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Synthesis Of New Silylated Sulfur-containing Heterocycles Through Thionation Of Bis(acylsilanes)

Jean-Philippe Bouillon, A. Capperucci, C. Portella, A. Degl'innocenti
Published 2004 · Chemistry

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Abstract The thionation of bis(acylsilanes) with spacers of variable size with hexamethyldisilathiane under cobalt(II) chloride or trimethylsilyl triflate catalysis affords 2,5-bis(trialkylsilyl)-thiophenes, 2,6-bis(trialkylsilyl)-4H-thiopyrans and 2,7-bis(trialkylsilyl)-4,5-dihydrothiepine generally along with a minor amount of the corresponding oxo analogue. The synthesis of both symmetrical and unsymmetrical bis(trialkylsilyl) derivatives was achieved.
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