Online citations, reference lists, and bibliographies.
← Back to Search

Controlled Facile Synthesis, Growth Mechanism, And Exothermic Properties Of Large-area Co3O4 Nanowalls And Nanowires On Silicon Substrates

Z. Qiao, D. Xu, Fude Nie, Guangcheng Yang, K. Zhang
Published 2012 · Physics

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Co3O4 nanowalls and nanowires have been synthesized onto silicon substrates by low-temperature thermal oxidation of sputtered Co thin films in static air. The synthesis method is very simple and suitable for large-scale fabrication. The effects of the thermal oxidation temperature and duration on the size, amount, and length of the nanowires and nanowalls are systematically investigated both by scanning electron microscopy characterization and differential scanning calorimetry thermal analysis. It is found that the Co/CoO oxidation and Co3O4 decomposition are important factors contributing to the growth of the Co3O4 nanowalls and nanowires. The mechanical adhesion between the Co3O4 nanowalls/nanowires/film and the silicon substrate is observed to be very strong, which is beneficial for many practical applications. Based on the experimental observations, the detailed growth mechanisms of the nanowalls and nanowires are presented. Finally, the promising novel exothermic reaction properties of the Co3O4 nano...
This paper references
10.1109/JMEMS.2007.893519
Nanoenergetic Materials for MEMS: A Review
C. Rossi (2007)
10.1088/0957-4484/18/27/275607
Synthesis of large-area and aligned copper oxide nanowires from copper thin film on silicon substrate
K. Zhang (2007)
10.1021/NL0725906
Mesoporous Co3O4 nanowire arrays for lithium ion batteries with high capacity and rate capability.
Y. Li (2008)
10.1021/LA049887T
Surface modification studies of edge-oriented molybdenum sulfide nanosheets.
Heng Zhang (2004)
10.1016/J.PROCI.2010.05.048
Synthesis and ignition of energetic CuO/Al core/shell nanowires
Y. Ohkura (2011)
10.1021/NL035166N
Growth and Structure of Chemically Vapor Deposited Ge Nanowires on Si Substrates
T. Kamins (2004)
10.1016/J.PECS.2008.09.001
Metal-based reactive nanomaterials
E. Dreizin (2009)
10.1361/105497103770330514
Thermodynamic assessment of the Co-O system
M. Chen (2003)
10.1063/1.325359
Interactions in the Co/Si thin‐film system. I. Kinetics
S. Lau (1978)
10.1088/0957-4484/19/15/155606
Rapid, low-temperature synthesis of single-crystalline Co(3)O(4) nanorods on silicon substrates on a large scale.
Longbing He (2008)
10.1016/J.ACTAMAT.2010.07.008
Synthesis, growth mechanism and gas-sensing properties of large-scale CuO nanowires
M. Zhong (2010)
10.1002/1521-4095(20020104)14:1<64::AID-ADMA64>3.0.CO;2-G
Carbon Nanowalls Grown by Microwave Plasma Enhanced Chemical Vapor Deposition
Y. Wu (2002)
10.1002/ADMA.200400833
Beaded Cobalt Oxide Nanoparticles along Carbon Nanotubes: Towards More Highly Integrated Electronic Devices
L. Fu (2005)
10.1016/J.APENERGY.2010.07.010
Development of micro power generators – A review
Siaw Kiang Chou (2011)
10.1039/A700125H
Optical recognition of CO and H2 by use of gas-sensitiveAu–Co3O4 composite films
M. Ando (1997)
10.1002/ADMA.200500322
Controlled Growth and Field‐Emission Properties of Cobalt Oxide Nanowalls
T. Yu (2005)
10.1039/A804767G
Thermal evolution of cobalt hydroxides: a comparative study of their various structural phases
Z. P. Xu (1998)
10.1063/1.2643979
Enhanced field emission properties from well-aligned zinc oxide nanoneedles grown on the Au∕Ti∕n-Si substrate
C. J. Park (2007)
10.1126/SCIENCE.1122716
Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes
K. Nam (2006)
10.1021/JP063484F
Optical CO gas sensor using a cobalt oxide thin film prepared by pulsed laser deposition under various argon pressures.
Hyun-Jeong Nam (2006)
10.1088/0957-4484/21/23/235602
Local and CMOS-compatible synthesis of CuO nanowires on a suspended microheater on a silicon substrate.
K. Zhang (2010)
10.1021/NL060883D
Direct formation of catalyst-free ZnO nanobridge devices on an etched Si substrate using a thermal evaporation method.
J. S. Lee (2006)
10.1070/RC2008V077N01ABEH003748
Exothermic reaction waves in multilayer nanofilms
A. Rogachev (2008)
10.1002/PREP.200400085
Combustion Behavior of Highly Energetic Thermites: Nano versus Micron Composites
M. Pantoya (2005)
10.1016/S0009-2614(01)00768-0
Solid–liquid–solid (SLS) growth of coaxial nanocables: silicon carbide sheathed with silicon oxide
Yingjie Xing (2001)
10.1088/0022-3719/21/7/007
The Raman spectra of Co3O4
V. G. Hadjiev (1988)
10.1063/1.2072847
Superconducting NbSe 2 nanowires and nanoribbons converted from NbSe 3 nanostructures
Y. Hor (2005)
10.1063/1.360923
Dominant diffusing species during cobalt silicide formation
C. Comrie (1996)
10.1002/1521-4095(20020805)14:15<1029::AID-ADMA1029>3.0.CO;2-3
Junctions and Networks of SnO Nanoribbons
Z. Wang (2002)
10.1149/1.1836646
Electrochromic Properties of Cobalt Oxide Thin Films Prepared by Chemical Vapor Deposition
T. Maruyama (1996)
10.1021/JA065308Q
Freestanding mesoporous quasi-single-crystalline CO3O4 nanowire arrays.
Y. Li (2006)
10.1146/ANNUREV.MATSCI.31.1.291
Design and Synthesis of Energetic Materials1
L. Fried (2001)
10.1007/S12274-010-0063-Z
A facile method to improve the high rate capability of Co3O4 nanowire array electrodes
H. Cheng (2010)
10.1088/0957-4484/19/15/155605
Synthesis of NiO nanowalls by thermal treatment of Ni film deposited onto a stainless steel substrate.
K. Zhang (2008)
10.1002/ADFM.200400429
Co3O4 nanomaterials in lithium-ion batteries and gas sensors
Weiyang Li (2005)
10.1021/nl202539m
Localized joule heating as a mask-free technique for the local synthesis of ZnO nanowires on silicon nanodevices.
C. Chen (2011)
10.1088/0957-4484/22/10/105605
Oxidative fabrication of patterned, large, non-flaking CuO nanowire arrays.
F. Mumm (2011)
10.1021/JP075365L
Synthesis and Physical Properties of Co3O4 Nanowires
Z. Dong (2007)
10.1002/ADMA.200304918
Organic Semiconductor Nanowires for Field Emission
Jiann-Jong Chiu (2003)
10.1038/nature07877
Low-temperature oxidation of CO catalysed by Co3O4 nanorods
X. Xie (2009)
10.1016/J.CATCOM.2005.02.006
Co3O4/CeO2 and Co3O4/CeO2–ZrO2 composite catalysts for methane combustion: Correlation between morphology reduction properties and catalytic activity
L. Liotta (2005)



