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Convenient Methods For Preparing π-conjugated Linkers As Building Blocks For Modular Chemistry

Jiří Kulhánek, Filip Bureš, Miroslav Ludwig

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Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.