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Raman Spectroscopy Of The Acetates Of Sodium, Potassium And Magnesium At Liquid Nitrogen Temperature

R. Frost, J. T. Kloprogge
Published 2000 · Chemistry

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Abstract A comprehensive Raman spectroscopic study of the acetates of potassium, sodium and magnesium in the solid state have been made at both 298 and 77 K. Band separation of the CO stretching region was not achieved in the 298 K spectra but was in the 77 K spectra. The CO stretching vibration is observed as a single band in both the 298 and 77 K spectra and its frequency is cation dependent. Single C–C stretching bands are observed for the acetates in the 77 K spectra. The OCO deformation vibrations were also cation dependent. Low frequency vibrations of magnesium acetate are observed at 338, 253 and 268 cm −1 and are assigned to the MgO stretching vibration of the magnesium bisacetato complex. Low frequency bands were also observed for sodium acetate at 219, 277 and 288 cm −1 .
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