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Dissipation And Adsorption Of Isoproturon, Tebuconazole, Chlorpyrifos And Their Main Transformation Products Under Laboratory And Field Conditions.

E. Papadopoulou, P. Karas, S. Nikolaki, V. Storck, F. Ferrari, M. Trevisan, G. Tsiamis, F. Martin-Laurent, D. Karpouzas
Published 2016 · Chemistry, Medicine

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Assessment of dissipation constitutes an integral part of pesticides risk assessment since it provides an estimate of the level and the duration of exposure of the terrestrial ecosystem to pesticides. Within the frame of an overall assessment of the soil microbial toxicity of pesticides, we investigated the dissipation of a range of dose rates of three model pesticides, isoproturon (IPU), tebuconazole (TCZ), and chlorpyrifos (CHL), and the formation and dissipation of their main transformation products following a tiered lab-to-field approach. The adsorption of pesticides and their transformation products was also determined. IPU was the least persistent pesticide showing a dose-dependent increase in its persistence in both laboratory and field studies. CHL dissipation showed a dose-dependent increase under laboratory conditions and an exact opposite trend in the field. TCZ was the most persistent pesticide under lab conditions showing a dose-dependent decrease in its dissipation, whereas in the field TCZ exhibited a biphasic dissipation pattern with extrapolated DT90s ranging from 198 to 603.4days in the ×1 and ×2 dose rates, respectively. IPU was demethylated to mono- (MD-IPU) and di-desmethyl-isoproturon (DD-IPU) which dissipated following a similar pattern with the parent compound. CHL was hydrolyzed to 3,5,6-trichloro-2-pyridinol (TCP) which dissipated showing a reverse dose-dependent pattern compared to CHL. Pesticides adsorption affinity increased in the order IPU
This paper references
10.1007/978-1-4614-1463-6_3
Adsorption and desorption of chlorpyrifos to soils and sediments.
Seyoum Y. Gebremariam (2012)
10.1039/JR9600003973
786. Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids
C. H. Giles (1960)
10.1080/03067319.2013.814122
Pesticide residues in groundwaters and soils of agricultural areas in the Águeda River Basin from Spain and Portugal
S. Sánchez-González (2013)
10.1016/j.chemosphere.2009.09.020
Characterization of an isoproturon mineralizing bacterial culture enriched from a French agricultural soil.
S. Hussain (2009)
10.1016/J.CHEMOSPHERE.2005.12.004
Effects of temperature and water content on degradation of isoproturon in three soil profiles.
L. Alletto (2006)
10.1007/s10311-015-0513-7
Chlorpyrifos: pollution and remediation
E. John (2015)
10.1016/j.scitotenv.2016.01.151
Effect of different rates of spent mushroom substrate on the dissipation and bioavailability of cymoxanil and tebuconazole in an agricultural soil.
Alba Álvarez-Martín (2016)
10.1016/J.EJSOBI.2015.12.005
Individual and combined effects of tebuconazole and carbendazim on soil microbial activity
C. Wang (2016)
10.1016/S0045-6535(01)00193-X
Biotransformation of phenylurea herbicides by a soil bacterial strain, Arthrobacter sp. N2: structure, ecotoxicity and fate of diuron metabolite with soil fungi.
C. Tixier (2002)
10.1016/J.JHYDROL.2013.01.025
Occurrence of pesticides and some of their degradation products in waters in a Spanish wine region
E. Herrero-Hernández (2013)
10.2134/jeq2008.0162
Influence of different organic amendments on the leaching and dissipation of terbuthylazine in a column and a field study.
Christina Dolaptsoglou (2009)
10.1016/j.ecoenv.2011.04.023
Field-scale dissipation of tebuconazole in a vineyard soil amended with spent mushroom substrate and its potential environmental impact.
E. Herrero-Hernández (2011)
10.1016/S0269-7491(00)00092-0
Spatial variability in the degradation rate of isoproturon in soil.
A. Walker (2001)
10.1002/ps.4092
The dissipation of fipronil, chlorpyrifos, fosthiazate and ethoprophos in soils from potato monoculture areas: first evidence for the enhanced biodegradation of fosthiazate.
