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Direct Formation Of Isotactic Poly(1-butene) Form I Crystal From Memorized Ordered Melt

Fengmei Su, X. Li, W. Zhou, Shanshan Zhu, Y. Ji, Z. Wang, Zeming Qi, L. Li
Published 2013 · Chemistry

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Crystallization from memorized ordered melt (MOM) of isotactic polybutene-1 (iPB-1) is investigated with in situ Fourier transformation infrared microspectroscopic imaging and wide- and small-angle X-ray scattering. After being partially melted at high temperature, a small portion of form I crystal of iPB-1 recovers back when the temperature is lowered. This is different from a disordered melt, which crystallizes into form II directly. The recovery of form I crystal is attributed to the presence of MOM, which may keep the conformation order of form I crystal. Experimental evidence show that MOM possesses three characteristics, namely: (i) associating with the preserved form I; (ii) occupying only a small portion of the melt in the partially melted sample; (iii) being stable at high temperature. All this experimental evidence suggests that MOM locates at the boundary of crystal and melt. This is in line with the physical picture of nonclassical nucleation and growth theory or the multistage approach, where...
This paper references
10.1021/MA1019686
Conformational Ordering in Growing Spherulites of Isotactic Polypropylene
Yuanhua Cong (2010)
10.1021/MA1020193
Flow Memory and Stability of Shear-Induced Nucleation Precursors in Isotactic Polypropylene
D. Cavallo (2010)
10.1016/0032-3861(92)90400-Q
Structural formation of poly(ethylene terephthalate) during the induction period of crystallization. 2: Kinetic analysis based on the theories of phase separation
M. Imai (1992)
10.1246/BCSJ.39.742
The Vibrational Spectra and Vibrational Assignments of Isotactic Polybutene-1
Minoru Ukita (1966)
10.1021/MA301595K
Conformational Ordering on the Growth Front of Isotactic Polypropylene Spherulite
Yuanhua Cong (2012)
10.1021/MA00158A036
Kinetics of crystallization in semicrystalline/amorphous polymer mixtures
G. Alfonso (1986)
10.1021/MA60070A047
A New Theoretical Approach of the Secondary Nucleation at High Supercooling
J. Point (1979)
10.1063/1.1747055
Rate of Nucleation in Condensed Systems
D. Turnbull (1949)
10.1002/POL.1985.180230121
Linear high polymers as host in intercalates. Introduction and example
J. Point (1985)
10.1016/0022-3093(93)91250-7
Diffuse interface theory of nucleation
L. Gránásy (1993)
10.1002/POL.1965.110030619
Infrared spectra of the polybutene‐1 polymorphs
J. Luongo (1965)
10.1063/1.1713205
Isotactic Polybutene‐1 Single Crystals: Morphology
V. F. Holland (1964)
10.1021/MA0015875
A Temperature- and Molar Mass-Dependent Change in the Crystallization Mechanism of Poly(1-butene): Transition from Chain-Folded to Chain-Extended Crystallization?
Q. Fu (2001)
10.1021/MA071382X
alpha and beta interfacial structures of the iPP/PET matrix/fiber systems
X. Sun (2007)
10.1038/nmat2405
Cloning polymer single crystals through self-seeding.
J. Xu (2009)
10.1063/1.1733363
Rate of Spherulitic Crystallization with Chain Folds in Polychlorotrifluoroethylene
J. D. Hoffman (1962)
10.1002/POLB.1986.090240212
Experimental criterion for the crystallization regime in polymer crystals grown from dilute solution: possible limitation due to fractionation
J. Point (1986)
10.1002/POL.1968.110061105
Infrared investigations of the polymorphic modifications of polybutene‐1
G. Goldbach (1968)
10.1016/J.POLYMDEGRADSTAB.2010.06.027
Effect of molecular weight on the polymorphic transformation of isotactic poly(1-butene)
A. He (2010)
10.1016/S0081-1947(08)60638-4
Homogeneous Nucleation and the Temperature Dependence of the Crystal-Melt Interfacial Tension
F. Spaepen (1994)
10.1007/BF00354556
Phase II to phase I crystal transformation in polybutene-1 single crystals: a reinvestigation
S. Kopp (1994)
10.1063/1.477658
Computer simulation study of gas–liquid nucleation in a Lennard-Jones system
P. T. Wolde (1998)
10.1016/J.POLYMER.2010.07.010
Origin of the melt memory effect in polymer crystallization
J. A. Martins (2010)
10.1088/0953-8984/8/47/079
Density functional approaches to the dynamics of phase transitions
D. W. Oxtoby (1996)
10.1016/J.EURPOLYMJ.2012.03.010
Memory effect of the molecular topology of lamellar polyethylene on the strain-induced fibrillar structure
