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Synthesis Of Poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt) By The RAFT Process And Preparation Of Organic-solvent-dispersive Ag NPs By Automatic Reduction Of Metal Ions In The Presence Of PDHSt-b-PSt.

Y. Saito, H. Yabu
Published 2015 · Chemistry, Medicine

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We proposed a block copolymer, poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt), that contains catechol groups in the side chains of PDHSt moieties. Since catechol groups automatically reduce silver (Ag) ions to their metallic state, the block copolymer was used as a reductant to synthesize organic-solvent-dispersive Ag NPs (NPs) stabilized with the block copolymer at room temperature. Ag NP sizes were controlled by changing molecular weights of PDHSt of the block copolymer.
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