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A Versatile Glycosylation Strategy Via Au(iii) Catalyzed Activation Of Thioglycoside Donors

Amol M. Vibhute, Arun Dhaka, Vignesh Athiyarath, Kana M. Sureshan

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We report a mild, versatile and high yielding glycosylation method via activation of thioglycoside donors using a Au(iii) catalyst and without using any co-promoter. Both armed and disarmed donors could be activated by this method and the anomeric selectivity could be tuned by changing the solvents.