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Effect Of Conformational Rigidity On The Stereoselectivity Of Nucleophilic Additions To Five-membered Ring Bicyclic Oxocarbenium Ion Intermediates

Olga Lavinda, Vi Tuong Tran, K. A. Woerpel

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Nucleophilic substitution reactions of five-membered ring acetals bearing fused rings reveal that subtle changes in the structure of the fused ring can exert dramatic influences on selectivity.