Online citations, reference lists, and bibliographies.
← Back to Search

Ultrastrong And Stiff Layered Polymer Nanocomposites

P. Podsiadlo, A. Kaushik, E. Arruda, A. Waas, B. S. Shim, J. Xu, H. Nandivada, Benjamin G. Pumplin, J. Lahann, A. Ramamoorthy, N. Kotov
Published 2007 · Materials Science, Medicine

Cite This
Download PDF
Analyze on Scholarcy
Share
Nanoscale building blocks are individually exceptionally strong because they are close to ideal, defect-free materials. It is, however, difficult to retain the ideal properties in macroscale composites. Bottom-up assembly of a clay/polymer nanocomposite allowed for the preparation of a homogeneous, optically transparent material with planar orientation of the alumosilicate nanosheets. The stiffness and tensile strength of these multilayer composites are one order of magnitude greater than those of analogous nanocomposites at a processing temperature that is much lower than those of ceramic or polymer materials with similar characteristics. A high level of ordering of the nanoscale building blocks, combined with dense covalent and hydrogen bonding and stiffening of the polymer chains, leads to highly effective load transfer between nanosheets and the polymer.
This paper references
10.1021/CM990475T
Cross-Linking of Poly(vinyl alcohol) Chains by Al Ions in Macro-Defect-Free Cements: A Theoretical Study
A. A. Bonapasta (2000)
Relationship between crystalline structure and mechanical properties in Kevlar® 9 fibres
A. M. Hindeleh (1989)
10.5254/1.3538823
Mechanical Behavior of Particle Filled Elastomers
J. Bergström (1999)
10.1115/1.1857937
Mechanical Properties of Kevlar® KM2 Single Fiber
M. Cheng (2005)
10.1038/NMAT747
Molecular design of strong single-wall carbon nanotube/polyelectrolyte multilayer composites
A. Mamedov (2002)
10.1007/BFB0117061
Einfluß von Polyvinylpyrrolidon auf die Struktur und einige physikalische Eigenschaften von chemisch vernetzten Polyvinylalkoholgelen
M. Nagy (1976)
10.1038/381678A0
Exceptionally high Young's modulus observed for individual carbon nanotubes
M. Treacy (1996)
10.1126/SCIENCE.277.5330.1232
Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites
Gero Decher (1997)
10.1002/ADMA.200602706
Fusion of Seashell Nacre and Marine Bioadhesive Analogs: High‐Strength Nanocomposite by Layer‐by‐Layer Assembly of Clay and L‐3,4‐Dihydroxyphenylalanine Polymer
P. Podsiadlo (2007)
10.1021/JP061548G
Fabry-Perot fringes and their application to study the film growth, chain rearrangement, and erosion of hydrogen-bonded PVPON/PAA films.
Y. Guan (2006)
10.1021/BM0493685
Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field.
M. A. S. Azizi Samir (2005)
10.1002/ADMA.200600113
Biomedical Applications of Layer‐by‐Layer Assembly: From Biomimetics to Tissue Engineering
Z. Tang (2006)
10.1002/ADMA.200400133
Graphite Nanoplatelet Reinforcement of Electrospun Polyacrylonitrile Nanofibers
Julia J. Mack (2005)
10.1002/ADMA.200502444
Freestanding Nanostructures via Layer‐by‐Layer Assembly
C. Jiang (2006)
10.1016/S0266-3538(99)00137-2
Effects of heat treatment on the mechanical properties of Kevlar-29 fibre
C. Y. Yue (2000)
10.1021/JP0302818
Elastic Properties of a Single Lamella of Montmorillonite by Molecular Dynamics Simulation
O. L. Manevitch (2004)
10.1021/NL048950W
Layer-by-layer assembled composites from multiwall carbon nanotubes with different morphologies
M. Olek (2004)
10.1038/NMAT906
Nanostructured artificial nacre
Zhiyong Tang (2003)
10.1002/ADMA.19960080104
Polymer Layered Silicate Nanocomposites
E. Giannelis (1996)
10.1021/BM049291K
Elastic modulus and stress-transfer properties of tunicate cellulose whiskers.
Adriana Šturcová (2005)
10.1016/J.PROGPOLYMSCI.2003.08.002
POLYMER/LAYERED SILICATE NANOCOMPOSITES: A REVIEW FROM PREPARATION TO PROCESSING
S. Ray (2003)
10.1002/PC.20058
Big returns from small fibers: A review of polymer/carbon nanotube composites
O. Breuer (2004)
10.1038/423703a
Super-tough carbon-nanotube fibres
A. Dalton (2003)
10.1021/LA990957J
Stratified Assemblies of Magnetite Nanoparticles and Montmorillonite Prepared by the Layer-by-Layer Assembly
A. Mamedov (2000)
10.1126/SCIENCE.287.5453.637
Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load
Yu (2000)
10.1016/S0009-2614(00)00764-8
Ab initio study of the elastic properties of single-walled carbon nanotubes and graphene
G. Lier (2000)
10.1021/NL0700649
Counterintuitive effect of molecular strength and role of molecular rigidity on mechanical properties of layer-by-layer assembled nanocomposites.
P. Podsiadlo (2007)
10.1007/BF01566233
Intra- und intermolekulare Vernetzung von Polyvinylalkohol mit Dialdehyden
D. Braun (1980)
10.1002/ADMA.200400760
Form and Function in Multilayer Assembly: New Applications at the Nanoscale
P. Hammond (2004)