S. Humbert (2012)
10.1007/S101890070033
Commentary on theories of polymer crystallization
M. Muthukumar (2000)
10.1016/0032-3861(94)90932-6
Epitaxial crystallization and crystalline polymorphism of poly(1-butene) : forms III and II
S. Kopp (1994)
10.1007/S101890070032
Commentary on polymer crystallization: Selection rules in different length scales of a nucleation process
S. Cheng (2000)
10.1140/EPJE/E2005-00022-1
Crystallization of a poly(ethylene-co-octene): I A precursor structure and two competing mechanisms
A. Häfele (2005)
10.1246/BCSJ.34.1209
Infrared Spectra of Isotactic Poly-α-olefins
H. Tadokoro (1961)
10.1002/MASY.19971180143
Melt memory effects in polymer crystallization
G. C. Alfonso (1997)
10.1021/AR9702278
Nucleation of First-Order Phase Transitions
D. Oxtoby (1998)
10.6028/jres.064A.007
Theory of Formation of Polymer Crystals with Folded Chains in Dilute Solution
J. I. Lauritzen (1960)
10.1016/0022-0248(74)90100-6
Nucleation-controlled growth on a one-dimensional growth of finite length
F. C. Frank (1974)
10.1098/rspa.1961.0163
On the theory of polymer crystallization
F. Frank (1961)
10.1140/EPJE/E2005-00023-0
Crystallization of poly(ethylene-co-octene): II Melt memory effects on first order kinetics
A. Häfele (2005)
10.1016/S0032-3861(97)00071-2
Kinetic of crystallization from the melt and chain folding in polyethylene fractions revisited: theory and experiment
J. Hoffman (1997)
10.1080/00222348208204934
On the molecular mechanism of the crystal transformation (tetragonal-hexagonal) in polybutene-1
R. M. Gohil (1982)
10.6028/jres.065A.035
Crystallization of Bulk Polymers With Chain Folding: Theory of Growth of Lamellar Spherulites
J. Hoffman (1961)
10.1103/PhysRevLett.81.373
Spinodal-assisted crystallization in polymer melts
P. Olmsted (1998)
10.1007/S101890070030
From the melt via mesomorphic and granular crystalline layers to lamellar crystallites: A major route followed in polymer crystallization?
G. Strobl (2000)
10.1007/BF00254659
II-I phase transformation of melt-crystallized oriented lamellae of polybutene-1 by shear deformation
Y. Fujiwara (1985)
10.1002/POL.1966.160040613
Infrared characterization of polymorphism in polybutene‐1
J. Luongo (1966)
10.1140/EPJE/E2005-00032-Y
A thermodynamic multiphase scheme treating polymer crystallization and melting
G. Strobl (2005)
10.1016/S0022-3093(97)00250-0
Diffuse interface model of crystal nucleation
L. Gránásy (1997)
10.1021/MA051337U
Block formation during polymer crystallization
T. Hippler (2005)
10.1063/1.471146
DIFFUSE INTERFACE THEORY FOR HOMOGENEOUS VAPOR CONDENSATION
L. Gránásy (1996)
10.1016/0032-3861(92)90399-H
Structural formation of poly (ethylene terephthalate) during the induction period of crystallization: 1. Ordered structure appearing before crystal nucleation
M. Imai (1992)
10.1007/12_013
Spinodal crystallization of polymers: Crystallization from the unstable melt
K. Kaji (2005)
10.1007/S101890070031
What can polymer crystal structure tell about polymer crystallization processes?
B. Lotz (2000)
10.1063/1.480806
Cahn–Hilliard theory with triple-parabolic free energy. I. Nucleation and growth of a stable crystalline phase
L. Gránásy (2000)
10.1021/MA702725G
Initial Stage of iPP β to α Growth Transition Induced by Stepwise Crystallization
H. Li (2008)
10.1021/MA8025496
CO2-Induced Crystal Phase Transition from Form II to I in Isotactic Poly-1-butene
L. Li (2009)
10.1023/A:1012499918018
Analysis of Calorimetric Curves Detected During the Polymorphic Transformation of Isotactic Polybutene-1
G. Alfonso (2001)
10.1021/MA021005E
Polymorphism of Isotactic Poly(1-butene) as Revealed by Microindentation Hardness. 1. Kinetics of the Transformation
F. Azzurri (2002)
10.1016/J.POLYMER.2010.09.066
Kinetic study of the II—I phase transition of isotactic polybutene-1
Maruyama Masanori (2010)



This paper is referenced by
10.1016/J.POLYMER.2018.06.032
Concentration fluctuations in the early stages of LLPS and partial dissolution of melt-memory in broadly distributed ethylene copolymers
Xuejian Chen (2018)
10.1021/ACS.MACROMOL.5B02688
Flow-Induced Crystallization of Polymers: Molecular and Thermodynamic Considerations
Z. Wang (2016)
10.1016/J.EURPOLYMJ.2018.02.038
Polymorph selection during crystallization of random copolymers
Yuqing Lai (2018)
10.1016/J.POLYMER.2018.01.078
