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Ni-catalysed Regioselective 1,2-diarylation Of Unactivated Olefins By Stabilizing Heck Intermediates As Pyridylsilyl-coordinated Transient Metallacycles

Surendra Thapa, Roshan K. Dhungana, Rajani Thapa Magar, Bijay Shrestha, Shekhar KC, Ramesh Giri

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Ni-catalysed diarylation of vinylpyridylsilanes with arylzinc reagents and aryl halides is reported by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles.