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DOI: 10.1139/V79-180

A New Type Of Lycopodium Alkaloid. The C30N3 Alkaloids From Lycopodium Lucidulum

William A. Ayer, Lois M. Browne, Yuji Nakahara, Motoo Tori, Louis T. J. Delbaere

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The structures of lucidine B, dihydrolycolucine, and lycolucine, representatives of a new type of Lycopodium alkaloid, have been determined, mainly on the basis of an X-ray crystallographic study of a derivative (N,O-di-p-bromobenzoyltetrahydrodeoxyoxolucidine B) of lucidine B. Dehydrogenation of lucidine B gives dihydrolycolucine which in turn has been prepared from lycolucine.