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Excited-state Dynamics Of Alizarin-sensitized TiO2 Nanoparticles From Resonance Raman Spectroscopy

Lian C. T. Shoute, G. R. Loppnow
Published 2002 · Chemistry

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Resonance Raman spectra of alizarin-sensitized TiO2 nanoparticles have been obtained at excitation wavelengths throughout the 488-nm charge transfer absorption band. The resonance Raman spectrum of the alizarin-sensitized TiO2 nanoparticle is significantly different from the spectrum of free alizarin, consistent with a chemisorption-type interaction. This interaction is probably chelation of surface titanium ions by the hydroxy groups of alizarin, supported by the observed enhancement of bridging C–O modes at 1326 cm−1. In contrast to resonance Raman intensity analysis of homogeneous electron transfer where vibrations of both the donor and acceptor are observed, self-consistent analysis of the resulting resonance Raman excitation profiles and absorption spectrum using the time-dependent wave packet propagation formalism show mode-specific reorganization along alizarin vibrations exclusively; no resonance-enhanced vibrations attributable to the TiO2 moiety are observed. Therefore, the total resonance Raman...
This paper references
10.1021/AR000007L
Subpicosecond solvent dynamics in charge-transfer transitions: challenges and opportunities in resonance Raman spectroscopy.
J. L. McHale (2001)
10.1002/(SICI)1521-3765(20000103)6:1<33::AID-CHEM33>3.0.CO;2-7
Energy-gap dependence of photoinduced charge separation and subsequent charge recombination in 1,4-phenylene-bridged zinc--free-base hybrid porphyrins
Osuka (2000)
10.1146/ANNUREV.PC.41.100190.003243
Femtosecond Optical Spectroscopy: A Direct Look at Elementary Chemical Events
S. Mukamel (1990)
10.1016/0301-0104(93)80257-A
Observation of temperature independent heterogeneous electron transfer reactions in the inverted Marcus region
J. Moser (1993)
10.1021/J100094A008
Ultrafast nonlinear optical studies of surface reaction dynamics: Mapping the electron trajectory
Joseph M. Lanzafame (1994)
10.1016/0013-4686(91)85044-8
Experimental assessment of dynamic structural parameters for homogeneous and interfacial charge-transfer reactions: case studies based on time-dependent Raman scattering methods
S. Doorn (1991)
10.1021/JP993438Y
Electron Injection, Recombination, and Halide Oxidation Dynamics at Dye-Sensitized Metal Oxide Interfaces
Todd A. Heimer (2000)
10.1021/JP9938009
Resonance Raman Intensity Analysis of the Carbazole/Tetracyanoethylene Charge-Transfer Complex: Mode-Specific Reorganization Energies for a Hole-Transport Molecule†
Debra S. Egolf (2000)
10.1246/BCSJ.49.1409
Chelation effect of alizarin dyes on the semiconductor-aqueous solution systems.
M. Matsumura (1976)
10.1016/0927-0248(96)00063-3
Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder
A. Kay (1996)
10.1021/JP992774B
Electron injection and recombination in dye sensitized nanocrystalline titanium dioxide films: A comparison of ruthenium bipyridyl and porphyrin sensitizer dyes
Y. Tachibana (2000)
10.1021/AR9602720
Using resonance Raman spectroscopy to examine vibrational barriers to electron transfer and electronic delocalization.
