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Salt Metathesis As An Alternative Approach To Access Aluminium(i) And Gallium(i) β-diketiminates

Oleksandr Kysliak, Helmar Görls, Robert Kretschmer

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Aluminium(i) and gallium(i) β-diketiminates are accessed by a new route that provides better overall yields. In the case of aluminium it is also much faster, but some molecules turn into a dead end and merge into a dinuclear aluminium(iii) hydride.