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Self-assembly Of Diphenylalanine With Preclick Components As Capping Groups

Andrea Gemma, Enric Mayans, Gema Ballano, Juan Torras, Angélica Díaz, Ana I. Jiménez, Jordi Puiggalí, Carlos Cativiela, Carlos Alemán

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Alkyne and azide, which are commonly used in the cycloaddition reaction recognized as “click chemistry”, have been used as capping groups of two engineered diphenylalanine (FF) derivatives due to their ability to form weak intermolecular interactions (i.e. dipole–π and π–π stacking).