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Why Does Togni's Reagent I Exist In The High-energy Hypervalent Iodine Form? Re-evaluation Of Benziodoxole Based Hypervalent Iodine Reagents

Tian-Yu Sun, Xiao Wang, Hao Geng, Yaoming Xie, Yun-Dong Wu, Xinhao Zhang, Henry F. Schaefer III

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For Togni's reagent I, the high energy barrier could prevent it from converting to its ether isomer. This might be one reason why it exists in the high-energy hypervalent iodine form.