Online citations, reference lists, and bibliographies.
← Back to Search

Diffusion Mechanism Of Lithium Ion Through Basal Plane Of Layered Graphene.

Fei Yao, Fethullah Güneş, H. Q. Ta, Seung Mi Lee, Seung Jin Chae, Kyeu-Yoon Sheem, Costel Sorin Cojocaru, S. Xie, Y. H. Lee
Published 2012 · Chemistry, Medicine

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Coexistence of both edge plane and basal plane in graphite often hinders the understanding of lithium ion diffusion mechanism. In this report, two types of graphene samples were prepared by chemical vapor deposition (CVD): (i) well-defined basal plane graphene grown on Cu foil and (ii) edge plane-enriched graphene layers grown on Ni film. Electrochemical performance of the graphene electrode can be split into two regimes depending on the number of graphene layers: (i) the corrosion-dominant regime and (ii) the lithiation-dominant regime. Li ion diffusion perpendicular to the basal plane of graphene is facilitated by defects, whereas diffusion parallel to the plane is limited by the steric hindrance that originates from aggregated Li ions adsorbed on the abundant defect sites. The critical layer thickness (l(c)) to effectively prohibit substrate reaction using CVD-grown graphene layers was predicted to be ∼6 layers, independent of defect population. Our density functional theory calculations demonstrate that divacancies and higher order defects have reasonable diffusion barrier heights allowing lithium diffusion through the basal plane but neither monovacancies nor Stone-Wales defect.
This paper references
Electrochim. Acta
T Takamura (1055)
Chem. Lett
K Persson (1176)
Ruoff, R. S. Science
X S Li (1312)
ACS Nano
S Chen (1321)
J. Power Sources Electrochem. Soc. Corros. Sci J. Sci. Res. J. Electrochem. Soc. Electrochim. Acta J. Electrochem. Soc
J Vetter (1483)
47) Zheng
T M G Mohiuddin (1651)
J. Electrochem. Soc. Electrochim. Acta Z. J. Power Sources J. Phys. Chem. C
K Naoi (1753)
A634. (43) Yoo
C A Chu (1785)
10.1103/PHYSREVB.40.10810
Diffusion of lithium in highly oriented pyrolytic graphite at low concentrations and high temperatures.
Jungblut (1989)
Phys. Rev. B
B Jungblut (1989)
Extended Abstracts, Spring Meeting of the Electrochemical Society, May
J. M. Tarascon (1989)
10.1063/1.458452
An all‐electron numerical method for solving the local density functional for polyatomic molecules
B. Delley (1990)
Extended Abstracts, Spring Meeting of the Electrochemical Society
M Guyomard (1993)
Extended Abstracts , Spring Meeting of the Electrochemical Society , May 16 − 21 ,
J. M. Tarascon (1993)
10.1016/0022-0728(95)03907-X
Lithium intercalation/deintercalation behavior of basal and edge planes of highly oriented pyrolytic graphite and graphite powder
T. Tran (1995)
10.1103/PHYSREVLETT.77.3865
Generalized Gradient Approximation Made Simple.
Perdew (1996)
10.1149/1.1837560
In Situ Electrochemical Atomic Force Microscope Study on Graphite Electrodes
Karen A. Hirasawa (1997)
10.1149/1.1838160
Electrochemistry of Highly Ordered Pyrolytic Graphite Surface Film Formation Observed by Atomic Force Microscopy
Andrew C. Chu (1997)
10.1016/S0378-7753(96)02556-6
A.c. impedance analysis of electrochemical lithium intercalation into highly oriented pyrolytic graphite
Atsushi Funabiki (1997)
10.1149/1.1838281
Graphites for lithium-ion cells : The correlation of the first-cycle charge loss with the Brunauer-Emmett-Teller surface area
M. Winter (1998)
10.1149/1.1838857
Capacity Fade Mechanisms and Side Reactions in Lithium‐Ion Batteries
P. Arora (1998)
10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z
Insertion Electrode Materials for Rechargeable Lithium Batteries
M. Winter (1998)
10.1149/1.1391688
A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li‐Ion Batteries
D. Bar‐Tow (1999)
10.1016/S0013-4686(99)00400-4
Electrochemical intercalation of lithium species into disordered carbon prepared by the heat-treatment of poly (p-phenylene) at 650°C for anode in lithium-ion battery
Jinbao Gong (2000)
10.1016/J.ELECTACTA.2003.10.034
Effect on aluminum corrosion of LiBF4 addition into lithium imide electrolyte; a study using the EQCM
Seung-Wan Song (2004)
10.1149/1.2041867
Corrosion of Aluminum Current Collectors in Lithium-Ion Batteries with Electrolytes Containing LiPF6
Xueyuan Zhang (2005)
10.1149/1.1896531
Disordered Carbon Anode for Lithium-Ion Battery I. An Interfacial Reversible Redox Action and Anomalous Topology Changes
K. Naoi (2005)
10.1016/J.JPOWSOUR.2005.01.006
Ageing mechanisms in lithium-ion batteries
J. Vetter (2005)
10.1016/J.JPOWSOUR.2005.05.062
A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries
K. Edström (2006)
10.1016/J.CORSCI.2006.10.025
Real time pit initiation studies on stainless steels : The effect of sulphide inclusions
T. Wijesinghe (2007)
10.1149/1.2742321
Corrosion of Aluminum Current Collectors in High-Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles
Tzipi Cohen Hyams (2007)
10.1063/1.2818692
Raman Fingerprint of Charged Impurities in Graphene
C. Casiraghi (2007)
10.1016/J.ELECTACTA.2007.03.052
Identification of nano-sized holes by TEM in the graphene layer of graphite and the high rate discharge capability of Li-ion battery anodes
T. Takamura (2007)
Appl. Phys. Lett
S Pisana (2007)
10.1021/JP8003536
Poly(vinyl chloride) (PVC) Coated Idea Revisited: Influence of Carbonization Procedures on PVC-Coated Natural Graphite as Anode Materials for Lithium Ion Batteries
H. Zhang (2008)
10.1002/anie.200702505
Nanomaterials for rechargeable lithium batteries.
