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Solution Size Variation Of Linear And Dendritic Bis-MPA Analogs Using DOSY-1H NMR

Oluwapelumi O. Kareem, Farzin Rahmani, Jason A. Hyman, Christopher B. Keller, Melissa A. Pasquinelli, Daniel A. Savin, Scott M. Grayson

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The size and size variability of bis-MPA dendrimers is shown to be smaller by DOSY-1H NMR than their linear analog, PBBM. This was accomplished using five different solvents and for the first time confirms, experimentally, what has been theorized.