Online citations, reference lists, and bibliographies.
← Back to Search

Two-Dimensional Phonon Transport In Supported Graphene

J. Seol, I. Jo, Arden Moore, L. Lindsay, Zachary H. Aitken, M. Pettes, Xuesong Li, Z. Yao, R. Huang, D. Broido, N. Mingo, R. Ruoff, L. Shi
Published 2010 · Materials Science, Medicine

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Heat Flow in Graphene Unsupported graphene sheets show exceptional thermal transport properties, but are these properties maintained when a graphene sheet is in contact with a substrate? Seol et al. (p. 213; see the Perspective by Prasher) measured the thermal conductivity of graphene supported on silicon dioxide and found that, while the conductivity was considerably lower than that of free-standing graphene, it was still greater than that of metals such as copper. A theoretical model suggested that the out-of-plane flexing vibrations of the graphene play a key role in thermal transport. Thus, graphene may help in applications such as conducting heat away from electronic circuits. The thermal conductivity of graphene supported on silicon dioxide remains high, despite phonon scattering by the substrate. The reported thermal conductivity (κ) of suspended graphene, 3000 to 5000 watts per meter per kelvin, exceeds that of diamond and graphite. Thus, graphene can be useful in solving heat dissipation problems such as those in nanoelectronics. However, contact with a substrate could affect the thermal transport properties of graphene. Here, we show experimentally that κ of monolayer graphene exfoliated on a silicon dioxide support is still as high as about 600 watts per meter per kelvin near room temperature, exceeding those of metals such as copper. It is lower than that of suspended graphene because of phonons leaking across the graphene-support interface and strong interface-scattering of flexural modes, which make a large contribution to κ in suspended graphene according to a theoretical calculation.
This paper references
10.1103/PHYSREV.127.694
Anisotropic Thermal Conductivity of Pyrolytic Graphite
G. A. Slack (1962)
10.1063/1.1713251
Thermal Conductivity of Pure and Impure Silicon, Silicon Carbide, and Diamond
G. A. Slack (1964)
10.1016/0008-6223(94)90096-5
Thermal conductivity of graphite in the basal plane
P. Klemens (1994)
10.1007/978-94-011-0295-7_8
Introduction to lattice dynamics
H. Schober (1995)
10.1063/1.123994
Phonon scattering in silicon films with thickness of order 100 nm
Y. Ju (1999)
10.1103/PhysRevLett.87.215502
Thermal transport measurements of individual multiwalled nanotubes.
P. Kim (2001)
10.1023/A:1006776107140
Theory of Thermal Conduction in Thin Ceramic Films
P. Klemens (2001)
10.1021/JP040650F
Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics.
C. Berger (2004)
10.1126/SCIENCE.1102896
Electric Field Effect in Atomically Thin Carbon Films
K. Novoselov (2004)
10.1063/1.1713033
Thermal and electrical characterization of Cu/CoFe superlattices
Y. Yang (2004)
10.1021/NL051044E
Thermal conductance and thermopower of an individual single-wall carbon nanotube.
Choongho Yu (2005)
10.1103/PhysRevLett.95.155505
Negative differential conductance and hot phonons in suspended nanotube molecular wires.
E. Pop (2005)
10.1103/PhysRevLett.99.246803
Measurement of scattering rate and minimum conductivity in graphene.
Y. Tan (2007)
10.1021/nl070613a
Atomic structure of graphene on SiO2.
M. Ishigami (2007)
10.1038/nnano.2008.58
Intrinsic and extrinsic performance limits of graphene devices on SiO2.
Jian-Hao Chen (2008)
10.1016/j.ssc.2008.02.024
Ultrahigh electron mobility in suspended graphene
K. Bolotin (2008)
10.1126/science.1157996
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
Changgu Lee (2008)
10.1103/PhysRevLett.100.076801
Flexural phonons in free-standing graphene.
E. Mariani (2008)
10.1021/nl0731872
Superior thermal conductivity of single-layer graphene.
A. Balandin (2008)
10.1038/nature07719
Large-scale pattern growth of graphene films for stretchable transparent electrodes
K. Kim (2009)
10.1016/J.PHYSREP.2009.02.003
Raman spectroscopy in graphene
L. Malard (2009)
10.1063/1.3136860
Lattice thermal conductivity of graphene flakes: Comparison with bulk graphite
D. Nika (2009)
10.1126/science.1171245
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
Xuesong Li (2009)
10.1103/PHYSREVB.80.125407
Lattice thermal conductivity of single-walled carbon nanotubes: Beyond the relaxation time approximation and phonon-phonon scattering selection rules
L. Lindsay (2009)
10.1103/PHYSREVB.79.155413
Phonon thermal conduction in graphene: Role of Umklapp and edge roughness scattering
D. Nika (2009)
10.1103/PhysRevB.80.235415
Theory of thermopower in two-dimensional graphene
E. Hwang (2009)
10.1103/PhysRevLett.102.076102
Intrinsic and extrinsic corrugation of monolayer graphene deposited on SiO2.
V. Geringer (2009)
10.1063/1.3075065
Acoustic mismatch model for thermal contact resistance of van der Waals contacts
R. Prasher (2009)
10.1126/science.1181044
Iron-Clad Fibers: A Metal-Based Biological Strategy for Hard Flexible Coatings
Matthew J. Harrington (2010)
10.2172/1033083
Department of Energy – Office of Science Pacific Northwest Site Office Environmental Monitoring Plan for the DOE-SC PNNL Site
S. Snyder (2011)
Materials and methods are available as supporting materials on Science Online



