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The Electronic Structure Of FeV-cofactor In Vanadium-dependent Nitrogenase

Zhi-Yong Yang, Emilio Jimenez-Vicente, Hayden Kallas, Dmitriy A. Lukoyanov, Hao Yang, Julia S. Martin del Campo, Dennis R. Dean, Brian M. Hoffman, Lance C. Seefeldt

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Active site FeV-cofactor of the V-nitrogenase and the EPR spectrum of the reduced cofactor showing 51V-hyperfine coupling.