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Kinetically Controlled Seeded Growth Synthesis Of Citrate-stabilized Gold Nanoparticles Of Up To 200 Nm: Size Focusing Versus Ostwald Ripening.
Neus G. Bastús, J. Comenge, V. Puntes
Published 2011 · Chemistry, Medicine
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Monodisperse citrate-stabilized gold nanoparticles with a uniform quasi-spherical shape of up to ∼200 nm and a narrow size distribution were synthesized following a kinetically controlled seeded growth strategy via the reduction of HAuCl(4) by sodium citrate. The inhibition of any secondary nucleation during homogeneous growth was controlled by adjusting the reaction conditions: temperature, gold precursor to seed particle concentration, and pH. This method presents improved results regarding the traditional Frens method in several aspects: (i) it produces particles of higher monodispersity; (ii) it allows better control of the gold nanoparticle size and size distribution; and (iii) it leads to higher concentrations. Gold nanoparticles synthesized following this method can be further functionalized with a wide variety of molecules, hence this method appears to be a promising candidate for application in the fields of biomedicine, photonics, and electronics, among others.
This paper references
Turkevich method for gold nanoparticle synthesis revisited.
J. Kimling (2006)
Mediating tumor targeting efficiency of nanoparticles through design.
Steven D. Perrault (2009)
Nanoparticles, Proteins, and Nucleic Acids: Biotechnology Meets Materials Science.
C. Niemeyer (2001)
Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15−300 nm
C. Ziegler (2011)
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols
V. Lamer (1950)
SERS-based diagnosis and biodetection.
R. Alvarez-Puebla (2010)
Hydroxylamine Seeding of Colloidal Au Nanoparticles in Solution and on Surfaces
Kenneth R. Brown and (1998)
Seeding Growth for Size Control of 5−40 nm Diameter Gold Nanoparticles
N. R. Jana (2001)
One-step seed-mediated growth of 30–150 nm quasispherical gold nanoparticles with 2-mercaptosuccinic acid as a new reducing agent
Jiali Niu (2007)
The Growth of Uniform Colloidal Dispersions
H. Reiss (1951)
Small Gold Nanoparticles Synthesized with Sodium Citrate and Heavy Water: Insights into the Reaction Mechanism
Isaac Ojea-Jiménez (2010)
A study of the nucleation and growth processes in the synthesis of colloidal gold
J. Turkevich (1951)
Hydroxylamine Seeding of Colloidal Au Nanoparticles. 3. Controlled Formation of Conductive Au Films
K. Brown (2000)
The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
K. Kelly (2003)
Distribution and potential toxicity of engineered inorganic nanoparticles and carbon nanostructures in biological systems
E. Casals (2008)
Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers
H. Sellers (1993)
Shuttling Gold Nanoparticles into Tumoral Cells with an Amphipathic Proline‐Rich Peptide
S. Pujals (2009)
Homogeneous conjugation of peptides onto gold nanoparticles enhances macrophage response.
Neus G Bastús (2009)
Determining the size and shape dependence of gold nanoparticle uptake into mammalian cells.
B. Chithrani (2006)
Biological applications of gold nanoparticles.
Ralph A. Sperling (2008)
Methods for describing the electromagnetic properties of silver and gold nanoparticles.
J. Zhao (2008)
Seeding of Colloidal Au Nanoparticle Solutions. 2. Improved Control of Particle Size and Shape
K. Brown (2000)
Monodisperse platinum nanospheres with adjustable diameters from 10 to 100 nm: synthesis and distinct optical properties.
N. C. Bigall (2008)
Gold nanoparticles: past, present, and future.
R. Sardar (2009)
Detoxification of gold nanorods by treatment with polystyrenesulfonate.
A. Leonov (2008)
Size control of gold nanocrystals in citrate reduction: the third role of citrate.
Xiaohui Ji (2007)
Preparation of monodispersed metal particles
D. Goia (1998)
Seeded growth of submicron Au colloids with quadrupole plasmon resonance modes.
J. Rodríguez-Fernández (2006)
Kinetics of II-VI and III-V Colloidal Semiconductor Nanocrystal Growth: “Focusing” of Size Distributions
X. Peng (1998)
Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.
M. Daniel (2004)
Synthesis and surface modification of highly monodispersed, spherical gold nanoparticles of 50-200 nm.
Steven D. Perrault (2009)
Synthesis of platinum cubes, polypods, cuboctahedrons, and raspberries assisted by cobalt nanocrystals.
Stephanie I. Lim (2010)
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Acoustic and photoacoustic characterization of micron-sized perfluorocarbon emulsions
E. Strohm (2012)
Compound semiconducting SnSb alloy anodes for Li ion batteries: Effect of elemental composition of Sn-Sb
L. Devaraj (2020)
Nanocrystal growth via the precipitation method
C. Fanelli (2019)
A quick one-step synthesis of luminescent gold nanospheres.
Angela Candreva (2020)
Designing of ordered two-dimensional gold nanoparticles film for cocaine detection in human urine using surface-enhanced Raman spectroscopy.
Juan Meng (2017)
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L. Ouyang (2019)
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Neus G Bastús (2019)
Unraveling the role of hydrogen peroxide in α-synuclein aggregation using an ultrasensitive nanoplasmonic probe.
Yan Xu (2015)
Self-assembly of gold supraparticles with crystallographically aligned and strongly coupled nanoparticle building blocks for SERS and photothermal therapy† †Electronic supplementary information (ESI) available: Fig. S1–S13. See DOI: 10.1039/c6sc02465c
S. Paterson (2016)
NANO EXPRESS Open Access
J. Lorbeer (2014)
Hydrogel-based Nanocomposite Plasmonic Sensors for Biomedical Applications
B. Miranda (2020)
Monitoring the multiphasic evolution of bismuth telluride nanoplatelets
Ahmed Subrati (2020)
Modification of Surface Bond Au Nanospheres by Chemically and Plasmonically Induced Pd Deposition
Heike Lisa Kerstin Stephanie Stolle (2021)
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K. Kim (2017)
Transition metal ion-assisted synthesis of monodisperse, quasi-spherical gold nanocrystals via citrate reduction
P. Zhang (2014)
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Lukas Steinmetz (2019)
Surfactant-dependant thermally induced nonlinear optical properties of L-ascorbic acid-stabilized colloidal GNPs and GNP–PVP thin films
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M. I. Setyawati (2017)
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P. Zhang (2016)
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