E. Papadopoulou (2016)
10.1080/15320383.2013.733448
Tebuconazole Sorption in Contrasting Soil Types
Eva Čadková (2013)
10.1023/A:1011902012131
Biodegradation of the Phenylurea Herbicide Isoproturon and its Metabolites in Agricultural Soils
S. R. Sørensen (2004)
10.1071/SR02062
Contrasting behaviour of chlorpyrifos and its primary metabolite, TCP (3,5,6-trichloro-2-pyridinol), with depth in soil profiles
S. Baskaran (2003)
10.1021/JF0115443
Fate of 14C-labeled soybean and corn pesticides in tropical soils of Brazil under laboratory conditions
V. Laabs (2002)
10.1016/0038-0717(95)00099-2
Mineralization of free and cell-wall-bound isoproturon in soils in relation to soil microbial parameters
S. Lehr (1996)
10.1016/J.SOILBIO.2014.04.022
A tiered assessment approach based on standardized methods to estimate the impact of nicosulfuron on the abundance and function of the soil microbial community
D. Karpouzas (2014)
10.1016/j.chroma.2012.08.014
High performance liquid chromatography-tandem mass spectrometry method for quantifying phenylurea herbicides and their main metabolites in amended and unamended soils.
J. Fenoll (2012)
10.1094/PDIS-09-14-0993-RE
Baseline Sensitivity of Didymella bryoniae to Cyprodinil and Fludioxonil and Field Efficacy of these Fungicides Against Isolates Resistant to Pyraclostrobin and Boscalid.
A. Keinath (2015)
10.1007/978-1-4612-4362-5_1
Environmental fate of chlorpyrifos.
K. D. Racke (1993)
10.2134/JEQ2003.1250
Mineralization of soil-aged isoproturon and isoproturon metabolites by Sphingomonas sp. strain SRS2.
H. Johannesen (2003)
Guidance Document on Estimating Persistence and Degradation Kinetics from Environmental Fate Studies on Pesticides in EU Registration
J. Dyson (2006)
10.1080/10643389.2014.1001141
Abiotic and Biotic Processes Governing the Fate of Phenylurea Herbicides in Soils: A Review
S. Hussain (2015)
10.1016/J.SOILBIO.2006.04.051
Field-scale study of the variability in pesticide biodegradation with soil depth and its relationship with soil characteristics
M. S. Rodríguez-Cruz (2006)
10.1021/JF00096A029
Resistance of chlorpyrifos to enhanced biodegradation in soil
K. Racke (1990)
10.2134/JEQ1999.00472425002800010014X
Isoproturon Sorption and Degradation in a Soil from Grassed Buffer Strip
P. Benoît (1999)
10.1021/JF9506141
Factors Affecting the Hydrolytic Degradation of Chlorpyrifos in Soil
K. Racke (1996)
10.1021/IE970796J
Influence of surface characteristics on liquid-phase adsorption of phenol by activated carbons prepared from bituminous coal
T. Hsisheng (1998)
10.1094/PDIS-01-14-0091-RE
Efficacy of Fungicide Applications During and After Anthesis Against Fusarium Head Blight and Deoxynivalenol in Soft Red Winter Wheat.
D. D’Angelo (2014)
10.1007/s11356-012-1368-0
ECOFUN-MICROBIODIV: an FP7 European project for developing and evaluating innovative tools for assessing the impact of pesticides on soil functional microbial diversity—towards new pesticide registration regulation?
F. Martin-Laurent (2012)
10.1007/s11356-012-1198-0
The influence of copper on tebuconazole sorption onto soils, humic substances, and ferrihydrite
Eva Čadková (2012)
10.2134/JEQ2004.0473
Accelerated soil dissipation of tebuconazole following multiple applications to peanut.
T. Potter (2005)
10.1016/S0045-6535(99)00546-9
Leaching and degradation of corn and soybean pesticides in an Oxisol of the Brazilian Cerrados.
V. Laabs (2000)
10.1016/j.envpol.2015.10.027
Identification and characterization of tebuconazole transformation products in soil by combining suspect screening and molecular typology.
V. Storck (2016)
10.1002/PS.844
Contribution of non-agricultural pesticides to pesticide load in surface water.
