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Effect Of Molecule-metal Electronic Coupling On Through-bond Hole Tunneling Across Metal-organic Monolayer-semiconductor Junctions.

Y. Selzer, A. Salomon, D. Cahen
Published 2002 · Medicine, Chemistry

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Using Hg/alkyl-chain-monolayer/p-Si devices we find that the type of contact between the chains and the electrodes (chemical bonding or not) is of critical importance for electronic transport across the junctions. As the semiconductor is p-type, the transport is that of holes. In agreement with theory we find that holes tunnel more efficiently through alkyl chains than do electrons.



This paper is referenced by
10.1007/s10854-016-6065-1
Single-molecule devices: materials, structures and characteristics
Biswanath Mukherjee (2016)
10.1016/S1369-7021(05)70985-8
Energetics of molecular interfaces
D. Cahen (2005)
10.1021/JP509581E
Metastable Molecular Metal–Semiconductor Junctions
L. Zhu (2015)
10.1021/ja907003w
Copper-metal deposition on self assembled monolayer for making top contacts in molecular electronic devices.
Oliver Seitz (2009)
10.1039/B611448B
Interfacial bridge-mediated electron transfer: mechanistic analysis based on electrochemical kinetics and theoretical modelling.
M. Newton (2007)
10.1016/J.ICA.2006.08.030
Electrochemical characterization of redox centers organized at Hg surfaces
Michela Cattabriga (2007)
Assembling large numbers of molecules into nano-scaled objects to form new devices and circuit architectures is discussed in this paper as a means for realizing a new paradigm for information processing.
Molecular Nanoelectronics (2010)
10.1093/OXFORDHB/9780199533060.013.9
Molecular electronics based on self-assembled monolayers
Dominique Vuillaume (2010)
10.1007/978-3-319-22611-8_4
Introduction to Self-Assembled Monolayers
Marta Galbiati (2016)
10.1021/acsnano.5b01629
Experimental and Theoretical Analysis of Nanotransport in Oligophenylene Dithiol Junctions as a Function of Molecular Length and Contact Work Function.
Z. Xie (2015)
10.1016/J.JELECHEM.2004.01.002
Photoelectrochemical etching of silicon derivatized with an electroactive thiophene-terminated alkyl monolayer: toward a redox center-induced etching activation and anisotropy
B. Fabre (2004)
10.1021/JP711833K
Synthesis and Characterization of a Thiol-Tethered Tripyridyl Porphyrin on Au(111)
Yang-Hsiang Chan (2008)
Probing molecule-semiconductor interfaces through Metal Molecule Semiconductor transport characteristics
Archana Bahuguna (2009)
10.1002/SMLL.200500052
A tunnel current in self-assembled monolayers of 3-mercaptopropyltrimethoxysilane.
D. Aswal (2005)
10.1149/1.1627353
Effect of Organic Contamination on the Electrical Degradation of Hydrogen-Terminated Silicon upon Exposure to Air under Ambient Conditions
Yong-jun Liu (2003)
10.1021/JP303072A
Comparison of SAM-Based Junctions with Ga2O3/EGaIn Top Electrodes to Other Large-Area Tunneling Junctions
C. A. Nijhuis (2012)
10.1063/1.2204917
Optical properties of current carrying molecular wires.
Michael Galperin (2006)
10.1002/adma.201706322
Stable Molecular Diodes Based on π-π Interactions of the Molecular Frontier Orbitals with Graphene Electrodes.
P. Song (2018)
10.1098/rsta.2007.2029
The study of charge transport through organic thin films: mechanism, tools and applications
E. Weiss (2007)
10.1002/adma.201200579
Multilayer graphene-coated atomic force microscopy tips for molecular junctions.
Yugeng Wen (2012)
10.1002/SLCT.201600455
Improved Efficiency of Hybrid Inorganic-Organic Light Emitting Diodes
Jayaraman Jayabharathi (2016)
10.1039/c3cp54619e
Construction of a metal-organic monolayer-semiconductor junction on a hydrogen-terminated Si(111) surface via Si-C covalent linkage and its electrical properties.
Kohei Uosaki (2014)
10.1039/C4QI00077C
Synthesis, characterisation, water adsorption and proton conductivity of three Cd(II) based luminescent metal–organic frameworks
Srinivasulu Parshamoni (2014)
10.1016/J.APSUSC.2016.04.121
Organic molecules on silicon surface: A way to tune metal dependent Schottky barrier
M. K. Rabinal (2016)
10.1016/S0167-9317(03)00458-1
The metal/organic monolayer interface in molecular electronic devices
D. Vuillaume (2003)
10.1021/JP304051R
Interfacial Charge-Transfer Effects in Semiconductor–Molecule–Metal Structures: Influence of Contact Variation
Z. Mao (2012)
Modulation of Metastable Metal-Semiconductor Junctions
Lixia Zhu (2014)
10.1039/B507854G
Metalloprotein tunnel junctions: compressional modulation of barrier height and transport mechanism.
J. J. Davis (2006)
10.1039/B609560G
Studying electron transfer through alkanethiol self-assembled monolayers on a hanging mercury drop electrode using potentiometric measurements.
Meirav Cohen-Atiya (2006)
10.1039/B920233A
Grafting of poly(3-hexylthiophene) brushes on oxides using click chemistry
P. Paoprasert (2010)
10.1109/JPROC.2003.818320
Fabrication, assembly, and characterization of molecular electronic components
B. Mantooth (2003)
10.1109/JPROC.2010.2063410
Molecular Nanoelectronics
D. Vuillaume (2010)
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