Online citations, reference lists, and bibliographies.
← Back to Search

Practical NMR Analysis Of Morphology And Structure Of Polymers

T. Yamanobe, Hiroki Uehara, Masaki Kakiage
Published 2010 · Materials Science

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract Practical analytical methods to investigate the relationship between polymer morphology and properties by a combination of 1 H pulse NMR and/or high-resolution NMR in the solid state with other techniques, such as electron microscopy, X-ray diffraction and so on, are reviewed. The complete free induction decay (FID) fitting method by exponential, Weibullian and Weibullian/sine function is introduced. Applications of this method to polyethylenes prepared by various conditions successfully explain the morphology and physical properties. Crystallisation mechanism of nylon 46 by high-resolution NMR in the solid state is also introduced.
This paper references
10.1021/MA9911187
Chain Mobility in Polymer Systems: On the Borderline between Solid and Melt. 3. Phase Transformations in Nascent Ultrahigh Molecular Weight Polyethylene Reactor Powder at Elevated Pressure As Revealed by in Situ Raman Spectroscopy
L. Kurelec (2000)
10.1002/pol.1977.180150506
Proton magnetic resonance studies of the phase structure of bulk‐crystallized linear polyethylene
R. Kitamaru (1977)
10.1103/PHYSREVB.10.822
Free-inducation-decay measurements and determination of moments in Ca F 2
M. Engelsberg (1974)
10.1016/S0032-3861(00)00911-3
Lamellar characteristics controlled by prior polymer concentration for solution-crystallized ultra-high molecular weight polyethylene
Hiroki Uehara (2001)
10.1126/SCIENCE.288.5463.116
Chain mobility in the amorphous region of nylon 6 observed under active uniaxial deformation
Lôo (2000)
10.1021/MA990080V
Deuterium nuclear magnetic resonance of phenol-d5 in nylon 6 under active uniaxial deformation
L. S. Loo (1999)
10.1021/MA50007A032
Pulsed NMR studies of crystalline-state extrusion of high-density polyethylene
M. Ito (1981)
10.1021/JP984539J
PHASE DISTRIBUTION DURING ISOTHERMAL CRYSTALLIZATION OF POLYETHYLENE PROBED BY SOLID-STATE PROTON NMR FREE INDUCTION DECAY
P. E. Kristiansen (1999)
10.1021/MA00180A032
Super-drawing of ultrahigh molecular weight polyethylene. 1. Effect of techniques on drawing of single crystal mats
T. Kanamoto (1988)
10.1021/MA010408W
Effects of Molecular Structure on Segment Orientation in Poly(diethylsiloxane) Elastomers. 2. NMR Measurements from Uniaxially Stretched Samples
R. Hedden (2001)
10.1016/S0032-3861(00)00254-8
The morphology of nascent and moulded ultra-high molecular weight polyethylene. Insights from solid-state NMR, nitric acid etching, GPC and DSC
J. Cook (2000)
10.1016/S0032-3861(98)00102-5
Structural characterization of ultrahigh-molecular-weight polyethylene reactor powders based on fuming nitric acid etching
Hiroki Uehara (1998)
10.1063/1.1746878
Nuclear Resonance Absorption in Hydrated Crystals: Fine Structure of the Proton Line
G. Pake (1948)
10.1007/BF01466665
Three component model of molecular dynamics in polyethylene melts —a nuclear magnetic relaxation study
R. Kimmich (1980)
10.1016/J.MOLSTRUC.2006.06.010
Structure and characterization of nylon 46
T. Yamanobe (2007)
10.1063/1.1727249
Nuclear Magnetic Resonance Study of Molecular Motions in Solid Hydrogen Sulfide
D. Look (1966)
10.1016/J.POLYMER.2007.10.018
In situ SAXS analysis of extended-chain crystallization during melt-drawing of ultra-high molecular weight polyethylene
Masaki Kakiage (2007)
10.1016/S0032-3861(98)00864-7
Microscopically viewed structural change of PE during the isothermal crystallization from the melt: II. Conformational ordering and lamellar formation mechanism derived from the coupled interpretation of time-resolved SAXS and FTIR data
S. Sasaki (1999)
10.1021/AR00068A002
