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Sodium Phosphaethynolate, Na(OCP), As A “P” Transfer Reagent For The Synthesis Of N-heterocyclic Carbene Supported P3and PAsP Radicals

Aaron M. Tondreau, Zoltán Benkő, Jeffrey R. Harmer, Hansjörg Grützmacher

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From Na(OCP) as a “P” transfer reagent, the radicals (NHC–P–E–P–NHC) (E = P, As) were synthesized and characterized as donor–acceptor adducts by EPR spectroscopy and DFT computations.