J. Hupp (2001)
10.1063/1.432142
Temperature dependent activation energy for electron transfer between biological molecules
J. Jortner (1976)
10.1021/JA9900454
Large Acceleration Effect of Photoinduced Electron Transfer in Porphyrin−Quinone Dyads with a Rigid Spacer Involving a Dihalosubstituted Three-Membered Ring
H. Tsue (2000)
10.1021/JP953720E
Physical Chemistry of Semiconductor−Liquid Interfaces
A. Nozik (1996)
10.1021/J100124A027
Pathways for photoinduced electron transfer within a mixed-metal bisporphyrin
A. Harriman (1993)
10.1201/b16936-17
Biological applications of Raman spectroscopy
T. Spiro (1987)
10.1002/JRS.1250050203
Resonance Raman spectra of a peroxotitanium (IV) cation in aqueous solution
V. Peruzzo (1976)
10.1021/JP983915X
Femtosecond IR Study of Excited-State Relaxation and Electron-Injection Dynamics of Ru(dcbpy)2(NCS)2 in Solution and on Nanocrystalline TiO2 and Al2O3 Thin Films
J. Asbury (1999)
10.1016/0304-4173(85)90014-X
Electron transfers in chemistry and biology
R. Marcus (1985)
10.1021/JP002010S
Electron Injection and Recombination in Fluorescein 27-Sensitized TiO2 Thin Films
Gábor Benko (2001)
10.1063/1.477792
Resonance Raman intensity analysis of a dicyanovinyl-azaadamantane: Mode-specific reorganization energies for charge-transfer and locally-excited states
M. Lilichenko (1998)
10.1021/JP9944381
The Role of Surface States in the Ultrafast Photoinduced Electron Transfer from Sensitizing Dye Molecules to Semiconductor Colloids
R. Huber (2000)
10.1016/0301-0104(85)85069-2
Single crystal and polarized infrared spectra of two forms of 1,8-dihydroxyanthraquinone vibrational assignment and crystal structures
G. Smulevich (1985)
10.1021/J100329A027
Preparation and characterization of quantum-size titanium dioxide
C. Kormann (1988)
10.1016/0022-2860(89)80074-2
Raman spectroscopic studies of substituted bipyridines, their ruthenium(II) complexes and surface-derivatized TiO2
S. Umapathy (1989)
10.1016/c2009-0-02601-4
The Photosynthetic Reaction Center
J. Deisenhofer (1993)
10.1016/0301-0104(82)85207-5
Resonance Raman and polarized light infrared spectra of 1,4-dihydroxyanthraquinone. vibrational studies of the ground and excited electronic states
G. Smulevich (1982)
10.1016/S0166-1280(97)00216-9
Reorganization energies in organic π systems
S. Larsson (1998)
10.1021/JP991530O
Resonance Raman Intensity Analysis of Vibrational and Solvent Reorganization in Photoinduced Charge Transfer
A. Kelley (1999)
10.1021/J100035A016
The Kinetics of Electron Transfer Through Ferrocene-Terminated Alkanethiol Monolayers on Gold
J. F. Smalley (1995)
10.1021/J100125A029
Artificial photosynthesis. 1. Photosensitization of titania solar cells with chlorophyll derivatives and related natural porphyrins
A. Kay (1993)
10.1039/FT9938902397
Excited-state properties and photosensitization behaviour of bis(2,4-dihydroxyphenyl)squaraine
P. Kamat (1993)
10.1016/s0167-2991(97)x8001-2
Semiconductor nanoclusters-physical, chemical, and catalytic aspects
P. Kamat (1997)
10.1038/280571a0
Chemical modification of a titanium (IV) oxide electrode to give stable dye sensitisation without a supersensitiser
S. Anderson (1979)
10.1021/JA00066A036
Intramolecular photoinduced charge separation and charge recombination of the product ion pair states of a series of fixed-distance dyads of porphyrins and quinones: energy gap and temperature dependences of the rate constants
T. Asahi (1993)
10.1021/JP003485M
Ultrafast Electron Transfer Dynamics from Molecular Adsorbates to Semiconductor Nanocrystalline Thin Films
J. Asbury (2001)
10.1016/S0009-2614(01)00398-0
Transient absorption studies of the Ru(dcbpy)2(NCS)2 excited state and the dye cation on nanocrystalline TiO2 film
J. Kallioinen (2001)
10.1021/JP982740O
Effect of Structure on Electron Transfer Reactions between Anthracene Dyes and TiO2 Nanoparticles
I. B. Martini (1998)
10.1021/JP9525651
Charge-Transfer Dynamics in Plastocyanin, a Blue Copper Protein, from Resonance Raman Intensities
E. Fraga (1996)
Laser techniques in chemistry
A. Myers (1995)
Surface Electron Transfer Processes
R. Miller (1995)
10.1021/J100050A008
Spectroscopic, Kinetic, and Thermodynamic Deuterium Isotope Effects in the Hexamethylbenzene/Tetracyanoethylene Charge-Transfer Complex
K. Kulinowski (1995)
10.1021/CR00033A003
Light-Induced Redox Reactions in Nanocrystalline Systems
A. Hagfeldt (1995)
10.1016/S0006-3495(88)82928-X
Excited-state structure and isomerization dynamics of the retinal chromophore in rhodopsin from resonance Raman intensities.