P. Bruce (2008)
10.1126/science.1156965
Fine Structure Constant Defines Visual Transparency of Graphene
R. R. Nair (2008)
10.1021/NL071822Y
Raman spectra of graphite oxide and functionalized graphene sheets.
K. Kudin (2008)
10.1021/nl800957b
Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries.
E. Yoo (2008)
10.1103/PHYSREVLETT.102.073005
Accurate molecular van der Waals interactions from ground-state electron density and free-atom reference data.
A. Tkatchenko (2009)
10.1038/nature07719
Large-scale pattern growth of graphene films for stretchable transparent electrodes
K. Kim (2009)
10.1126/science.1171245
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
Xuesong Li (2009)
10.1103/PhysRevB.79.205433
Uniaxial Strain in Graphene by Raman Spectroscopy: G peak splitting, Gruneisen Parameters and Sample Orientation
T. Mohiuddin (2009)
10.1016/j.otohns.2009.05.016
Nature
R. Rosenfeld (2009)
Adv. Mater. Nano
G H Han (2009)
10.1016/J.ELECTACTA.2009.10.068
A novel perspective on the formation of the solid electrolyte interphase on the graphite electrode for lithium-ion batteries
Jian Yan (2010)
10.1021/nn101926g
Synthesis of nitrogen-doped graphene films for lithium battery application.
A. M. Reddy (2010)
10.1021/la1019857
Role of edge orientation in kinetics of electrochemical intercalation of lithium-ion at graphite.
Y. Yamada (2010)
10.1021/ja905488x
Influence of size on the rate of mesoporous electrodes for lithium batteries.
Yu Ren (2010)
10.1021/nl101223k
The interaction of Li+ with single-layer and few-layer graphene.
Elad Pollak (2010)
10.1021/JZ100188D
Lithium Diffusion in Graphitic Carbon
K. Persson (2010)
Adv. Mater. ACS Nano
Hal Yu (2010)
10.1016/J.APSUSC.2011.09.007
Diffusion of Li+ ion on graphene: A DFT study
J. Zheng (2011)
10.1002/adma.201004444
Ultra-transparent, flexible single-walled carbon nanotube non-volatile memory device with an oxygen-decorated graphene electrode.
W. Yu (2011)
10.1021/nl201980p
Influence of copper morphology in forming nucleation seeds for graphene growth.
Gang Hee Han (2011)
10.1142/S1793292011002780
UV-LIGHT-ASSISTED OXIDATIVE sp3 HYBRIDIZATION OF GRAPHENE
Fethullah Güneş (2011)
10.1016/J.ELECOM.2011.05.012
Superior cycle stability of nitrogen-doped graphene nanosheets as anodes for lithium ion batteries
Xifei Li (2011)
10.1002/ADFM.201101241
Graphene Versus Carbon Nanotubes in Electronic Devices
C. Biswas (2011)
10.1021/nn102598m
Structural defects in graphene.
F. Banhart (2011)
10.1021/nn103028d
Oxidation resistance of graphene-coated Cu and Cu/Ni alloy.
Shanshan Chen (2011)
10.1021/nn203507y
Graphene: corrosion-inhibiting coating.