C. Skark (2004)
10.1128/AEM.67.12.5403-5409.2001
Isolation from Agricultural Soil and Characterization of a Sphingomonas sp. Able To Mineralize the Phenylurea Herbicide Isoproturon
S. R. Sørensen (2001)
10.1080/03601239709373118
Dissipation of chlorpyrifos, oxon, and 3,5,6-trichloro-2-pyridinol in litter and elm forest soil
H. Jin (1997)
10.1007/s10661-015-4591-6
Dissipation, residues, and safety evaluation of trifloxystrobin and tebuconazole on ginseng and soil
Y. Wang (2015)
10.1080/03601234.2012.640918
Sorption of tebuconazole onto selected soil minerals and humic acids
Eva Čadková (2012)
10.1080/03067319508033140
The Occurrence of Pesticides in Groundwater—Results of Case-studies
C. Skark (1995)
10.1046/J.1365-3180.2003.00327.X
The effect of weather factors on the performance of herbicides to control Alopecurus myosuroides in winter wheat
L. Collings (2003)
10.1016/S0043-1354(00)00409-7
Analysing transformation products of herbicide residues in environmental samples.
R. K. Juhler (2001)
10.1111/J.1365-3180.1983.TB00545.X
The persistence and metabolism of isoproturon in soil
P. J. Muud (1983)
10.1016/J.AGEE.2007.07.011
The mobility and degradation of pesticides in soils and the pollution of groundwater resources
M. Arias-Estévez (2008)
10.1002/PS.860
Tebuconazole dissipation and metabolism in Tifton loamy sand during laboratory incubationt.
T. Strickland (2004)
10.1016/J.CROPRO.2015.07.022
Comparing efficacy of insecticides against cabbage maggot (Diptera: Anthomyiidae) in the laboratory
S. V. Joseph (2015)
10.1016/j.chemosphere.2014.11.031
Enantioselectivity in tebuconazole and myclobutanil non-target toxicity and degradation in soils.
Yuanbo Li (2015)
10.1016/J.SOILBIO.2011.07.001
Tebuconazole application decreases soil microbial biomass and activity
Borja Muñoz-Leoz (2011)
10.1128/AEM.69.9.5198-5206.2003
Effects of Soil pH on the Biodegradation of Chlorpyrifos and Isolation of a Chlorpyrifos-Degrading Bacterium
B. Singh (2003)



This paper is referenced by
10.3389/fmicb.2020.610298
Assessing the Effects of β-Triketone Herbicides on the Soil Bacterial and hppd Communities: A Lab-to-Field Experiment
Clémence Thiour-Mauprivez (2020)
10.1080/15320383.2018.1564733
Environmental Fate of Two Organophosphorus Insecticides in Soil Microcosms under Mediterranean Conditions and Their Effect on Soil Microbial Communities
Asma Ben Salem (2019)
10.1016/j.scitotenv.2020.138374
Field measurement and modelling of chlorotoluron and flufenacet persistence in unamended and amended soils.
J. M. Marín-Benito (2020)
10.1038/s41598-018-21288-y
Individual and combined effects of herbicide tribenuron-methyl and fungicide tebuconazole on soil earthworm Eisenia fetida
J. Chen (2018)
10.3389/fmicb.2017.00378
Influence of Herbicide Triasulfuron on Soil Microbial Community in an Unamended Soil and a Soil Amended with Organic Residues
E. Pose-Juan (2017)
10.1016/j.chemosphere.2019.03.183
Investigation of etoxazole metabolites in citrus, soil and earthworms by ultra-performance liquid chromatography with time-of-flight mass spectrometry.
D. Sun (2019)
10.1007/s11356-017-9652-7
Influence of selected cyclodextrins in sorption-desorption of chlorpyrifos, chlorothalonil, diazinon, and their main degradation products on different soils
M. Báez (2017)
10.1002/ps.5570
Degradation studies of dimethachlor in soils and water by UHPLC-HRMS: putative elucidation of unknown metabolites.
