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Reaction Of N-halosulfoximines With Disulfides

T. Akasaka, N. Furukawa, S. Ōae
Published 1985 · Chemistry

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Abstract The reaction of S,S-diphenyl-N-chloro-(1), S,S-diphenyl-N-bromo-(2), and S-methyl-S-phenyl-N-chloro-sulfoximine (5) with disulfides in refluxing carbon tetrachloride was found to afford the corresponding sulfoxides. In the presence of pyridine, 1 and 2 reacted with disulfides at room temperature to give the corresponding bis-diphenylsulfoximinyl alkyl or aryl sulfonium halides arising from the reaction of the intermediary N-sulfenylated sulfoximine and the starting N-halosulfoximine.
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