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Photodegradation Of The Antibiotic Sulphamethoxazole In Water With UV/H2O2 Advanced Oxidation Process

Y. Lester, D. Avisar, H. Mamane
Published 2010 · Medicine, Chemistry

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Photodegradation of the antibiotic sulphamethoxazole (SMX) in water using a medium‐pressure UV lamp combined with H2O2 (UV/H2O2) was used to generate the advanced oxidation process (AOP). The photodegradation process was steadily improved with addition of H2O2 at relatively low to moderate concentrations (5 to 50 mg L−1). However, the addition of H2O2 to the photolysis process at higher concentrations (50 to 150 mg L−1) did not improve the degradation rate of SMX (in comparison with 50 mg L−1 H2O2). Addition of H2O2 to the UV photolysis process resulted in several processes occurring concurrently as follows: (a) formation of HO· radicals which contributed to the SMX degradation, (b) decrease in the available light for direct UV photolysis of SMX, and (c) scavenging of the HO· radicals by H2O2, which was highly dominant at moderate to high concentrations of H2O2. It is clear that these factors, separately and synergistically, and possibly others such as by‐product formation, affect the overall difference in SMX degradation in the AOP process at different H2O2 concentrations.
This paper references
Corftizen, Reactions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures
H. Christensen (1982)
Reactions of Hydroxyl Radicals with Hydrogen Peroxide at Ambient and Elevated Temperatures
H. Christensen (1982)
Degradation of nitroaromatic compounds by the UV-H2O2 process using polychromatic radiation sources.
F. S. García Einschlag (2002)
Evaluating the biodegradability of sulfamethazine, sulfamethoxazole, sulfathiazole, and trimethoprim at different stages of sewage treatment.
Sandra Villegas Pérez (2005)
Occurrence of antibiotics in the aquatic environment.
R. Hirsch (1999)
Sulfamethoxazole detected in a deep phreatic aquifer beneath effluent irrigated land
D Avisar (2009)
Standardization of Methods for Fluence (UV Dose) Determination in Bench-Scale UV Experiments
J. Bolton (2003)
Sulfamethoxazole detected in a deep phreatic aquifer beneath effluent irrigated land
Y. Lester D. Avisar (2009)
Oxidative transformations of environmental pharmaceuticals by Cl₂, ClO₂, O₃, and Fe(VI): kinetics assessment.
V. Sharma (2008)
Thurman, Analysis of trace levels of sulfonamide and tetracycline antimicrobials, in groundwater and surface water using solid-phase extraction and liquid chromatography/ mass spectrometry
M. E. Lindsey (2001)
MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide: efficiency of the processes and bromate formation.
J. L. Acero (2001)
The ROH,UV concept to characterize and the model UV/H2O2 process in natural waters, Environ
E. J. Rosenfeldt (2007)
Photochemical fate of sulfa drugs in the aquatic environment: sulfa drugs containing five-membered heterocyclic groups.
Anne L. Boreen (2004)
Pharmaceuticals in STP effluents and their solar photodegradation in aquatic environment.
R. Andreozzi (2003)
Critical effect of hydrogen peroxide in photochemical oxidative decolorization of dyes: Acid Orange 8, Acid Blue 74 and Methyl Orange
A. Aleboyeh (2003)
Oxidative transformations of environmental pharmaceuticals by Cl2, ClO2, O3 and Fe(VI)
V. K. Sharma (2008)
Oxidation of pharmaceuticals during ozonation and advanced oxidation processes.
M. M. Huber (2003)
Dogruel , Pre - treatment of penicillin formulation effluent by advanced oxidation processes
I. Arslan-Alaton (2004)
Kinetic investigation on UV and UV/H2O2 degradations of pharmaceutical intermediates in aqueous solution
A. López (2003)
UV concept to characterize and the model UV / H 2 O 2 process in natural waters
E. J. Rosenfeldt (2007)
Suppression of pokeweed mitogen-driven human IgM and IgG responses by the hydroxylamine of sulfamethoxazole.
M. Sisson (1997)
Removal of antibiotics in conventional and advanced wastewater treatment: implications for environmental discharge and wastewater recycling.