This paper is referenced by
10.1016/J.APSUSC.2018.02.104
Construct 3D porous hollow Co 3 O 4 micro-sphere: A potential oxidizer of nano-energetic materials with superior reactivity
J. Wang (2018)
10.5755/J01.MS.24.2.18266
Firing and Initiation Characteristics of Energetic Semiconductor Bridge Integrated with Varied Thickness of Al/MoO3 Nanofilms
P. Zhu (2018)
10.1016/J.JALLCOM.2017.07.081
Thermite synthesis, structural and magnetic properties of Co-Al2O3 nanocomposite films
V. G. Myagkov (2017)
10.1063/1.4876264
Energetic semiconductor bridge device incorporating Al/MoOx multilayer nanofilms and negative temperature coefficient thermistor chip
P. Zhu (2014)
10.1039/c7nr01789h
Rapid, all dry microfabrication of three-dimensional Co3O4/Pt nanonetworks for high-performance microsupercapacitors.
X. Ma (2017)
10.1016/J.CERAMINT.2014.07.032
Large-scale synthesis of aligned Co3O4 nanowalls on nickel foam and their electrochemical performance for Li-ion batteries
Lizhi Xiong (2014)
10.1007/s11356-019-06974-2
Structured cobalt oxide catalysts for VOC abatement: the effect of preparation method
P. Topka (2019)
10.1016/J.JALLCOM.2017.02.004
Structural and morphological evolution of free-standing Co3O4 nanowires via water vapor-assisted thermal oxidation of Co foil
Y. Li (2017)
10.1002/BKCS.10853
Electrochemical Preparation of Ru/Co Bi‐layered Catalysts on Ti Substrates for the Oxygen Evolution Reaction
J. Y. Kim (2016)
10.1016/J.COMBUSTFLAME.2014.04.015
Pressure loss and compensation in the combustion process of Al-CuO nanoenergetics on a microheater chip
J. Shen (2014)
10.1039/C4RA15476B
Micropatterning of nanoenergetic films of Bi2O3/Al for pyrotechnics
V. Patel (2015)
10.1007/s10853-018-3044-3
In situ synthesis of energetic metal–organic frameworks [Cd5(Mtta)9]n film exhibiting excellent ignition capability
W. Liu (2018)
Semantic Scholar Logo Some data provided by SemanticScholar