G. R. Loppnow (1988)
10.1021/LA00060A018
Surface complexation of colloidal semiconductors strongly enhances interfacial electron-transfer rates
Jacques-E. Moser (1991)
10.1002/JRS.1250070606
Raman spectrum of anatase, TiO2
T. Ohsaka (1978)
10.1021/JA003299U
Engineering of efficient panchromatic sensitizers for nanocrystalline TiO(2)-based solar cells.
M. Nazeeruddin (2001)
10.1016/S0022-3697(00)00229-8
Raman spectroscopy and phase transition of anatase TiO2 under high pressure
T. Sekiya (2001)
10.1021/J150608A016
Resonance Raman spectra of adsorbed species at solid-gas interfaces. 2. p-Nitrosodimethylaniline and p-dimethylaminoazobenzene adsorbed on semiconductor oxide surfaces
J. Brazdil (1981)
10.1021/J100389A007
Time-resolved resonance Raman spectroscopic studies of the photosensitization of colloidal titanium dioxide
S. Umapathy (1990)
10.1021/JA00003A060
Surface intervalence enhanced Raman scattering from ferrocyanide on colloidal titanium dioxide. A mode-by-mode description of the Franck-Condon barrier to interfacial charge transfer
R. L. Blackbourn (1991)
10.1021/CR950249C
Resonance Raman Intensities and Charge-Transfer Reorganization Energies.
A. Myers (1996)
10.1021/JP981806C
DIRECT OBSERVATION OF ULTRAFAST ELECTRON INJECTION FROM COUMARIN 343 TO TIO2 NANOPARTICLES BY FEMTOSECOND INFRARED SPECTROSCOPY
H. Ghosh (1998)
10.1016/0301-0104(90)80027-U
Ultrafast electron injection from excited dye molecules into semiconductor electrodes
R. Eichberger (1990)
10.1016/0301-0104(87)80211-2
Photoinduced electron transfer in pyromellitimide-bridged porphyrins
R. Harrison (1987)
10.1021/J100252A017
Spectral and photophysical properties of Ru(bpy)32+ adsorbed onto porous Vycor glass
S. Wei (1985)
10.1021/LA001651B
Phthalocyanine-Sensitized Nanostructured TiO2 Electrodes Prepared by a Novel Anchoring Method
J. He (2001)
10.1038/353737A0
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
B. O'Regan (1991)



This paper is referenced by
10.1002/cphc.200800752
Electron transfer from photoexcited TiO2 to chelating alizarin molecules: reversible photochromic effect in alizarin@TiO2 under UV irradiation.
Yesica Di Iorio (2009)
10.1560/U3GF-G11X-325D-0WJ1
Thermal effects in the ultrafast photoinduced electron transfer from a molecular donor anchored to a semiconductor acceptor
W. Stier (2002)
10.1021/jp205166j
Initial excited-state structural dynamics of 2'-deoxyguanosine determined via UV resonance Raman spectroscopy.
A. F. El-Yazbi (2011)
10.1021/bm301908y
Adhesion of mussel foot protein-3 to TiO2 surfaces: the effect of pH.
J. Yu (2013)
10.1021/JP310155Q
Spectroscopy and Dynamics of Phosphonate-Derivatized Ruthenium Complexes on TiO2
P. Giokas (2013)
10.1039/c2cp40080d
Surface-Enhanced Raman Scattering (SERS) on transition metal and semiconductor nanostructures.
X. Wang (2012)
10.1039/c4cp05794e
Effect of TiO2 particles on normal and resonance Raman spectra of coumarin 343: a theoretical investigation.
L. Yang (2015)
10.1021/jp301952v
Initial excited-state structural dynamics of thymine derivatives.
