Online citations, reference lists, and bibliographies.
Referencing for people who value simplicity, privacy, and speed.
Get Citationsy
← Back to Search

Synthesis Of A Metallic Mesoporous Pyrochlore As A Catalyst For Lithium–O2 Batteries.

Si Hyoung Oh, Robert W. Black, E. Pomerantseva, Jin-hyon Lee, L. Nazar
Published 2012 · Chemistry, Medicine

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
The lithium–O2 ‘semi-fuel’ cell based on the reversible reaction of Li and O2 to form Li2O2 can theoretically provide energy densities that exceed those of Li-ion cells by up to a factor of five. A key limitation that differentiates it from other lithium batteries is that it requires effective catalysts (or ‘promoters’) to enable oxygen reduction and evolution. Here, we report the synthesis of a novel metallic mesoporous oxide using surfactant templating that shows promising catalytic activity and results in a cathode with a high reversible capacity of 10,000 mAh g(−1) (∼1,000 mAh g(−1) with respect to the total electrode weight including the peroxide product). This oxide also has a lower charge potential for oxygen evolution from Li2O2 than pure carbon. The properties are explained by the high fraction of surface defect active sites in the metallic oxide, and its unique morphology and variable oxygen stoichiometry. This strategy for creating porous metallic oxides may pave the way to new cathode architectures for the Li–O2 cell.
This paper references
10.1021/ja2021747
Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes.
S. Freunberger (2011)
10.1016/0025-5408(81)90112-4
New oxide pyrochlores: A2[B2−xAx]O7−y (A = Pb, Bi; B = Ru, Ir)
H. S. Horowitz (1981)
10.1021/ja1036572
Platinum-gold nanoparticles: a highly active bifunctional electrocatalyst for rechargeable lithium-air batteries.
Y. Lu (2010)
10.1016/0304-5102(86)87045-6
Dioxygen electrocatalysis: mechanisms in relation to catalyst structure
E. Yeager (1986)
10.1021/JA056811Q
Rechargeable LI2O2 electrode for lithium batteries.
Takeshi Ogasawara (2006)
10.1016/J.JCRYSGRO.2004.08.002
Flux growth and physical properties of pyrochlore Pb2Ru2O6.5 single crystals
T. Akazawa (2004)
10.5796/ELECTROCHEMISTRY.79.876
Design of Non-aqueous Liquid Electrolytes for Rechargeable Li-O2 Batteries
Fuminori Mizuno (2011)
10.1149/1.1836594
CoO2, The End Member of the Li x CoO2 Solid Solution
G. Amatucci (1996)
10.1038/nchem.1069
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries.
Jin Suntivich (2011)
10.1126/SCIENCE.279.5350.548
Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores
Y Zhao (1998)
10.1016/0167-2738(96)00330-X
Performance of Bellcore's plastic rechargeable Li-ion batteries
Jean-Marie Tarascon (1996)
10.1149/1.3430093
Air Dehydration Membranes for Nonaqueous Lithium–Air Batteries
J. Zhang (2010)
10.1021/ja2111543
Screening for superoxide reactivity in Li-O2 batteries: effect on Li2O2/LiOH crystallization.
Robert. Black (2012)
10.1016/0022-4596(88)90002-3
The electrical properties of A2[Ru2−xAx]O7−y (A = Pb or Bi) pyrochlores as a function of composition and temperature
R. Beyerlein (1988)
10.1002/anie.201102357
The lithium-oxygen battery with ether-based electrolytes.
S. Freunberger (2011)
10.1021/JP908090S
Elucidating the Mechanism of Oxygen Reduction for Lithium-Air Battery Applications
Cormac O. Laoire (2009)
10.1126/science.269.5228.1242
Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants
S. Bagshaw (1995)
10.1021/ja207229n
On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries.
B. McCloskey (2011)
10.1149/1.3005989
High-Capacity Lithium–Air Cathodes
S. Beattie (2009)
10.1021/nl902423a
Ordered mesoporous metallic MoO2 materials with highly reversible lithium storage capacity.
