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Decarboxylative Reduction Of Free Aliphatic Carboxylic Acids By Photogenerated Cation Radical.

Y. Yoshimi, Tatsuya Itou, M. Hatanaka
Published 2007 · Chemistry, Medicine

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The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.
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