B. Billinghurst (2012)
10.1021/JP710252H
Electronic Excited State of Alizarin Dye Adsorbed on TiO2 Nanoparticles: A Study by Electroabsorption (Stark Effect) Spectroscopy
A. Nawrocka (2008)
Vibrational spectroscopy of photosensitizer dyes for organic solar cells
C. León (2005)
10.1016/J.APMT.2018.02.002
Noble metals-TiO2 nanocomposites: From fundamental mechanisms to photocatalysis, surface enhanced Raman scattering and antibacterial applications
J. Prakash (2018)
10.1016/J.SURFREP.2011.01.001
A surface science perspective on TiO2 photocatalysis
M. Henderson (2011)
10.1021/jp410781y
Probing Raman enhancement in a dopamine-Ti2O4 hybrid using stretched molecular geometries.
I. Urdaneta (2014)
10.1117/12.503646
Ab initio molecular dynamics of ultrafast electron injection from molecular donors to the TiO2 acceptor
W. Stier (2003)
10.1021/jp1095294
Initial excited-state structural dynamics of 9-methyladenine from UV resonance Raman spectroscopy.
Sulayman A Oladepo (2011)
10.1063/1.1796274
Laser pulse control of ultrafast heterogeneous electron transfer: a computational study.
L. Wang (2004)
10.1002/9783527645404.CH8
Sensitization of Titania Semiconductor: A Promising Strategy to Utilize Visible Light
Z. Wang (2013)
10.1002/asia.201000033
Strongly absorbing pi-pi* states in heteroleptic dipyrrin/2,2'-bipyridine ruthenium complexes: excited-state dynamics from resonance raman spectroscopy.
T. M. McLean (2010)
10.1021/ACS.JPCC.6B01960
Dispersive Electron-Transfer Kinetics of Rhodamines on TiO2: Impact of Structure and Driving Force on Single-Molecule Photophysics
J. Tan (2016)
10.1002/asia.201100934
Surface-enhanced Raman scattering (SERS) of nitrothiophenol isomers chemisorbed on TiO2.
J. S. Teguh (2012)
10.1063/1.3615057
Theoretical investigation of resonance Raman scattering of dye molecules absorbed on semiconductor surfaces.
Y. Zhao (2011)
10.1039/c4sc02618g
Semiconductor-driven “turn-off” surface-enhanced Raman scattering spectroscopy: application in selective determination of chromium(vi) in water† †Electronic supplementary information (ESI) available: Detailed Benesi–Hildebrand plot, IR spectra, Raman assignments, and experiment optimization. See DOI
W. Ji (2015)
10.1021/JP8040742
Photoinduced Reactivity of Strongly Coupled TiO2 Ligands under Visible Irradiation : An Examination of an Alizarin Red@TiO2 Nanoparticulate System
Y. D. Iorio (2008)
10.14279/DEPOSITONCE-9585
Combined vibrational spectroscopy and electrochemistry for studying biological and materials systems
C. J. Querebillo (2020)
10.1366/000370206779321337
Degradation of Curcumin Dye in Aqueous Solution and on Ag Nanoparticles Studied by Ultraviolet—Visible Absorption and Surface-Enhanced Raman Spectroscopy
M. V. Cañamares (2006)
10.1021/jacs.5b10253
Probing Electric Field Effect on Covalent Interactions at a Molecule-Semiconductor Interface.
Papatya C Sevinç (2016)
10.1021/nl104160n
Simultaneous spectroscopic and topographic near-field imaging of TiO2 single surface states and interfacial electronic coupling.
Papatya C Sevinç (2011)
10.1021/ja808277u
SERS of semiconducting nanoparticles (TiO(2) hybrid composites).
Anthony Musumeci (2009)
10.1002/QUA.20885
Computational study of titanium (IV) complexes with organic chromophores
Ivan Kondov (2006)
10.1016/J.VIBSPEC.2012.09.003
The use of infrared and Raman microspectroscopy for identification of selected red organic dyes in model colour layers of works of art
E. Svobodová (2012)
10.1002/cphc.201000351
Multilayer substrate-mediated tuning resonance of plasmon and SERS EF of nanostructured silver.
L. Shoute (2010)
10.1063/1.5021024
Density functional theory study of atomic and electronic properties of defects in reduced anatase TiO2 nanocrystals
K. Morita (2018)
See more
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