Carbon-13 NMR chemical shifts and the microstructure of polymers
A. Tonelli (1981)
10.1002/CHIN.200023299
NMR Spectroscopy in Polymer Science
I. Ando (2000)
10.1002/POL.1978.130160705
Entanglement effects on the NMR spin-spin relaxation in polyethylene melts
R. Folland (1978)
10.1002/POL.1981.180190514
Ultradrawing of high-molecular-weight polyethylene cast from solution. II.Influence of initial polymer concentration
P. Smith (1981)
10.1002/POL.1975.180131013
The morphology of ultradrawn polyethylene. I. Nitric acid etching plus gel permeation chromatography
N. E. Weeks (1975)
10.1016/0032-3861(83)90025-3
Strongly entangled polymer chains in a melt. Description of n.m.r. properties associated with a submolecule model
J. Cohen-Addad (1983)
10.1021/MA047390K
Local order in liquid n-alkanes evidence from Raman spectroscopic study
L. Brambilla (2005)
10.1021/MA0608424
Stress-Induced Crystallization and Reinforcement in Filled Natural Rubbers: 2H NMR Study
J. Rault (2006)
10.1007/BF00255130
Determination of polymer crystallinity from proton solid-echo NMR measurements
K. Bergmann (1981)
10.1021/JP981753Z
Crystallinity of Polyethylene Derived from Solid-State Proton NMR Free Induction Decay
E. Hansen (1998)
10.1021/MA00113A029
Variable-Temperature Solid-State 13C NMR Studies of Nascent and Melt-Crystallized Polyethylene
F. G. Morin (1995)
10.1021/MA051232R
Crystal Modifications and Thermal Behavior of Poly(l-lactic acid) Revealed by Infrared Spectroscopy
J. Zhang (2005)
10.1016/c2009-0-21335-3
Multidimensional Solid-State Nmr and Polymers
K. Schmidt-Rohr (1994)
10.1021/CR60239A001
The Entanglement Concept in Polymer Systems
R. Porter (1966)
10.1007/BFB0117530
NMR-Studies of semicrystalline polymers using pulse techniques
W. Klüver (1978)
10.1016/0032-3861(91)90098-4
Morphological changes on annealing polyethylene single crystals
S. J. Spells (1991)
10.1107/S0021889878013485
Recent developments in polymer applications of small-angle neutron, X-ray and light scattering
J. S. Higgins (1978)
10.1002/POL.1970.110081012
On the size of the primary particles in ziegler catalysts
R. L. Graff (1970)
10.1016/0014-3057(79)90235-0
Effect of previous history on the NMR relaxation of polyethylene
R. Folland (1979)
10.1016/0032-3861(94)90579-7
Solid-state 1H n.m.r. studies of polypropylene
D. Dadayli (1994)
10.1007/BF01410466
Meßverfahren zur Untersuchung der Protonen-Spin-Spin-Relaxation ein und zweiphasiger Polymerer in einem Zeitbereich von fünf Dekaden
K. Bergmann, (1984)
10.1016/S0168-3659(02)00038-X
Experimental Methods in Polymer Science
B. Narasimhan (2002)
10.1002/POL.1981.180190508
NMR spin–spin relaxation in solid and molten polyethylene structures
I. Kamel (1981)
10.1002/(SICI)1097-4628(19971010)66:2<377::AID-APP18>3.0.CO;2-V
Relation between molecular orientation and mechanical properties in differently processed Polyamide 4.6/6 textile yarns
G. Schmack (1997)
Solid state NMR of polymers
安藤 勲 (1998)
10.1002/MARC.200800316
Novel in situ NMR Measurement System for Evaluating Molecular Mobility during Drawing from Highly Entangled Polyethylene Melts
Masaki Kakiage (2008)
10.1007/978-3-662-08982-8
NMR Spectroscopy of Polymers
K. Hatada (2004)
10.1103/PHYSREV.73.679
Relaxation Effects in Nuclear Magnetic Resonance Absorption
N. Bloembergen (1948)
10.1002/POLB.20883
Effects of molecular characteristics and processing conditions on melt‐drawing behavior of ultrahigh molecular weight polyethylene
Masaki Kakiage (2006)
10.1021/MA010464X
Solid-State 1H NMR Relaxation Analysis of Ultrahigh Molecular Weight Polyethylene Reactor Powder
Hiroki Uehara (2002)
High molecular weight polyethylene: an n.m.r. approach to partial crystallinity and swelling properties of thermoreversible gels
J. P. Cohen-Addad (1987)
10.1063/1.3057238
The Principles of Nuclear Magnetism
A. Abragam (1961)
10.1002/MARC.200600199