A. J. Watkinson (2007)
H2O2 determination by the I3- method and by KMnO4 titration
Normal V. Klassen (1994)
Free-radical-induced oxidative and reductive degradation of sulfa drugs in water: absolute kinetics and efficiencies of hydroxyl radical and hydrated electron reactions.
S. Mezyk (2007)
Detection and identification of sulphonamide drugs in municipal waste water by liquid chromatography coupled with electrospray ionisation tandem mass spectrometry.
C. Hartig (1999)
Sulfamethoxazole contamination of a deep phreatic aquifer.
Dror Avisar (2009)
Destruction of estrogenic activity in water using UV advanced oxidation.
E. Rosenfeldt (2007)
Degradation of the pharmaceutical metronidazole via UV, Fenton and photo-Fenton processes.
Hilla Shemer (2006)
Degrada - tion of the pharmaceutical metronidazole via UV , Fenton and photoFenton processes
Y. K. Kunukcu H. Shemer (2006)
Water quality and treatment : a handbook of community water supplies
R. Letterman (1999)
WEIGHTED FLUENCE-BASED PARAMETERS for Assessing UV and UV/H 2 O 2 Performance and Transferring Bench-Scale Results to Full-Scale Water Treatment Reactor Models
C. Sharpless (2005)
Aga, Evaluating the biodegradability of sulfamethazine, sulfamethoxazole, sulfathiazole and trimethoprim at different stages of sewage treatment, Environ
S. Perez (2005)
Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution
G. Buxton (1988)
Biodegradability properties of sulfonamides in activated sludge
F. Ingerslev (2000)
Rate constants for reaction of hydroxyl radicals with several drinking water contaminants
W. R. Haag (1992)
Sulfamethoxazole detected in a deep phreatic aquifer beneath effluent irrigated land, Sci
D. Avisar (2009)
Szinovatz, Remediation of ground water polluted with chlorinated ethylenes by ozone–electron beam irradiation treatment
P. Gehringer (1992)
The ROH,UV concept to characterize and the model uv/H202 process in natural waters.
Erik Rosenfeld (2007)
A kinetic model for H2O2/UV process in a completely mixed batch reactor
J. Crittenden (1999)
Remediation of groundwater polluted with chlorinated ethylenes by ozone-electron beam irradiation treatment.
P. Gehringer (1992)
Analysis of trace levels of sulfonamide and tetracycline antimicrobials in groundwater and surface water using solid-phase extraction and liquid chromatography/mass spectrometry.
M. E. Lindsey (2001)
Photochemical Processes of Water Treatment
T. Oppenländer (2007)
Pre-treatment of penicillin formulation effluent by advanced oxidation processes.
İ. Arslan-Alaton (2004)
UV/H2O2 Treatment: A Practical Solution for Organic Contaminant Control and Primary Disinfection
J. C. Kruithof (2007)
Photodegradation of metolachlor applying UV and UV/H2O2.
Changlong Wu (2007)
Genetic exchange between bacteria in the environment.
J. Davison (1999)
A national reconnaissance of pharmaceuticals and other organic wastewater contaminants in the United States--I) groundwater.
K. K. Barnes (2008)
Reac - tions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures
K. Sehested H. Christensen (1982)
The application of quantum chemical and statistical technique in developing quantitative structure-property relationships for the photohydrolysis quantum yields of substituted aromatic halides
Huifen. Chen (1998)
Pharmaceutical compounds in the wastewater process stream in Northwest Ohio.
A. L. Spongberg (2008)
Phototransformation of selected pharmaceuticals during UV treatment of drinking water.
S. Canonica (2008)
Advanced oxidation of the pharmaceutical drug diclofenac with UV/H2O2 and ozone.
Davide Vogna (2004)
Photodegradation of sulphadimethoxine in water by medium pressure UV lamp.
Y. Lester (2008)

This paper is referenced by
Degradation of 2,4-dichlorophenoxyacetate isopropyl amine (2,4-D IPA) by O3/AC/UV in an internally slurry airlift photo-reactor
N. Farhadian (2017)
Integrative Advanced Oxidation and Biofiltration for Treating Pharmaceuticals in Wastewater.
