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C-F Bond Activation By Pentamethylcyclopentadienyl-aluminium(i): A Combined Experimental/computational Exercise.

O. Kysliak, H. Görls, R. Kretschmer
Published 2020 · Medicine, Chemistry

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The reaction of (Cp*Al)4 with a series of fluoro(hetero)arenes has been investigated and C-F bond activation was observed with perfluorotoluene, pentafluoropyridine as well as 1,2,3,4-tetrafluoro-, pentafluoro- and hexafluorobenzene. The reaction mechanism has been probed by means of DFT calculations and the computational findings are in good agreement with the experimental observations.
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