D. Prasai (2012)
10.1016/J.JPOWSOUR.2011.10.085
Influence of graphite surface modifications on the ratio of basal plane to “non-basal plane” surface area and on the anode performance in lithium ion batteries
T. Placke (2012)
10.1149/2.073205JES
Effect of Graphite Orientation and Lithium Salt on Electronic Passivation of Highly Oriented Pyrolytic Graphite
M. Tang (2012)
J. Power Sources
T Placke (2012)



This paper is referenced by
10.1016/J.JMST.2020.12.084
Review on the corrosion-promotion activity of graphene and its inhibition
Wen Sun (2021)
10.1016/J.APSUSC.2021.149228
Space-confined carbonization strategy for synthesis of carbon nanosheets from glucose and coal tar pitch for high-performance lithium-ion batteries
Zhenshu Wang (2021)
10.1016/J.CARTRE.2021.100045
Li intercalation into multilayer graphene with controlled defect densities
M. Ochapski (2021)
10.1016/J.JALLCOM.2020.157432
The first-principles study on the performance of the graphene/WS2 heterostructure as an anode material of Li-ion battery
M. Zhang (2021)
10.1016/J.ELECTACTA.2021.138641
Remarkable-cycling-performance anode for Li-ion battery: The bilayer β-bismuthene
Chunmei Tang (2021)
10.3390/nano11071813
Identifying the Association between Surface Heterogeneity and Electrochemical Properties in Graphite
Jaewon Kim (2021)
10.1039/D0SE01860K
Balancing the anode and cathode using a reduced graphene binder for boosting both energy and power density of hybrid supercapacitors
Ji-Hyuk Choi (2021)
10.1016/J.CEJ.2021.129267
3D layered nanostructure of vanadium nitrides quantum Dots@Graphene anode materials via In-Situ redox reaction strategy
Yu-Yun Peng (2021)
10.1088/1361-651X/abebcc
Defect, temperature, and strain effects on lattice heat conductivity of egg-tray graphene
Zhihui Sun (2021)
10.1038/s41467-021-22403-w
Graphene collage on Ni-rich layered oxide cathodes for advanced lithium-ion batteries
C. Park (2021)
10.1016/j.matchemphys.2020.124138
Theoretical characterization and application of mechanical behavior of atoms/ions migrating on graphene surface
Man Li (2021)
10.1016/J.MEMSCI.2021.119437
Robust reduced graphene oxide membranes with high water permeance enhanced by K+ modification
Rujie Yang (2021)
10.1016/j.carbon.2020.02.001
Dramatic improvement in the performance of graphene as Li/Na battery anodes with suitable electrolytic solvents
Sankha Mukherjee (2020)
10.1063/5.0017690
First principles study of Mo2N monolayer as potential anode material for na-ion batteries
V. Mehta (2020)
10.1016/j.cej.2019.122981
Few-layer NbSe2@graphene heterostructures as anodes in lithium-ion half- and full-cell batteries
Q. H. Nguyen (2020)
10.1002/9781119468288.ch3
Graphene and Related Materials as Anode Materials in Li Ion Batteries: Science and Practicality
Sandeep Kumar Marka (2020)
10.1039/d0ta04638h
Highly efficient overall water splitting over a porous interconnected network by nickel cobalt oxysulfide interfacial assembled Cu@Cu2S nanowires
D. Tran (2020)
10.1016/j.ensm.2020.07.004
Anode-free rechargeable lithium metal batteries: Progress and prospects
Zhengkun Xie (2020)
10.1002/celc.201902098
Surface‐Functionalized Graphite as Long Cycle Life Anode Materials for Lithium‐ion Batteries
Xiaohui Gong (2020)
10.3990/1.9789036550253
Group IV elements in 2D structures
M. Ochapski (2020)
10.1039/d0cs00187b
Carbon materials for ion-intercalation involved rechargeable battery technologies.
Gang Wang (2020)
10.1016/j.carbon.2019.09.026
Understanding the processing-structure-performance relationship of graphene and its variants as anode material for Li-ion batteries: A critical review
Farjana J. Sonia (2020)
10.1016/j.matchemphys.2020.123527
Theoretical study for adsorption and migration behavior of atoms/ions on sinusoidal corrugated graphene surface
Man Li (2020)
10.1016/j.comptc.2020.112825
Rattling motion of proton through five membered aromatic ring systems
S. Chamoli (2020)
10.1016/j.jelechem.2020.114475
Influence of flake size and porosity of activated graphene on the performance of silicon/activated graphene composites as lithium-ion battery anodes
Young-jin Cho (2020)
10.1016/j.electacta.2020.136858
Succinimide-modified graphite as anode materials for lithium-ion batteries
Xiaohui Gong (2020)
10.1007/s40820-020-0391-9
Stabilising Cobalt Sulphide Nanocapsules with Nitrogen-Doped Carbon for High-Performance Sodium-Ion Storage
Yilan Wu (2020)
10.1016/j.jpowsour.2020.228364
Heterogeneous nucleation of Li3VO4 regulated in dense graphene aerogel for lithium ion capacitors
Miaoxin Zhang (2020)
10.1039/d0cp02167a
Structural and magnetic properties of a defective graphene buffer layer grown on SiC(0001): a DFT study.
C. P. Huelmo (2020)
10.1021/acs.analchem.0c00218
Charge Storage in Graphene Oxide: The Impact of the Cation on Ion Permeability and Interfacial Capacitance.
Waldemir J. Paschoalino (2020)
10.1039/d0ra07733j
Ultrafast-charging and long cycle-life anode materials of TiO2-bronze/nitrogen-doped graphene nanocomposites for high-performance lithium-ion batteries
Thanapat Autthawong (2020)
10.1093/nsr/nwz140
Designing ionic channels in novel carbons for electrochemical energy storage
Jianglin Ye (2020)
See more
Semantic Scholar Logo Some data provided by SemanticScholar