Yifeng Shi (2009)
10.1021/JP102019Y
Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium−Air Battery
Cormac O. Laoire (2010)
10.1039/C1EE01496J
All-carbon-nanofiber electrodes for high-energy rechargeable Li–O2 batteries
R. Mitchell (2011)
10.1149/1.1606454
Oxygen Transport Properties of Organic Electrolytes and Performance of Lithium/Oxygen Battery
J. Read (2003)
10.1021/JA00162A006
Surface protonation and electrochemical activity of oxides in aqueous solution
J. Goodenough (1990)
10.1149/1.2120111
Oxygen Electrocatalysis on Some Oxide Pyrochlores
H. S. Horowitz (1983)
10.1021/jp2073914
Predicting solvent stability in aprotic electrolyte Li-air batteries: nucleophilic substitution by the superoxide anion radical (O2(•-)).
V. S. Bryantsev (2011)
Nanomaterials : inorganic and bioinorganic perspectives
C. Lukehart (2008)
10.1149/1.3462981
Electrocatalytic Activity Studies of Select Metal Surfaces and Implications in Li-Air Batteries
Y. Lu (2010)
10.1149/1.3363047
The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries
Y. Lu (2010)
10.1021/JZ1005384
Lithium−Air Battery: Promise and Challenges
G. Girishkumar (2010)
10.1038/nchem.931
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts.
Fang-Yi Cheng (2011)
10.1039/C1EE01500A
The discharge rate capability of rechargeable Li–O2 batteries
Y. Lu (2011)
10.1002/AENM.201000010
Metal–Air Batteries with High Energy Density: Li–Air versus Zn–Air
J. Lee (2011)
10.1021/jz200352v
Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry.
B. McCloskey (2011)
10.5796/ELECTROCHEMISTRY.78.403
Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes
Fuminori Mizuno (2010)
10.1002/ADMA.200602499
Mesoporous Crystalline β‐MnO2—a Reversible Positive Electrode for Rechargeable Lithium Batteries
F. Jiao (2007)
10.1149/1.1393425
New Cathode Materials for Solid Oxide Fuel Cells Ruthenium Pyrochlores and Perovskites
T. Takeda (2000)
10.1038/NMAT1368
Nanostructured materials for advanced energy conversion and storage devices
A. Aricò (2005)
10.1149/1.3531981
Rechargeable Lithium/TEGDME- LiPF6 ∕ O2 Battery
Cormac O. Laoire (2011)
10.1016/0079-6786(83)90001-8
Oxide pyrochlores — A review
M. A. Subramanian (1983)
10.1002/ANIE.200603210
Ordered mesoporous copper oxide with crystalline walls.
Xiaoyong Lai (2007)
10.1149/1.1836378
A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
K. M. Abraham (1996)
10.1016/J.JPOWSOUR.2009.08.100
A review on air cathodes for zinc–air fuel cells
V. Neburchilov (2010)
10.1002/anie.200705648
Alpha-MnO2 nanowires: a catalyst for the O2 electrode in rechargeable lithium batteries.
A. Débart (2008)
10.1021/jz300243r
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li-O2 Batteries.
B. McCloskey (2012)
10.1149/1.3555366
Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells
L. Trahey (2011)
10.1021/JP2087412
Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes
Zheng-cheng Zhang (2011)



This paper is referenced by
10.1021/acsami.6b02402
A SnO2-Based Cathode Catalyst for Lithium-Air Batteries.
Delong Mei (2016)
10.1016/J.MSEB.2016.06.002
Overall conductivity and NCL-type relaxation behavior in nanocrystalline sodium peroxide Na2O2—Consequences for Na-oxygen batteries
A. Dunst (2016)
10.1002/anie.201808825
A Porous Pyrochlore Y2 [Ru1.6 Y0.4 ]O7-δ Electrocatalyst for Enhanced Performance towards the Oxygen Evolution Reaction in Acidic Media.
J. Kim (2018)
10.1016/J.JPCS.2017.11.030
Vibrational and elastic properties of Ln2Sn2O7 (Ln = La, Sm, Gd, Dy, Ho, Er, Yb, or Lu)
S. Akbudak (2018)
10.1002/smll.201800590
In Situ CVD Derived Co-N-C Composite as Highly Efficient Cathode for Flexible Li-O2 Batteries.
Z. Yang (2018)
10.1039/c5cc07884a
Reaction and degradation mechanism in all-solid-state lithium-air batteries.
H. Kitaura (2015)
10.1038/nchem.1516
Lithium-air batteries: Something from nothing.
Fangyi Cheng (2012)
10.1002/cssc.201500306
Synthesis of Porous δ-MnO2 Submicron Tubes as Highly Efficient Electrocatalyst for Rechargeable Li-O2 Batteries.