This paper is referenced by
10.1016/J.CEJ.2021.129466
3D isotropic hole-in-platelet graphene hydrogels with high surface area and fast mass transfer ability as efficient adsorbents
Jing Wu (2021)
10.1063/5.0038149
The measurement of anisotropic thermal transport using time-resolved magneto-optical Kerr effect
Luu Ly Pham Ngoc (2021)
Spatially mapping of the thermal conductivity of graphene by an opto-thermal method
Oliver Braun (2021)
10.1021/ACS.JPCC.1C02717
Electron–Phonon Interaction Enables Strong Thermoelectric Seebeck Effect Variation in Hybrid Nanoscale Systems
Marco A. Cabero Z. (2021)
10.1016/j.physe.2020.114557
CNT-sandwiched copper composites as super thermal conductors for heat management
Pengjie Wang (2021)
10.1038/s41598-020-80217-0
Bond order redefinition needed to reduce inherent noise in molecular dynamics simulations
I. Syuhada (2021)
Progress of microscopic thermoelectric effects studied by micro-and nano-thermometric techniques
Xue Gong (2021)
10.1016/J.IJTHERMALSCI.2021.107009
Coherent and incoherent effects of nanopores on thermal conductance in silicene
Liu Cui (2021)
10.1016/j.jallcom.2020.156703
High strength and conductivity copper matrix composites reinforced by in-situ graphene through severe plastic deformation processes
Tie-jun Li (2021)
10.1016/J.COMMATSCI.2021.110477
Reviewing computational studies of defect formation and behaviors in carbon fiber structural units
Sara B. Isbill (2021)
Two-step Dual-wavelength Flash Raman Mapping Method for Measuring Thermophysical Properties of Supported 2D Nanomaterials
Aoran Fan (2021)
10.1039/D0NA00944J
Thermal transport across wrinkles in few-layer graphene stacks
A. Mohapatra (2021)
10.1016/J.PHYSE.2021.114761
Improved thermal stability and tunable interfacial thermal resistance in a phosphorene/hBN bilayer heterostructure
Ting Li (2021)
10.1016/J.CARBON.2021.02.102
Coherency between thermal and electrical transport of partly reduced graphene paper
Jianshu Gao (2021)
10.1016/J.IJMECSCI.2021.106576
Tunable anisotropic thermal transport in porous carbon foams: The role of phonon coupling
Xue-Kun Chen (2021)
10.1039/d1nr00734c
Novel two-dimensional tetrahexagonal boron nitride with a sizable band gap and a sign-tunable Poisson's ratio.
M. Kilic (2021)
10.1016/J.CARBON.2021.02.105
Interfacial heat transport in nano-carbon assemblies
L. Qiu (2021)
10.1002/advs.202001274
Carbon‐Based Composite Phase Change Materials for Thermal Energy Storage, Transfer, and Conversion
Xiao Chen (2021)
10.1007/s10853-021-06231-3
Anisotropic transport properties of graphene-based conductor materials
D. Slawig (2021)
10.1088/1361-648X/ac1824
First-principles investigations on a two-dimensional S3N2/black phosphorene van der Waals heterostructure: mechanical, carrier transport and thermoelectric anisotropy
Jialin Li (2021)
10.1002/nano.202000142
Recent advances in the Van der Waals epitaxy growth of III‐V semiconductor nanowires on graphene
E. Anyebe (2021)
10.1039/d0nr08829c
A heat and force locating sensor with nanoscale precision: a knitted graphene sheet.
Ning Wei (2021)
10.1039/d1nr00455g
Two-dimensional WS2/MoS2 heterostructures: properties and applications.
Yichuan Chen (2021)
10.1080/15567265.2021.1902441
Impact of Electron-Phonon Interaction on Thermal Transport: A Review
Y. Quan (2021)
10.1016/J.DIAMOND.2021.108355
Improved performance of SiC radiation detectors due to optimized ohmic contact electrode by graphene insertion
Yuping Jia (2021)
10.1140/EPJP/S13360-021-01386-Z
Dimension-dependent thermal conductivity of graphene nanoribbons on silicon carbide
Junjie Chen (2021)
10.1016/j.carbon.2020.12.086
A multiscale study of the filler-size and temperature dependence of the thermal conductivity of graphene-polymer nanocomposites
Jie Wang (2021)
10.1038/s41467-020-20476-7
Thermoelectric current in a graphene Cooper pair splitter
Z. Tan (2021)
10.1016/J.SSC.2021.114249
Thermal conductivity of graphene/graphane/graphene heterostructure nanoribbons: Non-equilibrium molecular dynamics simulations
Jong-Chol Kim (2021)
10.1038/s41598-021-89579-5
Thermoelectric transports in pristine and functionalized boron phosphide monolayers
Min-Shan Li (2021)
10.3390/C7010005
First-Principles Study of the Electronic Properties and Thermal Expansivity of a Hybrid 2D Carbon and Boron Nitride Material
O. Olaniyan (2021)
10.1007/s12274-021-3492-y
Anisotropic in-plane thermal conductivity for multi-layer WTe2
Yuehua Wei (2021)
See more
Semantic Scholar Logo Some data provided by SemanticScholar