Online citations, reference lists, and bibliographies.
← Back to Search

Oxidation Potentials Correlate With Conductivities Of Aromatic Molecular Wires.

J. Quinn, F. Foss, L. Venkataraman, R. Breslow
Published 2007 · Medicine, Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Cyclic voltammetry determines first and second oxidation potentials of conducting diamines. The results show that unsubstituted and methyl-substituted molecules conduct electricity in partially positively charged states, reflecting electron delocalization at the wire−gold junctions, but with electron-withdrawing substituents, the molecular wires are closer to uncharged as conductors, consistent with HOMO arguments.



This paper is referenced by
10.3762/bjoc.4.50
Highly brominated anthracenes as precursors for the convenient synthesis of 2,9,10-trisubstituted anthracene derivatives
O. Cakmak (2008)
10.1063/1.3151682
Nonequilibrium Green's function study on the electronic structure and transportation behavior of the conjugated molecular junction: terminal connections and intramolecular connections.
Hongmei Liu (2009)
10.1103/PHYSREVB.83.125424
Conductance and application of organic molecule pairs as nanofuses
S. Rodríguez-Bolívar (2011)
10.1002/anie.201510935
Assembly of an Axially Chiral Dynamic Redox System with a Perfluorobiphenyl Skeleton into Dumbbell- or Tripod-type Electron Donors.
H. Tamaoki (2016)
10.1039/b922000c
The experimental determination of the conductance of single molecules.
R. Nichols (2010)
10.1039/c7cp04295g
Guidelines and diagnostics for charge carrier tuning in thiophene-based wires.
Ganna Gryn'ova (2017)
10.1088/0953-8984/20/37/374104
Charge transport in nanoscale aromatic and antiaromatic systems
R. Breslow (2008)
10.1039/d0ra00383b
Three-dimensional graphene oxide cross-linked by benzidine as an efficient metal-free photocatalyst for hydrogen evolution
Xin Zhou (2020)
10.1071/CH15634
Molecular Electronics: History and Fundamentals
Santiago Marqués-González (2016)
10.1016/J.TET.2011.08.008
Structure–property relationships in molecular wires
R. Breslow (2011)
10.1016/J.CCLET.2016.06.031
Recent advances of folded tetraphenylethene derivatives featuring through-space conjugation
Pingchuan Shen (2016)
10.1002/smll.200900494
Micrometer-sized DNA-single-fluorophore-DNA supramolecule: synthesis and single-molecule characterization.
J. Lee (2009)
10.1002/anie.201411909
Multichannel conductance of folded single-molecule wires aided by through-space conjugation.
Long Chen (2015)
10.1016/j.coelec.2019.10.008
Electrochemical electron transfer and its relation to charge transport in single molecule junctions
M. Hromadová (2020)
10.1002/chem.201103972
From monomers to π stacks, from nonconductive to conductive: syntheses, characterization, and crystal structures of benzidine radical cations.
X. Chen (2012)
10.1021/ACS.JPCC.6B10925
Influence of Molecular Structure on Contact Interaction between Thiophene Anchoring Group and Au Electrode
Jin-Chuan Mao (2017)
10.1016/J.PHYSE.2012.10.017
Elastic and inelastic electron transport in metal-molecule(s)-metal junctions
L. Lin (2013)
10.1002/ADFM.201203439
Fused Thiophene Semiconductors: Crystal Structure-Film Microstructure Transistor Performance Correlations
Jangdae Youn (2013)
10.1295/KORON.66.406
Long-Range Electron Transfer through Self-Assembled Monolayers Composed of Helical Peptides Carrying a Ferrocene Unit at the Terminal
T. Morita (2009)
10.1021/ja410061x
Electrochemical evidence for intermolecular proton-coupled electron transfer through a hydrogen bond complex in a p-phenylenediamine-based urea. Introduction of the "wedge scheme" as a useful means to describe reactions of this type.
Laurie A. Clare (2013)
10.1039/c4cs00264d
Incorporating single molecules into electrical circuits. The role of the chemical anchoring group.
E. Leary (2015)
10.1002/anie.201207412
Reversible σ-dimerizations of persistent organic radical cations.
X. Chen (2013)
10.1002/celc.201901801
Single Molecule Conductance of Electroactive Helquats. Solvent Effect.
V. Kolivoška (2019)
10.1007/128_2012_387
Antiaromaticity in nonbenzenoid oligoarenes and ladder polymers.
Rebecca R. Parkhurst (2014)
10.1016/J.ELECTACTA.2018.01.094
Correlation of electrochemical properties of expanded pyridinium compounds with their single molecule conductance
Š. Lachmanová (2018)
10.1039/c7ob01376k
Excited-state intermolecular proton transfer dependent on the substitution pattern of anthracene-diurea compounds involved in fluorescent ON1-OFF-ON2 response by the addition of acetate ions.
Hisato Matsumoto (2017)
10.1038/srep29314
Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
X. Chen (2016)
10.1021/JP2119923
Enhancing Molecular Conductance of Oligo(p-phenylene ethynylene)s by Incorporating Ferrocene into Their Backbones
Q. Lu (2012)
10.1002/asia.200900565
Integrating reaction chemistry into molecular electronic devices.
Q. Shen (2010)
10.1039/c5cs00244c
"Carbo-aromaticity" and novel carbo-aromatic compounds.
Kévin Cocq (2015)
10.1021/ja211555x
Correlations between molecular structure and single-junction conductance: a case study with oligo(phenylene-ethynylene)-type wires.
Veerabhadrarao Kaliginedi (2012)
10.1063/1.2955463
Theoretical investigation of electron transport modulation through benzenedithiol by substituent groups.
Manuel Smeu (2008)
See more
Semantic Scholar Logo Some data provided by SemanticScholar