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Selective Growth Of Conjugated Polymer Thin Films By The Vapor Deposition Polymerization

T. Yoshimura, N. Terasawa, Hayato Kazama, Yoshimi Naito, Y. Suzuki, K. Asama
Published 2006 · Materials Science

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Abstract We present a selective growth technique for polymer thin films using patterned hydrophobic/hydrophilic surface treatments. On a glass substrate surface, where a hydrophobic treatment was applied using hexamethyl–disilazane, a hydrophilic SiO thin film was deposited through a metal mask by the vacuum evaporation to form a hydrophilic/hydrophobic pattern. A poly-azomethine (poly-AM) film that is a conjugated polymer was grown on the surface by the vapor deposition polymerization using p -phenylenediamine and terephthalaldehyde as reactive source monomers. The poly-AM thin film was selectively grown on the SiO region, that is, on the hydrophilic region, without growth on the hydrophobic region.
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