Online citations, reference lists, and bibliographies.
← Back to Search

Convenient Synthesis Of Allenylphosphoryl Compounds Via Cu-catalysed Couplings Of P(O)H Compounds With Propargyl Acetates

Ruwei Shen, Bing Luo, Jianlin Yang, Lixiong Zhang, Li-Biao Han

Cite This
Download PDF
Analyze on Scholarcy

A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds in high yields. A plausible mechanism involving the nucleophilic interception of Cu-allenylidene intermediates is proposed.