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Dimerization Of Terminal Alkynes Promoted By A Heterobimetallic Zr/Co Complex

Jeffrey W. Beattie, Canning Wang, Hongtu Zhang, Jeremy P. Krogman, Bruce M. Foxman, Christine M. Thomas

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A reduced ZrIV/Co−I heterobimetallic complex facilitates the formation of 1,3-enynes from terminal alkynes through a cooperative bimetallic C–H activation process.