Phase Development Mechanism during Drawing from Highly Entangled Polyethylene Melts
Hiroki Uehara (2006)
10.1002/POLB.1987.090251010
Proton NMR relaxation and molecular motion of long-chain cyclic paraffins in the solid state
M. Takenaka (1987)
10.1016/0014-3057(94)90226-7
On the importance of diffusion of cocatalyst molecules through heterogeneous ziegler/natta catalysts
G.A.H. Nooijen (1994)
10.1007/BF01410349
Melt drawing as a route to high performance polyethylene
Z. Bashir (1989)
10.1016/J.POLYMER.2003.09.048
Structure and dynamics in the amorphous region of natural rubber observed under uniaxial deformation monitored with solid-state 13C NMR
T. Kameda (2003)
10.1021/MA9918957
Relationship between Solid-State Molecular Motion and Morphology for Ultrahigh Molecular Weight Polyethylene Crystallized under Different Conditions
Hiroki Uehara (2000)
10.1063/1.451850
Study of crystallization process of polymer from melt by a real-time pulsed NMR measurement
H. Tanaka (1986)
10.1021/MA991330A
Structure Development upon Melt Drawing of Ultrahigh Molecular Weight Polyethylene: Effect of Prior Thermal History
M. Nakae (2000)
10.1021/MA981491Z
Melt Drawability of Ultrahigh Molecular Weight Polyethylene
Hiroki Uehara (1999)
10.1016/J.POLYMER.2006.07.073
Transient crystallization during drawing from ultra-high molecular weight polyethylene melts having different entanglement characteristics
Masaki Kakiage (2006)
10.1021/MA00231A036
Small-angle neutron scattering studies on amorphous polystyrene oriented by solid-state coextrusion
G. Hadziioannou (1982)
10.1016/S0032-3861(99)00091-9
Phase distribution in polyethylene versus temperature probed by solid-state proton NMR free induction decay
P. E. Kristiansen (2000)
10.1002/(SICI)1099-0488(19990801)37:15<1921::AID-POLB16>3.0.CO;2-M
Melt drawing of ultra‐high molecular weight polyethylene: Comparison of Ziegler‐ and metallocene‐catalyzed reactor powders
M. Nakae (1999)
10.1002/POL.1978.180160907
Study of the molecular motions of polyethylene by line‐shape analysis of broad‐line proton NMR spectra
K. Bergmann (1978)



This paper is referenced by
10.1002/mrc.4866
Exploring the crystallinity of different powder sugars through solid echo and magic sandwich echo sequences
L. Grunin (2019)
10.1021/co200210c
Spatially resolved solid-state 1H NMR for evaluation of gradient-composition polymeric libraries.
J. Leisen (2012)
10.1021/MA400093W
New Phosphonate-Based Additives for Fortification in Model Epoxies
Christoph F. Kins (2013)
10.1016/j.ssnmr.2019.101637
Crystallinity of polyolefins with large side groups by low-field 1H NMR T2 relaxometry: Isotactic Polybutene-1 with form II and I crystals.
Yanan Qin (2019)
10.1016/B978-0-12-809453-2.00003-7
Experimental Techniques for Understanding Polymer Crystallization
N. Murthy (2018)
Design, development of a novel transdermal drug delivery system as wound dressing.
S. Manivannan (2012)
10.1021/ACS.MACROMOL.5B00475
Simple NMR Experiments Reveal the Influence of Chain Length and Chain Architecture on the Crystalline/Amorphous Interface in Polyethylenes
Arifuzzaman Tapash (2015)
10.1002/MACP.201200715
Compressed Exponential Response Function Arising From a Continuous Distribution of Gaussian Decays – Distribution Characteristics
E. W. Hansen (2013)
10.1515/epoly-2021-0004
Synthesis of highly branched water-soluble polyester and its surface sizing agent strengthening mechanism
Wangwang Duan (2020)
10.1134/S0965545X18040090
Oscillating Free Induction Decay in Polymer Systems: Theoretical Analysis
E. M. Pestryaev (2018)
10.1134/S0006350917020087
An NMR relaxation and spin diffusion study of cellulose structure during water adsorption
L. Grunin (2017)
Анализ компонентного состава и свойств тяжёлых нефтей in situ
В. Я. Волков (2018)
Semantic Scholar Logo Some data provided by SemanticScholar