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Dynamic Covalent Assembly And Disassembly Of Nanoparticle Aggregates

Stefan Borsley, Euan R. Kay

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A new type of dynamic covalent nanoparticle (NP) building block is reported, exhibiting rapid constitutional adaptation in a NP-bound monolayer of boronate esters, and formation of covalently linked NP assemblies, which despite being connected by covalent bonds, can be fully disassembled on application of a chemical stimulus.