This paper is referenced by
10.1016/j.jcis.2009.12.060
Bioinspired assembly of surface-roughened nanoplatelets.
Tzung-Hua Lin (2010)
Aramid Nanofiber Composites for Energy Storage Applications
Siu on Tung (2017)
10.1038/nmat2504
Mechanotransductive surfaces for reversible biocatalysis activation.
D. Mertz (2009)
Synergistic Toughening of Bioinspired Poly ( vinyl alcohol )
Jian-feng Wang (2014)
10.1021/ACS.IECR.7B01679
Review on 3D Prototyping of Damage Tolerant Interdigitating Brick Arrays of Nacre
R. Yadav (2017)
10.1021/acsnano.5b00119
Nanoasperity: structure origin of nacre-inspired nanocomposites.
Shuang Xia (2015)
10.1039/C0JM03317K
Oriented printable layered double hydroxide thin films via facile filtration
H. Zhu (2011)
10.1016/j.carbpol.2016.12.019
Tunable softening and toughening of individualized cellulose nanofibers-polyurethane urea elastomer composites.
M. Lee (2017)
10.1016/j.carbpol.2016.03.016
A novel method for fabricating hybrid biobased nanocomposites film with stable fluorescence containing CdTe quantum dots and montmorillonite-chitosan nanosheets.
Yawen Guo (2016)
10.1002/adma.202002004
Mechanical and Tribological Performances Enhanced by Self-Assembled Structures.
Zhenjie Xue (2020)
10.1016/J.CARBPOL.2011.07.019
Clay nanopaper composites of nacre-like structure based on montmorrilonite and cellulose nanofibers-Improvements due to chitosan addition
Andong Liu (2012)
Protection Of High-Voltage Transformer Bushings And Other Brittle Structures Against Impact
C. N. Henderson (2019)
10.3390/ma10050498
An Investigation into the Properties and Microstructure of Cement Mixtures Modified with Cellulose Nanocrystal
J. Flores (2017)
10.1002/smll.200801710
Deformation measurements on thin clay tactoids.
D. Kunz (2009)
10.1002/ANGE.201001577
Supramolekulare Kontrolle der mechanischen Eigenschaften feuerabschirmender biomimetischer Perlmuttanaloga
A. Walther (2010)
10.1016/j.jmbbm.2015.10.013
Nacre-like hybrid films: Structure, properties, and the effect of relative humidity.
M. T. Abba (2015)
10.1038/srep11181
3D Printable Graphene Composite
Xiaojun Wei (2015)
10.1007/s10965-015-0806-3
Preparation and characterization of mechanically and thermally enhanced polyimide/reactive halloysite nanotubes nanocomposites
S. Chen (2015)
10.1016/J.CARBPOL.2019.05.090
Bioinspired approach to enhance mechanical properties of starch based nacre-mimetic nanocomposite.
J. Li (2019)
10.1039/C0SM01347A
Exfoliation and liquid crystal phase formation of layered double hydroxide into waterborne polyurethane coatings
Anne-Lise Troutier-Thuilliez (2011)
10.1039/c9sm00649d
Rapidly responsive smart adhesive-coated micropillars utilizing catechol-boronate complexation chemistry.
Ameya R Narkar (2019)
10.1002/ADFM.201807611
Strategic Design of Clay‐Based Multifunctional Materials: From Natural Minerals to Nanostructured Membranes
Y. Zhou (2019)
10.1016/J.COMPOSITESB.2015.12.048
Enhanced electrical and mechanical properties of rubber/graphene film through layer-by-layer electrostatic assembly
L. Wang (2016)
10.1002/adma.201401226
Tunable elastic modulus of nanoparticle monolayer films by host-guest chemistry.
Youngdo Jeong (2014)
10.1016/J.CLAY.2014.04.017
Silica nanowires obtained on clay mineral layers and their influence on mini-emulsion polymerisation
M. C. Corobea (2014)
10.1039/C7RA02987J
Functionalization of halloysite nanotubes (HNTs) via mussel-inspired surface modification and silane grafting for HNTs/soy protein isolate nanocomposite film preparation
H. Kang (2017)
10.1007/s00396-012-2588-z
Novel polymer nanocomposite hydrogel with natural clay nanotubes
M. Liu (2012)
10.1002/CJOC.201600335
Spin Self‐Assembled Clay Nanocomposite Passivation Layers Made from a Photocrosslinkable Poly(vinyl alcohol) and Na+‐Montmorillonite Enhance the Environmental Stability of Organic Thin‐Film Transistors
Hayoung Jeon (2016)
10.1016/J.COLSURFA.2015.12.011
Novel colloidal nanofiber semiconductor electrolytes from solution blends of PVA/ODA–MMT, poly (itaconic anhydride-alt-2-vinyl-1,3-dioxalan) and its Ag-carrying polymer complex by reactive electrospinning
Z. Rzayev (2016)
10.1088/0957-4484/24/16/165601
Melt compounding with graphene to develop functional, high-performance elastomers.
S. Araby (2013)
10.1021/nn102456w
Co-cross-linking silk matrices with silica nanostructures for robust ultrathin nanocomposites.
Eugenia Kharlampieva (2010)
10.1038/ncomms4166
Overcoming the brittleness of glass through bio-inspiration and micro-architecture.
M. Mirkhalaf (2014)
See more
Semantic Scholar Logo Some data provided by SemanticScholar