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Electrochemical Preparation And Electrochromic Characteristics Of Dithienopyrrole-dithienothiophene, Dithienopyrrole-thionaphtheneindole And Dithienothiophene-thionaphtheneindole Copolymers

G. Beggiato, G. Casalbore-Miceli, A. Geri, A. Berlin, G. Pagani
Published 1996 · Chemistry

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Abstract Poly(dithienopyrrole-dithienothiophene) copolymers can be obtained as good conducting electrode films by electrolytic oxidation of acetonitrile solutions of monomer mixtures (electrolyte: tetrabutylammonium perchlorate). They show good electrochromic characteristics. Films of poly(dithienopyrrole-thionaphtheneindole) and poly(dithienothiophene-thionaphtheneindole) copolymers can be obtained in the same way as the previous ones. They are adherent to the electrodes but are insulating and non-electrochromic; the reason for this behaviour is proposed to be the break of conjugation in the polymeric chain due to the thionaphtheneindole moiety.
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