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Synthesis Of 3-trifluoromethylpyrazoles Via Trifluoromethylation/cyclization Of α,β-alkynic Hydrazones Using A Hypervalent Iodine Reagent

Guojing Ji, Xi Wang, Songnan Zhang, Yan Xu, Yuxuan Ye, Ming Li, Yan Zhang, Jianbo Wang

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A mild and efficient method for the synthesis of 3-trifluoromethylpyrazoles has been established via trifluoromethylation/cyclization of α,β-alkynic hydrazones using a hypervalent iodine reagent.