Peng Zhang (2015)
10.1002/chem.201403946
Synthesis of highly active and stable spinel-type oxygen evolution electrocatalysts by a rapid inorganic self-templating method.
T. Ma (2014)
10.1039/C5PY00482A
Highly stable membranes based on sulfonated fluorinated poly(ether ether ketone)s with bifunctional groups for vanadium flow battery application
Zhizhang Yuan (2015)
Non-Precious Metal Catalysts for Tuning Discharge Product Distribution at Solid-Solid Interfaces of Aprotic Li-O2 Batteries
S. Samira (2019)
10.6000/1929-6002.2013.02.04.1
Review on air cathode in Li-air batteries
WQ Han (2013)
10.1021/ACSCATAL.5B01196
Morphology and Active-Site Engineering for Stable Round-Trip Efficiency Li–O2 Batteries: A Search for the Most Active Catalytic Site in Co3O4
Kyeongse Song (2015)
10.1002/anie.201710156
Achilles' Heel of Lithium-Air Batteries: Lithium Carbonate.
Zhiwei Zhao (2018)
10.1021/acscentsci.7b00120
Nanoengineered Ultralight and Robust All-Metal Cathode for High-Capacity, Stable Lithium–Oxygen Batteries
J. Xu (2017)
10.1002/asia.201501102
Improving the Performance of Perovskite in Nonaqueous Oxygen Electrocatalysis.
M. Lu (2016)
10.1016/j.jelechem.2020.114654
High performance electrochemical L-cysteine sensor based on hierarchical 3D straw-bundle-like Mn-La oxides/reduced graphene oxide composite
Suling Yang (2020)
10.1016/j.actamat.2019.09.022
Thermodynamic and structural evolution of mechanically milled and swift heavy ion irradiated Er2Ti2O7 pyrochlore
C. Chung (2019)
10.2174/1570193X1203150429105418
M13 Bacteriophage-Based Self-Assembly Structures and Their Functional Capabilities
Jong-Sik Moon (2015)
10.5229/JECST.2014.5.2.58
Lyophobized Ordered Mesoporous Silica Additives for Li-O 2 Battery Cathode
Victor Roev (2014)
10.1016/J.SSI.2016.02.014
An effective three-dimensional ordered mesoporous CuCo2O4 as electrocatalyst for Li-O2 batteries
P. Li (2016)
10.1364/AOEE.2013.ASU3B.5
Fabrication and application of metallic nitrides as cathode electrocatalysts for rechargeable Li-O2 batteries
L. Zhang (2013)
10.1039/c4cc09808k
Rapid (<3 min) microwave synthesis of block copolymer templated ordered mesoporous metal oxide and carbonate films using nitrate-citric acid systems.
Yuanzhong Zhang (2015)
10.1039/C4EE00496E
Short-range Li diffusion vs. long-range ionic conduction in nanocrystalline lithium peroxide Li2O2—the discharge product in lithium-air batteries
A. Dunst (2014)
10.1039/c4cc07315k
A lithium air battery with a lithiated Al-carbon anode.
Ziyang Guo (2015)
10.1021/nn400477d
Ruthenium-based electrocatalysts supported on reduced graphene oxide for lithium-air batteries.
Hun-Gi Jung (2013)
10.1021/acsami.6b07989
Potassium Secondary Batteries.
A. Eftekhari (2017)
10.1002/9781119510000.ch6
Li–Air: Current Scenario and Its Future
S. Karuppiah (2019)
10.1039/C7QM00007C
Metal organic frameworks as precursors for the manufacture of advanced catalytic materials
Lide Oar-Arteta (2017)
10.1016/J.NANOEN.2015.10.027
Pd-functionalized MnOx–GeOy nanomembranes as highly efficient cathode materials for Li–O2 batteries
Xueyi Lu (2016)
10.1039/C6EE03046G
Single crystalline pyrochlore nanoparticles with metallic conduction as efficient bi-functional oxygen electrocatalysts for Zn–air batteries
Joohyuk Park (2017)
10.1016/J.JALLCOM.2018.06.318
Effect of Coulomb interactions on optoelectronic and magnetic properties of novel A2V2O7 (A= Fe and Co) compounds
M. Irfan (2018)
See more
Semantic Scholar Logo Some data provided by SemanticScholar