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Mussel-Inspired Thiol–Ene Polymer Networks: Influencing Network Properties And Adhesion With Catechol Functionality

B. Sparks, Ethan F. T. Hoff, LaTonya P. Hayes, Derek L Patton
Published 2012 · Materials Science

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In this work, we report the synthesis of photocurable, ternary polymer networks prepared by incorporating dopamine acrylamide (DAm) into a cross-linked thiol–ene network based on pentaerythritol triallyl ether (APE) and pentaerythritol tetra(3-mercaptopropionate) (PETMP). We systematically evaluate the effect of DAm, in the nonoxidized catechol form, on photopolymerization kinetics and thermal, thermomechanical, and mechanical properties of the modified thiol–ene networks. We show that while DAm only affects photopolymerization kinetics at high concentrations, the presence of the catechol moiety significantly increases the glass transition temperature of the networks across the compositional range (0–50 mol % DAm) due to hydrogen bonding interactions between the catechol and various hydrogen bonding acceptors (ethers, amides, esters) within the network, despite an obvious decrease in cross-link density with increasing concentration of the monofunctional acrylamide. Similarly, trends in the mechanical prop...
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