminescence, Cataluminescence and Electrochemiluminescence
Hongjie Song (2017)
10.1039/c4dt02658f
Band gap-tunable potassium doped graphitic carbon nitride with enhanced mineralization ability.
Shaozheng Hu (2015)
10.1016/J.APCATA.2012.07.034
Sulfonic groups functionalized preoxidated polyacrylonitrile nanofibers and its catalytic applications
Linjun Shao (2012)
10.1016/J.APCATB.2014.11.050
Visible light photoactivity enhancement via CuTCPP hybridized g-C3N4 nanocomposite
D. Chen (2015)
10.1039/c8pp00077h
Fluorescence response from the surface states of nitrogen-doped carbon nanodots: evidence of a heterogeneous population of molecular-sized fluorophores.
Nabaruna Basu (2019)
10.1039/c8an00895g
A novel "signal-on" photoelectrochemical sensor for ultrasensitive detection of alkaline phosphatase activity based on a TiO2/g-C3N4 heterojunction.
F. Wang (2018)
See more
Semantic Scholar Logo Some data provided by SemanticScholar