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Trifluoromethanesulfonyl Azide As A Bifunctional Reagent For Metal-free Azidotrifluoromethylation Of Unactivated Alkenes

Hong-Gui Huang, Weishuang Li, Dayou Zhong, Hu-Chong Wang, Jing Zhao, Wen-Bo Liu

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A two-component and metal-free azidotrifluoromethylation of alkenes is realized using readily synthesized trifluoromethanesulfonyl azide (N3SO2CF3) as a bifunctional reagent for both CF3 and N3 groups.