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Stereodivergent And Enantioselective Total Syntheses Of Isochaetominines A–C And Four Pairs Of Isochaetominine C Enantiomers: A Six-step Approach

Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang Huang

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We report the first total syntheses of (−)-isochaetominines A–C and eight 2,3-cis-stereoisomers of isochaetominine C, and structural revisions of (−)-pseudofischerine and (−)-aniquinazoline D.