Yaal Lester (2016)
Mechanisms and toxicity evaluation of the degradation of sulfamethoxazole by MPUV/PMS process.
Xiuwei Ao (2018)
Kinetics of Methyldiethanolamine Mineralization by Using UV/H2O2 Process
Sabtanti Harimurti (2013)
The hydroxyl radical scavenging effect of textile preparation auxiliaries on the photochemical treatment of nonylphenol ethoxylate
İdil Arslan-Alaton (2012)
Treatment of Antibiotics in Wastewater Using Advanced Oxidation Processes (AOPs)
A. Kurt (2017)
For Peer Review Only Feasibility of Radiation Technology for Wastewater
Parvaiz Ahmad (2013)
Degradation of sulfamethoxazole by medium pressure UV and oxidants: Peroxymonosulfate, persulfate, and hydrogen peroxide
Xiuwei Ao (2017)
Photodegradation of antibiotic 5-sulfaminouracil in the presence of vitamin B2: A kinetic study
Marta Susana Díaz (2015)
Ozonation of Naphthenic Acids in Water: Kinetic Study
Ali Kamel H. Al-jibouri (2015)
Photodegradation of cotrimaxazole by clinoptilolite-supported nickel oxide
N. Arabpour (2016)
Low pressure UV/H2O2 treatment for the degradation of the pesticides metaldehyde, clopyralid and mecoprop - Kinetics and reaction product formation.
Sofia Semitsoglou-Tsiapou (2016)
Trace Organic Compound Removal from Wastewater Reverse-Osmosis Concentrate by Advanced Oxidation Processes with UV/O3/H2O2
Aviv Kaplan (2020)
Catalytic ozonation of sulphamethoxazole in the presence of carbon materials: catalytic performance and reaction pathways.
A. Gonçalves (2012)
Hybrid ozonation process for industrial wastewater treatment: Principles and applications: A review
S. Malik (2020)
Effect of Bicarbonate on the Mineralization of Methyldiethanolamine by using UV/H2O2
Sabtanti Harimurti (2014)
Enhancing the biological degradability of sulfamethoxazole by ionizing radiation treatment in aqueous solution
Gyuri Sági (2016)
Removal of pharmaceuticals using combination of UV/H(2)O(2)/O(3) advanced oxidation process.
Y. Lester (2011)
Ozone Degradation of Cyclophosphamide – Effect of Alkalinity and Key Effluent Organic Matter Constituents
Yaal Lester (2013)
Demonstrating sucralose as a monitor of full-scale UV/AOP treatment of trace organic compounds.
Yaal Lester (2014)
Simultaneous purifying of Hg0, SO2, and NOx from flue gas by Fe3+/H2O2: the performance and purifying mechanism
Yi Xing (2017)
Kinetic studies and characterization of photolytic products of sulfamethazine, sulfapyridine and their acetylated metabolites in water under simulated solar irradiation.
M. J. García-Galán (2012)
Ceria dispersed on carbon materials for the catalytic ozonation of sulfamethoxazole
A. Gonçalves (2013)
Optimization and interpretation of O3 and O3/H2O2 oxidation processes to pretreat hydrocortisone pharmaceutical wastewater
Guiju Li (2015)
UV–H2O2 degradation of methyl orange catalysed by H3PW12O40/activated clay
Guangtao Wei (2012)
Treating wastewater from a pharmaceutical formulation facility by biological process and ozone.
Yaal Lester (2013)
Reducing THMFP by H2O2/UV oxidation for humic acid of small molecular weight
Hsing Yuan Yen (2015)
Heterogeneous catalytic ozonation of naphthenic acids in water
Ali Kamel H. Al jibouri (2019)
Feasibility of radiation technology for wastewater treatment
Sumira Jan (2015)
Photodegradation of taste and odor compounds in water in the presence of immobilized TiO2-SiO2 photocatalysts.
Sudheera Yaparatne (2018)
Mechanistic QSAR models for interpreting degradation rates of sulfonamides in UV-photocatalysis systems.
Xiangfeng Huang (2015)
High-energy oxidation process: an efficient alternative for wastewater organic contaminants removal
Andrea G. Capodaglio (2017)
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