Online citations, reference lists, and bibliographies.
← Back to Search

Effect Of Maleic Anhydride Content And Ethanol Dilution On The Polymerization Of Furfuryl Alcohol In Wood Veneer Studied By Differential Scanning Calorimetry

N. Herold, T. Dietrich, W. Grigsby, R. Franich, A. Winkler, B. Buchelt, A. Pfriem
Published 2013 · Materials Science

Cite This
Download PDF
Analyze on Scholarcy
Share
The polymerization kinetics of furfuryl alcohol in wood veneer were studied using differential scanning calorimetry (DSC) and were compared with weight gains of treated wood veneers. Maleic anhydride was used as the reaction initiator. DSC data were obtained for samples of the veneers that had been impregnated with neat furfuryl alcohol or with furfuryl alcohol diluted with ethanol, and using two ratios of maleic anhydride to furfuryl alcohol. The high ratio of maleic anhydride to furfuryl alcohol (1:9) favoured rapid polymerization at a lower temperature, whereas the lower ratio (1:19) resulted in a relatively slower rate of polymerization, which required higher temperatures to affect the reaction. A higher temperature also led to an increase in furfuryl alcohol evaporation from the prepared veneers. The DSC data was compared with data obtained from furfuryl alcohol impregnated wood veneers but without the addition of maleic anhydride. DSC data is in good agreement with weight percentage gains (WPGs) obtained for samples impregnated with differently composed solutions. While higher maleic anhydride contents led to higher WPGs, ethanol dilution inhibits polymer formation, resulting in lower WPG.
This paper references
10.1007/s00107-010-0480-4
Properties of furfurylated wood (Pinus pinaster)
Bruno Esteves (2010)
Resistance of furfurylated wood to termite attack
Y. Hadi (2005)
10.1080/02827580410017825
Differently modified wood: comparison of some selected properties
Hannah Epmeier (2004)
10.1016/S0040-4039(00)86798-2
Reactions of furfuryl alcohols with maleic anhydride
A. Peter (1982)
10.1002/MACP.1992.021930101
Polymerization of furfuryl alcohol with trifluoroacetic acid: the influence of experimental conditions
R. González (1992)
10.1016/S1381-5148(02)00086-X
Esterification of maleic acid with ethanol over cation-exchange resin catalysts
G. Yadav (2002)
10.1039/B707950H
Chemorheological analysis and model-free kinetics of acid catalysed furfuryl alcohol polymerization.
Nathanael Guigo (2007)
10.1039/B010086M
Melting and freezing of water in ordered mesoporous silica materials
A. Schreiber (2001)
10.1016/S0032-3861(05)80042-4
Differential scanning calorimetry of the effects of temperature and humidity on phenol-formaldehyde resin cure
X. Wang (1994)
“ Veneer treatments : DSC , ”
G. Alfredsen (2009)
10.1080/02773818208085138
Bond Formation By Wood Surface Reactions Part Iv Analysis of Furfuryl Alcohol, Tannin and Maleic Acid Bridging Agents
S. S. Kelley (1982)
10.1021/IE50601A039
Stable Furfuryl Alcohol Impregnating Solutions
I. S. Goldstein (1960)
“ Enzymatic hydrolysis of furfurylated Scots pine sapwood ( Pinus sylvestris , L . )
X.-M. Wang (1994)
10.1002/APP.1971.070150504
The chemistry of furfuryl alcohol resins
J. B. Barr (1971)
10.1002/APP.1968.070120716
An investigation of the polymerization of furfuryl alcohol with gel permeation chromatography
E. M. Wewerka (1968)
" Interpretation of curing mechanisms of furfuryl alcohol resins
B. Singaram (1983)
10.1080/0282758041001915
Properties of furfurylated wood
S. Lande (2004)
Furan polymer impregnated wood, of the polymer preparation and use thereof
マーク, エイチ シュネイダー, (2001)
" Furan polymer impregnated wood , method for preparing the polymer and uses thereof
A. Schreiber (2001)
10.1590/S0104-14282000000100004
The polymerization of furfuryl alcohol with p-toluenesulfonic acid: photocross-linkeable feature of the polymer
M. Príncipe (2000)
10.1021/MA951522F
Acid-Catalyzed Polycondensation of Furfuryl Alcohol: Mechanisms of Chromophore Formation and Cross-Linking
M. Choura (1996)
10.1039/B9PY00233B
Furans as offspring of sugars and polysaccharides and progenitors of a family of remarkable polymers: a review of recent progress
A. Gandini (2010)
“ Veneer treatments : DSC , ”
Y. S. Hadi (2005)
Durability of Modified Wood - Laboratory vs Field Performance
G. Alfredsen (2009)