Rosalía López-Ruíz (2019)
10.1080/10826076.2019.1642918
Dissipation kinetics of tebuconazole on Malus domestica (Golden Delicious and Jonathan) in an apple orchard from north-eastern Romania
Anda Cristina Coman-Babusanu (2019)
10.17635/LANCASTER/THESIS/1082
Soil carbon sequestration by grasslands to mitigate climate change
Radim Sarlej (2020)
10.1007/s12665-018-7698-6
Comparative agroenvironmental risks of pesticides in different cropping systems: application of the I-Phy indicator
C. Beber (2018)
10.3390/ENVIRONMENTS7100079
Effect of Multiple Stresses, Organic Amendment and Compaction, on the Fate and Impact of Isoproturon in Soil
L. Mamy (2020)
10.1007/s40201-020-00555-z
Chlorpyrifos removal: Nb/boron-doped diamond anode coupled with solid polymer electrolyte and ultrasound irradiation
Andrea Luca Tasca (2020)
10.4067/S0718-58392017000300281
Degradation and adsorption of tebuconazole and tribenuron-methyl in wheat soil, alone and in combination
Feifei Wang (2017)
10.1016/j.scitotenv.2018.05.073
Assessment of the impact of three pesticides on microbial dynamics and functions in a lab-to-field experimental approach.
P. Karas (2018)
10.1016/j.scitotenv.2019.06.409
Factors affecting coupled degradation and time-dependent sorption processes of tebuconazole in mineral soil profiles.
Michael Siek (2019)
10.1016/j.chemosphere.2017.09.143
Adsorption-desorption and hysteresis phenomenon of tebuconazole in Colombian agricultural soils: Experimental assays and mathematical approaches.
Carmen S. Mosquera-Vivas (2018)
10.1016/J.IBIOD.2017.12.001
Biodegradation of fungicide Tebuconazole by Serratia marcescens strain B1 and its application in bioremediation of contaminated soil
Wang Xin-hong (2018)
10.1016/J.JPCS.2019.01.018
Effect of Zr+4 doping on characteristics and sonocatalytic activity of TiO2/carbon nanotubes composite catalyst for degradation of chlorpyrifos
A. F. Hassan (2019)
10.1007/s11356-020-10222-3
Soil dissipation and bioavailability to earthworms of two fungicides under laboratory and field conditions
S. Nélieu (2020)
10.1007/698_2020_616
Impact of PhACs on Soil Microorganisms
Sara Gallego (2020)
10.1007/s11356-018-2559-0
Degradation kinetics of chlorpyrifos and diazinon in volcanic and non-volcanic soils: influence of cyclodextrins
M. Báez (2018)
Adaption of Catechol and Reversible Addition-Fragmentation Chain-Transfer (RAFT) Chemistries for Water-Based Applications
Olabode O. Oyeneye (2017)
10.1016/j.jchromb.2020.122285
New analytical method for chlorpyrifos determination in biobeds constructed in Brazil: Development and validation.
G. D. Quatrin (2020)
10.3389/fmicb.2018.01412
Lab to Field Assessment of the Ecotoxicological Impact of Chlorpyrifos, Isoproturon, or Tebuconazole on the Diversity and Composition of the Soil Bacterial Community
V. Storck (2018)
10.1016/j.envpol.2020.115124
Triazole resistance in Aspergillus fumigatus in crop plant soil after tebuconazole applications.
Duantao Cao (2020)
10.1016/j.jes.2020.02.009
Dissipation of S-metolachlor and butachlor in agricultural soils and responses of bacterial communities: Insights from compound-specific isotope and biomolecular analyses.
E. Torabi (2020)
10.1007/s11356-020-08840-y
Co-presence of the anionic surfactant sodium lauryl ether sulphate and the pesticide chlorpyrifos and effects on a natural soil microbial community
T. Pescatore (2020)
10.1007/s12161-017-1044-6
Simultaneous Determination of Fluoxastrobin and Tebuconazole in Cucumber and Soil Based on Solid-Phase Extraction and LC-MS/MS Method
Weimin Wang (2017)
10.1016/j.envpol.2020.115186
Assessment of pesticide inputs into surface waters by agricultural and urban sources - A case study in the Querne/Weida catchment, central Germany.
Nadine Tauchnitz (2020)
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