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Upgrading Of Carbohydrates To The Biofuel Candidate 5-Ethoxymethylfurfural (EMF)

Xiaofang Liu, Rui Wang
Published 2018 · Chemistry
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5-Ethoxymethylfurfural (EMF), one of the significant platform molecular derivatives, is regarded as a promising biofuel and additive for diesel, owing to its high energy density (8.7 kWh·L−1). Several catalytic materials have been developed for the synthesis of EMF derived from different feedstocks under relatively mild reaction conditions. Although a great quantity of research has been conducted over the past decades, the unsatisfactory production selectivity mostly limited to the range 50%–70%, and the classic fructose used as the substrate restricted its application for fuel manufacture in large scale. To address these production improvements, this review pays attention to evaluate the activity of various catalysts (e.g., mineral salts, zeolites, heteropolyacid-based hybrids, sulfonic acid-functionalized materials, and ionic liquids), providing potential research directions for the design of novel catalysts for the achievement of further improved EMF yields.
This paper references
10.1016/S2095-4956(13)60012-1
Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3·6H2O/BF3·(Et)2O in ethanol
Xiuquan Jia (2013)
10.1002/cssc.201701275
Cascade Reductive Etherification of Bioderived Aldehydes over Zr-Based Catalysts.
Suhas Shinde (2017)
10.1039/C3RA46570E
Preparation of potential biofuel 5-ethoxymethylfurfural and other 5-alkoxymethylfurfurals in the presence of oil shale ash
Indrek Viil (2014)
10.1016/j.scitotenv.2015.11.076
Variation of diesel soot characteristics by different types and blends of biodiesel in a laboratory combustion chamber.
Hamid Omidvarborna (2016)
10.1016/J.RSER.2014.07.003
Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals
Kai Yan (2014)
10.1016/J.FUEL.2013.06.015
Efficient conversion of carbohydrates into 5-ethoxymethylfurfural in ethanol catalyzed by AlCl3
Bing Liu (2013)
10.1039/C7RA07684C
Dehydration of glucose to 5-hydroxymethylfurfural and 5-ethoxymethylfurfural by combining Lewis and Brønsted acid
Haosheng Xin (2017)
10.1039/C6GC01206J
Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials
Zhenhua Wang (2016)
10.1021/cr300182k
Hydroxymethylfurfural, a versatile platform chemical made from renewable resources.
Robert-Jan van Putten (2013)
10.1016/J.TETLET.2016.08.061
Application of glucose derived magnetic solid acid for etherification of 5-HMF to 5-EMF, dehydration of sorbitol to isosorbide, and esterification of fatty acids
Raju S Thombal (2016)
10.1016/j.biortech.2012.03.126
Conversion of glucose into furans in the presence of AlCl3 in an ethanol-water solvent system.
Yu Yang (2012)
10.1002/CPLU.201300301
Synthesis of 5-Ethoxymethylfurfural from Fructose and Inulin Catalyzed by a Magnetically Recoverable Acid Catalyst.
Zehui Zhang (2014)
10.1016/j.biortech.2013.02.110
Efficient catalytic system for the conversion of fructose into 5-ethoxymethylfurfural.
Hongliang Wang (2013)
10.1002/cssc.201600507
One-Pot Conversion of Carbohydrates into Furan Derivatives via Furfural and 5-Hydroxylmethylfurfural as Intermediates.
Bing Liu (2016)
10.1002/APJ.2095
One‐pot ethanolysis of carbohydrates to promising biofuels: 5‐ethoxymethylfurfural and ethyl levulinate
Guizhuan Xu (2017)
10.1021/cr068360d
Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering.
George W. Huber (2006)
10.1002/14356007.l04_l01
Biorefineries–Industrial Processes and Products
Birgit Kamm. (2005)
10.1016/J.CATTOD.2016.02.016
Efficient production of 5-ethoxymethylfurfural from fructose by sulfonic mesostructured silica using DMSO as co-solvent
Gabriel Morales (2017)
10.1016/j.aca.2005.10.031
Changes in volatile composition of Madeira wines during their oxidative ageing
J. Câmara (2006)
10.1021/ja808537j
Simple chemical transformation of lignocellulosic biomass into furans for fuels and chemicals.
Joseph Binder (2009)
10.1039/C3GC41908H
Production of biomass-derived furanic ethers and levulinate esters using heterogeneous acid catalysts
Patricia Bomfim das Neves (2013)
10.1016/J.ENCONMAN.2014.03.037
Direct catalytic transformation of carbohydrates into 5-ethoxymethylfurfural with acid–base bifunctional hybrid nanospheres
Hu Li (2014)
10.1039/C8TA01242C
Three-step cascade over a single catalyst: synthesis of 5-(ethoxymethyl)furfural from glucose over a hierarchical lamellar multi-functional zeolite catalyst
Yuanyuan Bai (2018)
10.1021/jf034631z
Evolution of chemical and sensory properties during aging of top-fermented beer.
B. Vanderhaegen (2003)
10.1016/J.CATTOD.2013.07.008
Acid catalysed alcoholysis of wheat straw: Towards second generation furan-derivatives
R.J.H. Grisel (2014)
10.1002/cssc.200700033
Chemicals from renewables: aerobic oxidation of furfural and hydroxymethylfurfural over gold catalysts.
Esben Taarning (2008)
10.1039/C3RA41043A
One-pot conversion of carbohydrates into 5-ethoxymethylfurfural and ethyl D-glucopyranoside in ethanol catalyzed by a silica supported sulfonic acid catalyst
Bing Liu (2013)
10.1002/SLCT.201700807
Direct Conversion of Carbohydrates into 5‐Ethoxymethylfurfural (EMF) and 5‐Hydroxymethylfurfural (HMF) catalyzed by Oxomolybdenum complexes
Juliana Guisardi Pereira (2017)
10.1002/ENTE.201700153
Simply Assembly of Acidic Nanospheres for Efficient Production of 5-Ethoxymethylfurfural from 5-Hydromethylfurfural and Fructose
Zhongwei Wang (2017)
10.1021/cr300068p
Magnetic nanoparticles: design and characterization, toxicity and biocompatibility, pharmaceutical and biomedical applications.
Lakkireddy Harivardhan Reddy (2012)
10.1016/J.MOLCATA.2014.07.014
Elucidating the role of cobalt phthalocyanine in the dehydration of carbohydrates in ionic liquids
Kumar Karitkey Yadav (2014)
10.1016/J.CATCOM.2011.10.001
Solid acid catalysed formation of ethyl levulinate and ethyl glucopyranoside from mono- and disaccharides
S. Saravanamurugan (2012)
10.1039/c1cs15147a
Conversion of biomass to selected chemical products.
Pierre Gallezot (2012)
10.1002/cssc.201301149
Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels.
Margarida M Antunes (2014)
10.1126/SCIENCE.1146356
Chemicals from Biomass
D. R. Dodds (2007)
10.3390/CATAL7060182
Insights into the Metal Salt Catalyzed 5-Ethoxymethylfurfural Synthesis from Carbohydrates
Xin Yu (2017)
10.1016/J.FUEL.2015.02.020
Efficient synthesis of promising liquid fuels 5-ethoxymethylfurfural from carbohydrates
Ziliang Yuan (2015)
10.1016/J.RSER.2016.12.118
A review on synthesis of alkoxymethyl furfural, a biofuel candidate
Siamak Alipour (2017)
10.1055/S-0035-1562790
Application of 5-Ethoxymethylfurfural (EMF) for the Production of Cyclopentenones
Aleksei Bredihhin (2016)
10.1039/C2GC35102A
Etherification and reductive etherification of 5-(hydroxymethyl)furfural: 5-(alkoxymethyl)furfurals and 2,5-bis(alkoxymethyl)furans as potential bio-diesel candidates
Madhesan Balakrishnan (2012)
10.1016/J.APCATA.2016.04.017
Selective etherification of hydroxymethylfurfural to biofuel additives over Cs containing silicotungstic acid catalysts
G. Raveendra (2016)
10.1002/ANIE.200604274
Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.
Juben Nemchand Chheda (2007)
10.1039/C5GC01043H
Direct transformation of carbohydrates to the biofuel 5-ethoxymethylfurfural by solid acid catalysts
Hu Li (2016)
10.1016/J.JIEC.2013.09.020
Synthesis of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and fructose in ethanol catalyzed by MCM-41 supported phosphotungstic acid
Anqiu Liu (2014)
10.1134/S1070363216070276
Magnetically-recoverable carbonaceous material: An efficient catalyst for the synthesis of 5-hydroxymethylfurfural and 5-ethoxymethylfurfural from carbohydrates
Yuan Yao (2016)
10.1016/j.biortech.2012.06.001
Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production.
Penghua Che (2012)
10.1007/s10570-013-9944-0
Cellulose sulfuric acid as a bio-supported and recyclable solid acid catalyst for the synthesis of 5-hydroxymethylfurfural and 5-ethoxymethylfurfural from fructose
Bing Liu (2013)
10.1021/IE2025536
One-Pot Synthesis of 5-(Ethoxymethyl)furfural from Glucose using Sn-BEA and Amberlyst Catalysts
Christopher Lew (2012)
10.1039/C3CY00223C
Silica coated magnetic Fe3O4 nanoparticles supported phosphotungstic acid: a novel environmentally friendly catalyst for the synthesis of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and fructose
Shuguo Wang (2013)
10.1039/C2RA20574B
Solid-acid and ionic-liquid catalyzed one-pot transformation of biorenewable substrates into a platform chemical and a promising biofuel
Md. Imteyaz Alam (2012)
10.1039/C2GC35175G
A direct synthesis of 5-alkoxymethylfurfural ethers from fructose via sulfonic acid-functionalized ionic liquids
George A Kraus (2012)
10.1002/cssc.201000192
Facile single-step conversion of macroalgal polymeric carbohydrates into biofuels.
Bora Kim (2010)
10.1016/S0956-7135(02)00094-4
Influence of storage temperature on the volatile compounds of young white wines
María Soledad Pérez-Coello (2003)
10.1039/C5NJ03461B
HMF etherification using NH4-exchanged zeolites
Katia Barbera (2016)
10.1039/C3GC41109E
Graphene oxide as a facile acid catalyst for the one-pot conversion of carbohydrates into 5-ethoxymethylfurfural
Hong-liang Wang (2013)
10.1016/J.FUEL.2013.09.072
Efficient one-pot synthesis of 5-ethoxymethylfurfural from fructose catalyzed by heteropolyacid supported on K-10 clay
Anqiu Liu (2014)
10.1021/IE3020445
Efficient One-Pot Synthesis of 5-(Ethoxymethyl)furfural from Fructose Catalyzed by a Novel Solid Catalyst
Liu Bing (2012)
10.1016/J.JECE.2014.09.020
Characterization of particulate matter emitted from transit buses fueled with B20 in idle modes
Hamid Omidvarborna (2014)
10.1016/J.JIEC.2013.05.028
Catalytic conversion of fructose into furans using FeCl3 as catalyst
Xuanmu Zhou (2014)
10.1126/science.1159210
Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes
Edward L. Kunkes (2008)
10.1016/J.CATTOD.2011.05.008
Etherification of 5-hydroxymethyl-2-furfural (HMF) with ethanol to biodiesel components using mesoporous solid acidic catalysts
Paola Lanzafame (2011)
10.1039/C4TA06135G
Magnetic material grafted cross-linked imidazolium based polyionic liquids: an efficient acid catalyst for the synthesis of promising liquid fuel 5-ethoxymethylfurfural from carbohydrates
Shanshan Yin (2015)
10.1016/J.RSER.2015.04.019
Recent studies on soot modeling for diesel combustion
Hamid Omidvarborna (2015)
10.1016/j.carres.2011.12.006
Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol.
Ji-tian Liu (2012)
10.1126/science.1126337
Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose
Yuriy Román-Leshkov (2006)
10.1016/J.APENERGY.2012.04.049
Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate
Yu Yang (2012)
10.1039/C6RA06792A
Controlled deposition of Pt nanoparticles on Fe3O4@carbon microspheres for efficient oxidation of 5-hydroxymethylfurfural
Yuwei Zhang (2016)
10.1016/J.FUEL.2016.12.027
Efficient conversion of carbohydrates into 5-hydroxylmethylfurfan and 5-ethoxymethylfurfural over sufonic acid-functionalized mesoporous carbon catalyst
Junmei Wang (2017)
10.1002/cssc.201200031
One-pot conversions of lignocellulosic and algal biomass into liquid fuels.
Sudipta De (2012)
10.1016/j.carres.2011.05.026
Acidic resin-catalysed conversion of fructose into furan derivatives in low boiling point solvents.
H. J. Zhu (2011)
10.1021/jf981224s
Study of the formation mechanisms of some volatile compounds during the aging of sweet fortified wines.
I. Cutzach (1999)
10.1002/cssc.201402100
A continuous flow strategy for the coupled transfer hydrogenation and etherification of 5-(hydroxymethyl)furfural using Lewis acid zeolites.
Jennifer D. Lewis (2014)
10.1016/J.INDCROP.2017.11.001
An effective pathway for converting carbohydrates to biofuel 5-ethoxymethylfurfural via 5-hydroxymethylfurfural with deep eutectic solvents (DESs)
Miao Zuo (2018)
10.1016/J.JIEC.2014.05.024
Silver-exchanged heteropolyacid catalyst (Ag1H2PW): An efficient heterogeneous catalyst for the synthesis of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and fructose
Yong-shen Ren (2015)
10.1155/2014/481627
Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers
H. Li (2014)
10.1021/jf802147z
Impact of forced-aging process on madeira wine flavor.
H. Oliveira e Silva (2008)
10.1039/c1cs15131b
Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing.
Juan Carlos Serrano-Ruiz (2011)
10.1039/C0EE00082E
Continuous production of 5-hydroxymethylfurfural from fructose: a design case study
A. I. Torres (2010)



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