This paper is referenced by
10.17221/101/2015-JFS
Acid phosphomonoesterase activity as affected by salicylic acid and its relation to selected biochemical characteristics in soils of Norway spruce stands.
S. Kočvarová (2016)
10.22616/erdev2018.17.n257
Wood modification with furfuryl alcohol and furfurylated wood durability in water
A. Morozovs (2018)
10.15376/BIORES.9.4.6028-6040
Wood/Polymer Nanocomposites Prepared by Impregnation with Furfuryl Alcohol and Nano-SiO2
Youming Dong (2014)
10.15376/BIORES.11.2.3679-3690
Assessment of the Performance of Furfurylated Wood and Acetylated Wood: Comparison among Four Fast-Growing Wood Species
Youming Dong (2016)
10.15376/BIORES.9.1.545-553
Shape Retention of Furfurylated and Moulded Wood Veneer
N. Herold (2013)
10.1007/s00107-015-0941-x
Investigations of wood veneer during furfuryl alcohol modification using DMTA
Nadine Herold (2015)
10.1039/C3RA43095B
Natural tannin–furanic thermosetting moulding plastics
X. Li (2013)
10.1016/J.EURPOLYMJ.2015.05.020
Characterization of the curing process of mixed pine and spruce tannin-based foams by different methods
Matjaž Čop (2015)
10.1007/s00107-016-1057-7
Determining the curing parameters of furfuryl alcohol for wood modification by nanoindentation
W. Li (2016)
10.15376/BIORES.9.3.4756-4763
Changes in Cell Wall Dimensions during the Different Stages of Furfuryl Alcohol Modification
Nadine Herold (2014)
10.1515/hf-2019-0286
Fabrication of highly stable and durable furfurylated wood materials. Part I: process optimization
Wanju Li (2020)
10.1007/s10853-016-0740-8
Si/iron silicide nanocomposite anodes with furfuryl-alcohol-derived carbon coating for Li-ion batteries
Juyoung Jang (2017)
10.15376/BIORES.11.2.3614-3625
The Furfurylation of Wood: A Nanomechanical Study of Modified Wood Cells
W. Li (2016)
10.4028/www.scientific.net/MSF.997.29
Physical, and Thermal Properties of Wood Impregnated with a Mixture of Furfuryl Alcohol, Styrene, and Nanoclay
M. T. Sultan (2020)
10.1007/s00226-020-01194-1
Furfurylation result of Radiata pine depends on the solvent
L. Thygesen (2020)
Vers une voie de valorisation du hêtre : synthèse de monomères furaniques biosourcés et furfurylation.Towards a valorisation pathway of beech: synthesis of bio-based furan monomers and furfurylation.
Aurélia Imbert (2017)
10.1007/s00226-015-0721-0
Wood modification with furfuryl alcohol catalysed by a new composite acidic catalyst
W. Li (2015)
10.1007/s00226-015-0789-6
Combined treatment for conversion of fast-growing poplar wood to magnetic wood with high dimensional stability
Youming Dong (2015)
Semantic Scholar Logo Some data provided by SemanticScholar