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Formation And Evaluation Of Self-assembled Monolayers Derived From Conjugated Silylthiophene Derivatives

Nami Choi, T. Ishida, A. Inoue, W. Mizutani, H. Tokumoto
Published 1999 · Materials Science

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We synthesized soluble rod-like silylthiophene, silylbithiophene, and silylquaterthiophene derivatives with various functional groups. Their self-assembled monolayer films on silicon oxide were evaluated by atomic force microscopy, X-ray photoelectron spectroscopy, water contact angle measurements, and fourier transform infrared-reflection absorption spectroscopy. We found that the molecular density (molecules/area) of the resultant films increased with thiophene moiety. This is probably due to the effective π-stacking of aromatic rings between molecules.
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