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Mn-, Fe-, And Co-Catalyzed Radical Hydrofunctionalizations Of Olefins.

Steven W. M. Crossley, C. Obradors, Ruben M. Martinez, Ryan A. Shenvi
Published 2016 · Chemistry, Medicine

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Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.
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