Interfacial nucleation in iPP/PB-1 blends promotes the formation of polybutene-1 trigonal crystals
Zefan Wang (2018)
10.1039/C5CE01727K
The morphology and polymorphism of self-nucleated trigonal isotactic poly(1-butene) studied by synchrotron IR microspectroscopy
D. Cavallo (2016)
10.1002/PEN.24476
Effects of melt structure on non‐isothermal crystallization behavior of isotactic polypropylene nucleated with α/β compounded nucleating agents
Qiyan Zhang (2017)
10.1021/ACS.MACROMOL.5B02161
Mixing Assisted Direct Formation of Isotactic Poly(1-butene) Form I′ Crystals from Blend Melt of Isotactic Poly(1-butene)/Polypropylene
Y. Ji (2016)
10.1002/PI.5625
Isothermal crystallization kinetics and subsequent melting behavior of β‐nucleated isotactic polypropylene/graphene oxide composites with different ordered structure
Yansong Yu (2018)
10.1021/IE500007N
Study on Crystallization Kinetics of Partially Melting Polyethylene Aiming To Improve Mechanical Properties
Haili Zheng (2014)
10.1016/j.polymer.2020.122209
Crystallisation of iPB-1 based on preserved helix conformation
J. Li (2020)
10.1021/MA501272A
Molecular Weight Dependency of Crystallization Line, Recrystallization Line, and Melting Line of Polybutene-1
Yaotao Wang (2014)
10.3390/polym11121981
Isotactic Polybutene-1/Bamboo Powder Composites with Excellent Properties at Initial Stage of Molding
Bo Wang (2019)
10.1016/j.polymertesting.2019.106120
Polymorphism analysis of trans-1,4-polyisoprene during melt-recrystallization
Hua-rong Nie (2019)
10.1007/s10118-014-1502-1
New understanding on the memory effect of crystallized iPP
Xiangyang Li (2014)
10.1016/j.polymer.2019.121966
Transformation from form II to form I accelerated by oriented lamellae in Polybutene-1
Chen Jin-long (2019)
10.1016/J.EURPOLYMJ.2016.02.013
Opportunities and challenges for polymer science using synchrotron-based infrared spectroscopy
G. Ellis (2016)
10.1021/ACS.IECR.7B00543
Crystal Structure Regulation of Ferroelectric Poly(vinylidene fluoride) via Controlled Melt–Recrystallization
Yiran Zheng (2017)
10.1007/s10118-019-2184-5
Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy
J. Hu (2018)
10.1021/ACS.MACROMOL.5B02785
Refinement of the Crystal Structures of Forms I and II of Isotactic Polybutene-1 and a Proposal of Phase Transition Mechanism between Them
K. Tashiro (2016)
10.1016/j.mtchem.2020.100307
The outlined polymorph selection of iPB-1 revealing by incorporation of a dentritic polymer
Qian Wu (2020)
10.1039/c7sm00107j
Structural and morphological transitions in extension-induced crystallization of poly(1-butene) melt.
Z. Wang (2017)
10.1039/C9CE00576E
Role of conformation in crystal formation and transition of polybutene-1
Q. Xing (2019)
10.1007/s10965-014-0555-8
Shear effects on crystallization behaviors and structure transitions of isotactic poly-1-butene
J. Li (2014)
10.1007/s10118-015-1613-3
The spatial correlation between crystalline and amorphous orientations of isotactic polypropylene during plastic deformation: An in situ observation with FTIR imaging
W. Chen (2015)
10.1039/c7sm01366c
Rapid assessment of crystal orientation in semi-crystalline polymer films using rotational zone annealing and impact of orientation on mechanical properties.
Changhuai Ye (2017)
10.1016/j.polymer.2020.123029
Role of chain dynamics in crystal transition of isotactic polybutene-1
P. Fu (2020)
10.1007/s10965-018-1617-0
Local conformation controlled crystallization of isotactic poly(butene-1)
J. Li (2018)
10.1021/ACS.MACROMOL.6B01457
Featured Crystallization Polymorphism and Memory Effect in Novel Butene-1/1,5-Hexadiene Copolymers Synthesized by Post-Metallocene Hafnium Catalyst
Leilei He (2016)
10.1039/C9RA03416A
Ordered structure effects on β-nucleated isotactic polypropylene/graphene oxide composites with different thermal histories
Yansong Yu (2019)
10.1007/s10973-018-7776-8
Effects of ordered structure on non-isothermal crystallization kinetics and subsequent melting behavior of β-nucleated isotactic polypropylene/graphene oxide composites
Yansong Yu (2018)
10.1016/j.polymer.2019.121826
Crystallization behavior, morphology and crystal transformation of blends of isotactic Poly(1-Butene) with propene-hexene copolymer
O. R. D. Ballesteros (2019)
10.1007/s10118-018-2169-9
In Situ Synchrotron Radiation Techniques: Watching Deformation-induced Structural Evolutions of Polymers
L. Li (2018)
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